| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alejandro Valverde | Illes Balears - Caisse d'Epargne | 04:20:48 | |
| 2 | Ronald Mutsaars | Rabobank | + 42 | + 42 |
| 3 | Steven de Jongh | Rabobank | + 56 | + 56 |
| 4 | David Muñoz | Comunidad Valenciana | + 01:18 | + 01:18 |
| 5 | Rolf Aldag | T-Mobile Team | + 01:19 | + 01:19 |
| 6 | Aitor Perez Arrieta | Spiuk | + 01:21 | + 01:21 |
| 7 | Ricardo Serrano | Kaiku | + 01:21 | + 01:21 |
| 8 | Carlos Castaño | Andalucia - Paul Versan | + 01:21 | + 01:21 |
| 9 | Ezequiel Mosquera | Kaiku | + 01:21 | + 01:21 |
| 10 | Gorka Arrizabalaga Agirre | Orbea | + 01:21 | + 01:21 |
| 11 | Andreas Klier | Discovery Channel | + 01:31 | + 01:31 |
| 12 | Adolfo Garcia Quesada | Comunidad Valenciana | + 01:38 | + 01:38 |
| 13 | Rubén Plaza | Comunidad Valenciana | + 01:38 | + 01:38 |
| 14 | Antonio Tauler Llull | Illes Balears - Caisse d'Epargne | + 01:46 | + 01:46 |
| 15 | Marc Lotz | Quick Step | + 01:47 | + 01:47 |
| 16 | Stephan Schreck | T-Mobile Team | + 01:47 | + 01:47 |
| 17 | Ángel Gómez | Saunier Duval - Prodir | + 01:47 | + 01:47 |
| 18 | Gerben Löwik | Rabobank | + 01:47 | + 01:47 |
| 19 | Rik Verbrugghe | Quick Step | + 01:47 | + 01:47 |
| 20 | Javier Cherro Molina | Comunidad Valenciana | + 01:47 | + 01:47 |
| 21 | Rodrigo Garcia Rena | Kaiku | + 01:58 | + 01:58 |
| 22 | Vicente Reynès | Illes Balears - Caisse d'Epargne | + 01:58 | + 01:58 |
| 23 | Christian Werner | T-Mobile Team | + 01:58 | + 01:58 |
| 24 | Luis Pasamontes | Relax - Fuenlabarda | + 02:07 | + 02:07 |
| 25 | Óscar Freire | Rabobank | + 02:33 | + 02:33 |
| 26 | Joaquim Rodríguez | Saunier Duval - Prodir | + 02:33 | + 02:33 |
| 27 | David López | Euskaltel-Euskadi | + 02:33 | + 02:33 |
| 28 | Xavier Florencio | Relax - Fuenlabarda | + 02:47 | + 02:47 |
| 29 | Antonio Olmo | Comunidad Valenciana | + 02:54 | + 02:54 |
| 30 | Adrian Palomares | Kaiku | + 03:25 | + 03:25 |
| 31 | Luis Martinez Jose | Comunidad Valenciana | + 03:54 | + 03:54 |
| 32 | Erik Zabel | T-Mobile Team | + 04:15 | + 04:15 |
| 33 | David de La Fuente | Saunier Duval - Prodir | + 07:18 | + 07:18 |
| 34 | Jaume Rovira | Andalucia - Paul Versan | + 07:18 | + 07:18 |
| 35 | David Bernabeu | Comunidad Valenciana | + 07:18 | + 07:18 |
| 36 | Antonio Colom | Illes Balears - Caisse d'Epargne | + 09:52 | + 09:52 |
| 37 | Daniel Moreno | Relax - Fuenlabarda | + 09:52 | + 09:52 |
| 38 | Antonio Pastor Roldan Juan | Andalucia - Paul Versan | + 19:38 | + 19:38 |