| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Óscar Freire | Rabobank | 01:57:08 | |
| 2 | Joaquin Rojas José | Caisse d'Epargne | + 00 | |
| 3 | Gennady Mikhailov | Astana | + 00 | |
| 4 | Koldo Fernandez | Euskaltel-Euskadi | + 00 | |
| 5 | Enrico Gasparotto | Barloworld | + 00 | |
| 6 | Robert Förster | Gerolsteiner | + 00 | |
| 7 | Francisco Ventoso | Saunier Duval - Prodir | + 00 | |
| 8 | Bernhard Eisel | T-Mobile Team | + 00 | |
| 9 | Vicente Reynès | Caisse d'Epargne | + 00 | |
| 10 | Wouter Weylandt | Quick Step - Innergetic | + 00 | |
| 11 | Tomas Vaitkus | Discovery Channel | + 00 | |
| 12 | Unai Elorriaga Zubiaur | + 00 | ||
| 13 | Enrique Mata Cabello | Vina Magna - Cropu | + 00 | |
| 14 | Joaquin Sobrino | Relax - GAM | + 00 | |
| 15 | Gregory Rast | Astana | + 00 | |
| 16 | Gustavo Dominguez Lemos | Karpin-Galicia | + 00 | |
| 17 | Murilo Fischer | Liquigas | + 00 | |
| 18 | Erik Zabel | Team Milram | + 00 | |
| 19 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 00 | |
| 20 | Linas Balciunas | Agritubel | + 00 | |
| 21 | Thomas Fothen | Gerolsteiner | + 00 | |
| 22 | Assan Bazayev | Astana | + 00 | |
| 23 | Jesus Del Nero Montes | Saunier Duval - Prodir | + 00 | |
| 24 | Koen de Kort | Astana | + 00 | |
| 25 | Manuel Vazquez | Andalucia - Cajasur | + 00 | |
| 26 | Stijn Devolder | Discovery Channel | + 00 | |
| 27 | Iván Gutiérrez | Caisse d'Epargne | + 00 | |
| 28 | Denis Kudashev | Relax - GAM | + 00 | |
| 29 | Ignacio Sarabia | Spiuk - Extremadura | + 00 | |
| 30 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 00 | |
| 31 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 00 | |
| 32 | Fernando Torres Martin | Spiuk - Extremadura | + 00 | |
| 33 | Alexey Markov | Caisse d'Epargne | + 00 | |
| 34 | Enrico Poitschke | Team Milram | + 00 | |
| 35 | Jorge Ferrio Luque | Andalucia - Cajasur | + 00 | |
| 36 | Adrian Bonilla | Fuerteventura - Canarias | + 00 | |
| 37 | Alan Perez Lezaun | Euskaltel-Euskadi | + 00 | |
| 38 | José Cobo Juan | Saunier Duval - Prodir | + 00 | |
| 39 | Manuel Quinziato | Liquigas | + 00 | |
| 40 | Daniel Moreno | Relax - GAM | + 00 | |
| 41 | Nacor Burgos | Relax - GAM | + 00 | |
| 42 | Andrey Mizurov | Astana | + 00 | |
| 43 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 00 | |
| 44 | Maxim Gourov | Astana | + 00 | |
| 45 | Jesus Rosendo Prado | Andalucia - Cajasur | + 00 | |
| 46 | Oscar Gatto | Gerolsteiner | + 00 | |
| 47 | Alexey Kolessov | Astana | + 00 | |
| 48 | Jesus Tendero Marcos | Vina Magna - Cropu | + 00 | |
| 49 | Javier Aramendia | Orbea - Laukiz F.T. | + 00 | |
| 50 | Joan Llaneras Rosello | + 00 | ||
| 51 | Markel Irizar | Euskaltel-Euskadi | + 00 | |
| 52 | David de La Fuente | Saunier Duval - Prodir | + 00 | |
| 53 | Ángel Gómez | Saunier Duval - Prodir | + 00 | |
| 54 | Roberto Barrientos Fernandez | Orbea - Laukiz F.T. | + 00 | |
| 55 | Marcel Sieberg | Team Milram | + 00 | |
| 56 | Juan Olmo | Andalucia - Cajasur | + 00 | |
| 57 | Volodymyr Bileka | Discovery Channel | + 00 | |
| 58 | Iker Mezo Askargorta | Orbea - Laukiz F.T. | + 00 | |
| 59 | Iker Camaño | Saunier Duval - Prodir | + 00 | |
| 60 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 00 | |
| 61 | Martin Müller | Team Milram | + 00 | |
| 62 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 00 | |
| 63 | Koos Moerenhout | Rabobank | + 00 | |
| 64 | Adrian Palomares | Fuerteventura - Canarias | + 00 | |
| 65 | David García Dapena | Karpin-Galicia | + 00 | |
| 66 | Vicente Ballester Martinez | Fuerteventura - Canarias | + 00 | |
| 67 | Gorka Amuriza Gumucio | Grupo Nicolas Mateos | + 00 | |
| 68 | Pedro Romero Ocampo | Spiuk - Extremadura | + 00 | |
| 69 | David Bernabeu | Fuerteventura - Canarias | + 00 | |
| 70 | Julian Sanchez | Relax - GAM | + 00 | |
| 71 | Raul Alarcon | Saunier Duval - Prodir | + 00 | |
| 72 | Luengo Celaya Anton | Euskaltel-Euskadi | + 00 | |
| 73 | León Sánchez Luis | Caisse d'Epargne | + 00 | |
| 74 | Luis Pérez Rodríguez | Andalucia - Cajasur | + 00 | |
| 75 | Aitor Hernández | Euskaltel-Euskadi | + 00 | |
| 76 | José Oroz Juan | Orbea - Laukiz F.T. | + 00 | |
| 77 | Oscar Garcia-casarrubios | Relax - GAM | + 00 | |
| 78 | Diego Milan | Grupo Nicolas Mateos | + 00 | |
| 79 | Pavel Padrnos | Discovery Channel | + 00 | |
| 80 | Luis Perez Romero | Andalucia - Cajasur | + 00 | |
| 81 | Manuel Garate Juan | Quick Step - Innergetic | + 00 | |
| 82 | David Muñoz | Fuerteventura - Canarias | + 00 | |
| 83 | Josu Mondelo Diaz | Spiuk - Extremadura | + 00 | |
| 84 | Oleg Chuzhda | Fuerteventura - Canarias | + 00 | |
| 85 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 86 | Carlos Torrent | Vina Magna - Cropu | + 00 | |
| 87 | Gaizka Lasa Larraya | Karpin-Galicia | + 00 | |
| 88 | Bert Grabsch | T-Mobile Team | + 00 | |
| 89 | Diego Gallego | Vina Magna - Cropu | + 00 | |
| 90 | Linus Gerdemann | T-Mobile Team | + 00 | |
| 91 | Gianni Meersman | Discovery Channel | + 00 | |
| 92 | Raul Garcia de Mateos | Relax - GAM | + 00 | |
| 93 | Stefan Schumacher | Gerolsteiner | + 00 | |
| 94 | Antonio Banos Ballester Jose | Grupo Nicolas Mateos | + 00 | |
| 95 | Andreas Klier | T-Mobile Team | + 00 | |
| 96 | Miguel Alzamora Riera | + 00 | ||
| 97 | David Abal Diego | Karpin-Galicia | + 00 | |
| 98 | Gerben Löwik | Rabobank | + 00 | |
| 99 | Christian Knees | Team Milram | + 00 | |
| 100 | Imanol Erviti | Caisse d'Epargne | + 00 | |
| 101 | Francisco Pérez | Caisse d'Epargne | + 00 | |
| 102 | Ralf Grabsch | Team Milram | + 00 | |
| 103 | José Abril Merino Juan | Vina Magna - Cropu | + 00 | |
| 104 | Max van Heeswijk | Rabobank | + 00 | |
| 105 | Josu Agirre Asegniloaza | Orbea - Laukiz F.T. | + 00 | |
| 106 | Mikel Gaztanaga | Agritubel | + 00 | |
| 107 | Ezequiel Mosquera | Karpin-Galicia | + 00 | |
| 108 | Alberto Rodriguez | Vina Magna - Cropu | + 00 | |
| 109 | Johannes Fröhlinger | Gerolsteiner | + 00 | |
| 110 | Thomas Ziegler | T-Mobile Team | + 00 | |
| 111 | Steve Cummings | Discovery Channel | + 00 | |
| 112 | Ivan Gilmartin | Vina Magna - Cropu | + 00 | |
| 113 | Sebastien Siedler | Team Milram | + 00 | |
| 114 | Peter van Petegem | Quick Step - Innergetic | + 00 | |
| 115 | David Martin Peribanez | Vina Magna - Cropu | + 00 | |
| 116 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 00 | |
| 117 | Sebastian Lang | Gerolsteiner | + 00 | |
| 118 | Eduardo Gonzalo Ramirez | Agritubel | + 00 | |
| 119 | Iván Melero | Orbea - Laukiz F.T. | + 00 | |
| 120 | Igor Abakoumov | Astana | + 00 | |
| 121 | Servais Knaven | T-Mobile Team | + 00 | |
| 122 | Tom Boonen | Quick Step - Innergetic | + 00 | |
| 123 | Kevin Hulsmans | Quick Step - Innergetic | + 00 | |
| 124 | Cédric Vasseur | Quick Step - Innergetic | + 00 | |
| 125 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 00 | |
| 126 | Carlos Barredo | Quick Step - Innergetic | + 00 | |
| 127 | Aleksandr Kuschynski | Liquigas | + 00 | |
| 128 | David Millar | Saunier Duval - Prodir | + 00 | |
| 129 | Filippo Pozzato | Liquigas | + 00 | |
| 130 | Jorge Azanza | Euskaltel-Euskadi | + 00 | |
| 131 | Asier Fernandez Mateos | Orbea - Laukiz F.T. | + 00 | |
| 132 | Luis Fernandez Oliveira | Karpin-Galicia | + 00 | |
| 133 | Vladimir Gusev | Discovery Channel | + 00 | |
| 134 | Eloy Teruel | Grupo Nicolas Mateos | + 00 | |
| 135 | Jurgen van Goolen | Discovery Channel | + 00 | |
| 136 | Pieter Weening | Rabobank | + 00 | |
| 137 | Pedro Horrillo | Rabobank | + 00 | |
| 138 | Isidro Nozal Vega | Karpin-Galicia | + 00 | |
| 139 | Israel Pérez | Spiuk - Extremadura | + 00 | |
| 140 | Enrique Salgueiro | Karpin-Galicia | + 00 | |
| 141 | Sebastian Schwager | Team Milram | + 00 | |
| 142 | José Casas Claudio | Andalucia - Cajasur | + 00 | |
| 143 | Manuel Calvente | Agritubel | + 00 | |
| 144 | José Martínez Francisco | Andalucia - Cajasur | + 00 | |
| 145 | Alberto Fernandez | Saunier Duval - Prodir | + 00 | |
| 146 | Jan Hruska | Relax - GAM | + 00 | |
| 147 | Rodrigo Garcia Rena | Fuerteventura - Canarias | + 00 | |
| 148 | David Muntaner | + 00 | ||
| 149 | Miguel Ochoa Gonzalez | Grupo Nicolas Mateos | + 00 | |
| 150 | Javier Moreno | Spiuk - Extremadura | + 00 | |
| 151 | Patrik Sinkewitz | T-Mobile Team | + 00 | |
| 152 | Alessandro Proni | Quick Step - Innergetic | + 00 | |
| 153 | Luis Rubiera José | Discovery Channel | + 00 | |
| 154 | Florent Brard | Caisse d'Epargne | + 00 | |
| 155 | Trent Lowe | Discovery Channel | + 00 | |
| 156 | Yevgeniy Sladkov | Astana | + 00 | |
| 157 | Asier Maeztu | + 00 | ||
| 158 | Andre Korff | T-Mobile Team | + 00 | |
| 159 | Roman Troncoso | Karpin-Galicia | + 00 | |
| 160 | Jose Ruiz Sanchez | Andalucia - Cajasur | + 00 | |
| 161 | Vicente Peiro Marqueno | Grupo Nicolas Mateos | + 00 | |
| 162 | Antonio Tauler Llull | + 00 | ||
| 163 | Jose Terciado Francisco | Relax - GAM | + 00 | |
| 164 | Mikel Artetxe | Fuerteventura - Canarias | + 00 | |
| 165 | Moisés Dueñas | Agritubel | + 00 | |
| 166 | Benat Intxausti | Grupo Nicolas Mateos | + 00 | |
| 167 | Dennis Haueisen | Team Milram | + 00 | |
| 168 | Antonio Lopez Gil Jose | Andalucia - Cajasur | + 00 | |
| 169 | Marcus Burghardt | T-Mobile Team | + 00 | |
| 170 | Michael Albasini | Liquigas | + 00 | |
| 171 | Remmert Wielinga | Saunier Duval - Prodir | + 00 | |
| 172 | Tom Stamsnijder | Gerolsteiner | + 00 | |
| 173 | Unai Uribarri | Euskaltel-Euskadi | + 00 | |
| 174 | Serge Baguet | Quick Step - Innergetic | + 00 | |
| 175 | Gonzalo Rabuñal | Karpin-Galicia | + 00 | |
| 176 | Inigo Lazkano Iriondo | Orbea - Laukiz F.T. | + 00 | |
| 177 | Joost Posthuma | Rabobank | + 00 | |
| 178 | Dmitriy Kozontchuk | Rabobank | + 00 | |
| 179 | Eric Baumann | T-Mobile Team | + 00 | |
| 180 | Jose Herrada | Vina Magna - Cropu | + 00 | |
| 181 | Egoitz Murgoitio Rekalde | Grupo Nicolas Mateos | + 00 | |
| 182 | Angel Rodriguez Garcia | Spiuk - Extremadura | + 00 | |
| 183 | Óscar Pereiro | Caisse d'Epargne | + 00 | |
| 184 | Roberto Alvarez Martin Luis | Vina Magna - Cropu | + 00 | |
| 185 | Rafael Martinez Castillo Jose | Relax - GAM | + 00 | |
| 186 | Kai Reus | Rabobank | + 00 | |
| 187 | Davide Vigano | Quick Step - Innergetic | + 00 | |
| 188 | Guido Trenti | Liquigas | + 00 | |
| 189 | William Walker | Rabobank | + 00 | |
| 190 | Tim Klinger | Gerolsteiner | + 00 | |
| 191 | Luca Paolini | Liquigas | + 24 | + 24 |
| 192 | Björn Schröder | Team Milram | + 53 | + 53 |
| 193 | Magnus Bäckstedt | Liquigas | + 56 | + 56 |
| 194 | Aaron Villegas Trapaga | Orbea - Laukiz F.T. | + 01:03 | + 01:03 |
| 195 | Patrick Calcagni | Liquigas | + 02:16 | + 02:16 |
| 196 | Alfonso Rodriguez Garcia | Spiuk - Extremadura | + 02:16 | + 02:16 |