| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Stijn Devolder | Discovery Channel | 13:15:16 | |
| 2 | Alessandro Ballan | Lampre-Caffita | + 16 | + 16 |
| 3 | Nico Mattan | Davitamon - Lotto | + 24 | + 24 |
| 4 | León Sánchez Luis | Liberty Seguros - Würth Team | + 44 | + 44 |
| 5 | Roberto Petito | Fassa Bortolo | + 45 | + 45 |
| 6 | Servais Knaven | Quick Step | + 01:01 | + 01:01 |
| 7 | Michael Albasini | Liquigas - Bianchi | + 01:25 | + 01:25 |
| 8 | Mathew Hayman | Rabobank | + 01:31 | + 01:31 |
| 9 | Roy Sentjens | Rabobank | + 01:34 | + 01:34 |
| 10 | Mirko Celestino | Domina Vacanze | + 02:04 | + 02:04 |
| 11 | Christophe Detilloux | Française des Jeux | + 02:15 | + 02:15 |
| 12 | Viatcheslav Ekimov | Discovery Channel | + 04:48 | + 04:48 |
| 13 | Magnus Bäckstedt | Liquigas - Bianchi | + 04:59 | + 04:59 |
| 14 | Leif Hoste | Discovery Channel | + 05:09 | + 05:09 |
| 15 | Marc Wauters | Rabobank | + 05:11 | + 05:11 |
| 16 | Thomas Ziegler | Gerolsteiner | + 05:24 | + 05:24 |
| 17 | Sean Sullivan | Team Barloworld - Valsir | + 05:31 | + 05:31 |
| 18 | Nico Eeckhout | Chocolade Jacques - T-Interim | + 05:32 | + 05:32 |
| 19 | Enrico Franzoi | Lampre-Caffita | + 05:46 | + 05:46 |
| 20 | Marcus Ljungqvist | Liquigas - Bianchi | + 05:49 | + 05:49 |
| 21 | Stefan Adamsson | Team Barloworld - Valsir | + 05:49 | + 05:49 |
| 22 | David Boucher | MrBookmaker - Sports Tech | + 05:50 | + 05:50 |
| 23 | Niels Scheuneman | Rabobank | + 05:51 | + 05:51 |
| 24 | Léon van Bon | Davitamon - Lotto | + 06:01 | + 06:01 |
| 25 | Mark Renshaw | Française des Jeux | + 06:02 | + 06:02 |
| 26 | Unai Yus Kerejeta | Bouygues Telecom | + 06:08 | + 06:08 |
| 27 | Roger Hammond | Discovery Channel | + 06:11 | + 06:11 |
| 28 | Gregory Rast | Phonak Hearing Systems | + 06:12 | + 06:12 |
| 29 | Paolo Longo Borghini | Team Barloworld - Valsir | + 06:15 | + 06:15 |
| 30 | Wilfried Cretskens | Quick Step | + 06:16 | + 06:16 |
| 31 | Angel Castresana Del Val | MrBookmaker - Sports Tech | + 06:17 | + 06:17 |
| 32 | Dimitri de Fauw | Quick Step | + 06:23 | + 06:23 |
| 33 | Salvatore Commesso | Lampre-Caffita | + 06:26 | + 06:26 |
| 34 | Antonio Cruz | Discovery Channel | + 06:26 | + 06:26 |
| 35 | Antonio Flecha Juan | Fassa Bortolo | + 06:31 | + 06:31 |
| 36 | Dean Podgornik | Tenax - Nobili Rubinetterie | + 06:33 | + 06:33 |
| 37 | Nicola Loda | Liquigas - Bianchi | + 06:36 | + 06:36 |
| 38 | Frederik Willems | Chocolade Jacques - T-Interim | + 06:37 | + 06:37 |
| 39 | Bernhard Eisel | Française des Jeux | + 06:38 | + 06:38 |
| 40 | Luciano Pagliarini | Liquigas - Bianchi | + 06:43 | + 06:43 |
| 41 | Daniel Musiol | Team Wiesenhof | + 06:45 | + 06:45 |
| 42 | Gianluca Bortolami | Lampre-Caffita | + 06:50 | + 06:50 |
| 43 | Ludovic Auger | Française des Jeux | + 06:51 | + 06:51 |
| 44 | Erwin Thijs | MrBookmaker - Sports Tech | + 06:51 | + 06:51 |
| 45 | Kevin Hulsmans | Quick Step | + 06:58 | + 06:58 |
| 46 | Angelo Furlan | Domina Vacanze | + 06:59 | + 06:59 |
| 47 | Bert Scheirlinckx | Flanders | + 07:00 | + 07:00 |
| 48 | Gert Steegmans | Davitamon - Lotto | + 07:06 | + 07:06 |
| 49 | Wesley van der Linden | Chocolade Jacques - T-Interim | + 07:12 | + 07:12 |
| 50 | Simone Cadamuro | Domina Vacanze | + 07:32 | + 07:32 |
| 51 | Francis Mourey | Française des Jeux | + 07:45 | + 07:45 |
| 52 | Andrus Aug | Fassa Bortolo | + 08:01 | + 08:01 |
| 53 | Frank Høj | Gerolsteiner | + 08:35 | + 08:35 |
| 54 | Frederic Mainguenaud | Bouygues Telecom | + 09:04 | + 09:04 |
| 55 | Claudio Corioni | Fassa Bortolo | + 09:43 | + 09:43 |
| 56 | Carlos Barredo | Liberty Seguros - Würth Team | + 10:44 | + 10:44 |
| 57 | Johan Vansummeren | Davitamon - Lotto | + 10:48 | + 10:48 |
| 58 | Giosue Bonomi | Lampre-Caffita | + 11:02 | + 11:02 |
| 59 | Mads Christensen | Quick Step | + 14:04 | + 14:04 |
| 60 | Bert Roesems | Davitamon - Lotto | + 18:10 | + 18:10 |
| 61 | Sebastian Lang | Gerolsteiner | + 18:26 | + 18:26 |
| 62 | Alessandro Cortinovis | Domina Vacanze | + 18:47 | + 18:47 |
| 63 | Pedro Horrillo | Rabobank | + 18:52 | + 18:52 |
| 64 | Martin Elmiger | Phonak Hearing Systems | + 19:02 | + 19:02 |
| 65 | Sebastien Siedler | Team Wiesenhof | + 19:14 | + 19:14 |
| 66 | Denys Kostyuk | Jartazi - Granville Team | + 19:16 | + 19:16 |
| 67 | Robert Hunter | Phonak Hearing Systems | + 19:17 | + 19:17 |
| 68 | Raimondas Vilcinskas | Jartazi - Granville Team | + 19:25 | + 19:25 |
| 69 | Ronald Mutsaars | Rabobank | + 19:26 | + 19:26 |
| 70 | André Greipel | Team Wiesenhof | + 19:33 | + 19:33 |
| 71 | Aaron Kemps | Liberty Seguros - Würth Team | + 19:40 | + 19:40 |
| 72 | Stefan van Dijk | MrBookmaker - Sports Tech | + 19:53 | + 19:53 |
| 73 | Daniele Bennati | Lampre-Caffita | + 19:54 | + 19:54 |
| 74 | Sergei Ivanov | T-Mobile Team | + 19:54 | + 19:54 |
| 75 | Jan Valach | eD'system - ZVVZ | + 19:58 | + 19:58 |
| 76 | Ludo Dierckxsens | Landbouwkrediet - Colnago | + 20:07 | + 20:07 |
| 77 | Wim de Vocht | Davitamon - Lotto | + 20:08 | + 20:08 |
| 78 | René Obst | Team Wiesenhof | + 20:13 | + 20:13 |
| 79 | Steven de Neef | Bodysol - Win for Life - Jong Vlaan | + 20:13 | + 20:13 |
| 80 | Tom Steels | Davitamon - Lotto | + 20:22 | + 20:22 |
| 81 | Marco Righetto | Liquigas - Bianchi | + 20:29 | + 20:29 |
| 82 | Michal Precechtel | eD'system - ZVVZ | + 20:40 | + 20:40 |
| 83 | Rafael Nuritdinov | Domina Vacanze | + 20:44 | + 20:44 |
| 84 | Mirco Lorenzetto | Domina Vacanze | + 20:45 | + 20:45 |
| 85 | Allan Davis | Liberty Seguros - Würth Team | + 20:47 | + 20:47 |
| 86 | Paolo Fornaciari | Lampre-Caffita | + 21:06 | + 21:06 |
| 87 | Frédéric Guesdon | Française des Jeux | + 21:17 | + 21:17 |
| 88 | Wesley van Speybroeck | Chocolade Jacques - T-Interim | + 21:18 | + 21:18 |
| 89 | Zoran Klemencic | Tenax - Nobili Rubinetterie | + 21:52 | + 21:52 |
| 90 | Kevin van Impe | Chocolade Jacques - T-Interim | + 22:00 | + 22:00 |
| 91 | Francesco Chicchi | Fassa Bortolo | + 22:15 | + 22:15 |
| 92 | Mathieu Criquielion | Landbouwkrediet - Colnago | + 22:29 | + 22:29 |
| 93 | Christophe Mengin | Française des Jeux | + 23:01 | + 23:01 |
| 94 | Peter Ronsse | Jartazi - Granville Team | + 23:34 | + 23:34 |
| 95 | Jeroen van Rij | Bodysol - Win for Life - Jong Vlaan | + 23:44 | + 23:44 |
| 96 | Fabio Baldato | Fassa Bortolo | + 24:20 | + 24:20 |
| 97 | Johan Svensson | Jartazi - Granville Team | + 25:05 | + 25:05 |
| 98 | Daniel Lloyd | Flanders | + 25:09 | + 25:09 |
| 99 | Martin Müller | Team Wiesenhof | + 25:11 | + 25:11 |
| 100 | David Kupka | eD'system - ZVVZ | + 25:14 | + 25:14 |
| 101 | Leonardo Duque | Jartazi - Granville Team | + 25:35 | + 25:35 |
| 102 | Sergio Paulinho | Liberty Seguros - Würth Team | + 26:43 | + 26:43 |
| 103 | Matej Jurco | Domina Vacanze | + 26:51 | + 26:51 |
| 104 | Rony Martias | Bouygues Telecom | + 27:33 | + 27:33 |