| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alessandro Ballan | Lampre-Fondital | 05:21:05 | |
| 2 | Óscar Freire | Rabobank | + 00 | |
| 3 | Gerald Ciolek | T-Mobile Team | + 00 | |
| 4 | Danilo Napolitano | Lampre-Fondital | + 00 | |
| 5 | Erik Zabel | Team Milram | + 00 | |
| 6 | Davide Rebellin | Gerolsteiner | + 00 | |
| 7 | Paolo Bettini | Quick Step - Innergetic | + 00 | |
| 8 | Greg van Avermaet | Predictor - Lotto | + 00 | |
| 9 | Peter Wrolich | Gerolsteiner | + 00 | |
| 10 | Olaf Pollack | Team Wiesenhof - Felt | + 00 | |
| 11 | David Millar | Saunier Duval - Prodir | + 00 | |
| 12 | Manuele Mori | Saunier Duval - Prodir | + 00 | |
| 13 | William Bonnet | Crédit Agricole | + 00 | |
| 14 | Martin Elmiger | AG2R Prévoyance | + 00 | |
| 15 | Matti Breschel | Team CSC | + 00 | |
| 16 | Piet Rooijakkers | Skil - Shimano | + 00 | |
| 17 | Aitor Galdos | Euskaltel-Euskadi | + 00 | |
| 18 | Alexandre Usov | AG2R Prévoyance | + 00 | |
| 19 | Filippo Pozzato | Liquigas | + 00 | |
| 20 | Saïd Haddou | Bouygues Telecom | + 00 | |
| 21 | Pablo Lastras | Caisse d'Epargne | + 00 | |
| 22 | Marcus Burghardt | T-Mobile Team | + 00 | |
| 23 | Joaquin Rojas José | Caisse d'Epargne | + 05 | + 05 |
| 24 | Giovanni Visconti | Quick Step - Innergetic | + 05 | + 05 |
| 25 | Fumiyuki Beppu | Discovery Channel | + 05 | + 05 |
| 26 | Fabian Wegmann | Gerolsteiner | + 05 | + 05 |
| 27 | Jon Bru | Euskaltel-Euskadi | + 05 | + 05 |
| 28 | Jens Voigt | Team CSC | + 05 | + 05 |
| 29 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 05 | + 05 |
| 30 | Mathew Hayman | Rabobank | + 05 | + 05 |
| 31 | Sébastien Minard | Cofidis | +null | |
| 32 | Marcel Sieberg | Team Milram | + 10 | + 10 |
| 33 | Matteo Tosatto | Quick Step - Innergetic | + 10 | + 10 |
| 34 | Rinaldo Nocentini | AG2R Prévoyance | + 12 | + 12 |
| 35 | Stijn Devolder | Discovery Channel | + 12 | + 12 |
| 36 | Lloyd Mondory | AG2R Prévoyance | + 12 | + 12 |
| 37 | Anders Lund | Team Sparebanken Vest | + 12 | + 12 |
| 38 | Xavier Florencio | Bouygues Telecom | + 12 | + 12 |
| 39 | Jonas Ljungblad | Unibet.com | + 12 | + 12 |
| 40 | Adam Hansen | T-Mobile Team | + 12 | + 12 |
| 41 | Leif Hoste | Predictor - Lotto | + 12 | + 12 |
| 42 | Jussi Veikkanen | Française des Jeux | + 12 | + 12 |
| 43 | Björn Leukemans | Predictor - Lotto | + 19 | + 19 |
| 44 | Ángel Gómez | Saunier Duval - Prodir | + 24 | + 24 |
| 45 | Andrea Tonti | Quick Step - Innergetic | + 26 | + 26 |
| 46 | Riccardo Riccò | Saunier Duval - Prodir | + 26 | + 26 |
| 47 | Pieter Mertens | Predictor - Lotto | + 26 | + 26 |
| 48 | Rubens Bertogliati | Saunier Duval - Prodir | + 26 | + 26 |
| 49 | Steffen Wesemann | Team Wiesenhof - Felt | + 26 | + 26 |
| 50 | Antonio Flecha Juan | Rabobank | + 26 | + 26 |
| 51 | Lorenzo Bernucci | T-Mobile Team | + 26 | + 26 |
| 52 | Gorazd Stangelj | Lampre-Fondital | + 26 | + 26 |
| 53 | Leonardo Bertagnolli | Liquigas | + 26 | + 26 |
| 54 | Vladimir Gusev | Discovery Channel | + 26 | + 26 |
| 55 | Daniele Bennati | Lampre-Fondital | + 35 | + 35 |
| 56 | Sebastien Rosseler | Quick Step - Innergetic | + 39 | + 39 |
| 57 | Léon van Bon | Rabobank | + 42 | + 42 |
| 58 | Simon Gerrans | AG2R Prévoyance | + 55 | + 55 |
| 59 | Luciano Pagliarini | Saunier Duval - Prodir | + 01:16 | + 01:16 |
| 60 | Daniel Musiol | Team Wiesenhof - Felt | + 01:16 | + 01:16 |
| 61 | Christian Knees | Team Milram | + 01:16 | + 01:16 |
| 62 | Erki Pütsep | Bouygues Telecom | + 01:16 | + 01:16 |
| 63 | Koldo Fernandez | Euskaltel-Euskadi | + 01:19 | + 01:19 |
| 64 | Maarten Tjallingii | Skil - Shimano | + 01:19 | + 01:19 |
| 65 | Matthew Wilson | Unibet.com | + 01:19 | + 01:19 |
| 66 | Dionisio Galparsoro | Euskaltel-Euskadi | + 01:19 | + 01:19 |
| 67 | Sébastien Hinault | Crédit Agricole | + 01:19 | + 01:19 |
| 68 | José Oroz Juan | Orbea - Laukiz F.T. | + 01:19 | + 01:19 |
| 69 | David Deroo | Skil - Shimano | + 01:19 | + 01:19 |
| 70 | Marco Pinotti | T-Mobile Team | + 01:19 | + 01:19 |
| 71 | Raivis Belohvosciks | Saunier Duval - Prodir | + 01:19 | + 01:19 |
| 72 | Frédéric Guesdon | Française des Jeux | + 01:19 | + 01:19 |
| 73 | Tyler Farrar | Cofidis | + 01:19 | + 01:19 |
| 74 | Joaquim Rodríguez | Caisse d'Epargne | + 01:19 | + 01:19 |
| 75 | Leonardo Duque | Cofidis | + 01:36 | + 01:36 |
| 76 | Alan Perez Lezaun | Euskaltel-Euskadi | + 01:42 | + 01:42 |
| 77 | William Walker | Rabobank | + 01:48 | + 01:48 |
| 78 | Baden Cooke | Unibet.com | + 01:48 | + 01:48 |
| 79 | Thomas Dekker | Rabobank | + 01:48 | + 01:48 |
| 80 | Philippe Gilbert | Française des Jeux | + 02:22 | + 02:22 |
| 81 | Murilo Fischer | Liquigas | + 02:25 | + 02:25 |
| 82 | Thor Hushovd | Crédit Agricole | + 02:32 | + 02:32 |
| 83 | Claudio Corioni | Lampre-Fondital | + 03:13 | + 03:13 |
| 84 | Mark Renshaw | Crédit Agricole | + 03:55 | + 03:55 |
| 85 | Luke Roberts | Team CSC | + 04:00 | + 04:00 |
| 86 | Matthew Goss | Team CSC | + 04:00 | + 04:00 |
| 87 | Alexey Markov | Caisse d'Epargne | + 04:00 | + 04:00 |
| 88 | Floris Goesinnen | Skil - Shimano | + 04:00 | + 04:00 |
| 89 | Dario Cioni | Predictor - Lotto | + 04:00 | + 04:00 |
| 90 | Michael Albasini | Liquigas | + 04:00 | + 04:00 |
| 91 | Frederik Willems | Liquigas | + 04:00 | + 04:00 |
| 92 | Michael Blaudzun | Team CSC | + 04:00 | + 04:00 |
| 93 | Trent Lowe | Discovery Channel | + 04:00 | + 04:00 |
| 94 | Nicolas Rousseau | AG2R Prévoyance | + 04:00 | + 04:00 |
| 95 | Rony Martias | Bouygues Telecom | + 04:00 | + 04:00 |
| 96 | Sebastien Siedler | Team Milram | + 04:00 | + 04:00 |
| 97 | Markus Eichler | Unibet.com | + 04:00 | + 04:00 |
| 98 | Robert Retschke | Team Wiesenhof - Felt | + 04:00 | + 04:00 |
| 99 | Stephane Augé | Cofidis | + 04:00 | + 04:00 |
| 100 | Wouter Weylandt | Quick Step - Innergetic | + 04:00 | + 04:00 |
| 101 | Lars Bak | Team CSC | + 04:00 | + 04:00 |
| 102 | Artur Gajek | Team Wiesenhof - Felt | + 04:00 | + 04:00 |
| 103 | Johannes Fröhlinger | Gerolsteiner | + 04:00 | + 04:00 |
| 104 | David Kopp | Gerolsteiner | + 04:00 | + 04:00 |
| 105 | Preben van Hecke | Predictor - Lotto | + 05:16 | + 05:16 |
| 106 | Marco Zanotti | Unibet.com | + 05:16 | + 05:16 |
| 107 | Gorik Gardeyn | Unibet.com | + 05:16 | + 05:16 |
| 108 | Laurent Mangel | AG2R Prévoyance | + 05:16 | + 05:16 |
| 109 | Gerben Löwik | Rabobank | + 05:16 | + 05:16 |
| 110 | Michiel Elijzen | Cofidis | + 05:16 | + 05:16 |
| 111 | Marzio Bruseghin | Lampre-Fondital | + 05:16 | + 05:16 |
| 112 | Manuel Quinziato | Liquigas | + 05:16 | + 05:16 |
| 113 | Kenny van Hummel | Skil - Shimano | + 05:16 | + 05:16 |
| 114 | Frank Høj | Cofidis | + 05:16 | + 05:16 |
| 115 | Tom Boonen | Quick Step - Innergetic | + 05:16 | + 05:16 |
| 116 | Aart Vierhouten | Skil - Shimano | + 05:16 | + 05:16 |
| 117 | Pedro Horrillo | Rabobank | + 11:20 | + 11:20 |
| 118 | Imanol Erviti | Caisse d'Epargne | + 11:20 | + 11:20 |
| 119 | Yuriy Krivtsov | AG2R Prévoyance | + 11:20 | + 11:20 |
| 120 | Julian Dean | Crédit Agricole | + 11:20 | + 11:20 |
| 121 | Volker Ordowski | Gerolsteiner | + 11:20 | + 11:20 |
| 122 | Stephan Schreck | T-Mobile Team | + 11:20 | + 11:20 |
| 123 | Robert Wagner | Team Wiesenhof - Felt | + 11:20 | + 11:20 |
| 124 | Björn Schröder | Team Milram | + 11:20 | + 11:20 |
| 125 | Morris Possoni | Lampre-Fondital | + 11:20 | + 11:20 |
| 126 | Volodymyr Bileka | Discovery Channel | + 11:20 | + 11:20 |
| 127 | Yohann Gène | Bouygues Telecom | + 11:20 | + 11:20 |
| 128 | Mathieu Claude | Bouygues Telecom | + 11:20 | + 11:20 |
| 129 | Aurelien Clerc | Bouygues Telecom | + 11:20 | + 11:20 |
| 130 | Bernhard Eisel | T-Mobile Team | + 11:20 | + 11:20 |
| 131 | Marco Marzano | Lampre-Fondital | + 11:20 | + 11:20 |
| 132 | Matthé Pronk | Unibet.com | + 14:27 | + 14:27 |
| 133 | Mauro Da Dalto | Liquigas | + 14:54 | + 14:54 |