| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | George Hincapie | Discovery Channel | 04:59:42 | |
| 2 | Alexandre Usov | AG2R Prévoyance | + 00 | |
| 3 | Davide Rebellin | Gerolsteiner | + 00 | |
| 4 | Daniele Bennati | Lampre-Caffita | + 00 | |
| 5 | Peter Wrolich | Gerolsteiner | + 00 | |
| 6 | Markus Zberg | Gerolsteiner | + 00 | |
| 7 | Cristian Moreni | Quick Step | + 00 | |
| 8 | Luca Paolini | Quick Step | + 00 | |
| 9 | Asle Arvesen Kurt | Team CSC | + 00 | |
| 10 | Jan Ullrich | T-Mobile Team | + 00 | |
| 11 | Maxim Iglinskiy | Domina Vacanze | + 00 | |
| 12 | Danilo Di Luca | Liquigas - Bianchi | + 00 | |
| 13 | Philippe Gilbert | Française des Jeux | + 00 | |
| 14 | Laurent Brochard | Bouygues Telecom | + 00 | |
| 15 | Massimiliano Mori | Naturino - Sapore di Mare | + 00 | |
| 16 | David Etxebarria | Liberty Seguros - Würth Team | + 00 | |
| 17 | Iker Flores | Euskaltel-Euskadi | + 00 | |
| 18 | Xabier Zandio | Illes Balears - Caisse d'Epargne | + 00 | |
| 19 | Rémy Di Gregorio | Française des Jeux | + 00 | |
| 20 | Christophe Rinero | R.A.G.T. Semences | + 00 | |
| 21 | Manuele Mori | Saunier Duval - Prodir | + 00 | |
| 22 | Rory Sutherland | Rabobank | + 00 | |
| 23 | Michael Blaudzun | Team CSC | + 00 | |
| 24 | Chris Horner | Saunier Duval - Prodir | + 00 | |
| 25 | Gennady Mikhailov | Discovery Channel | + 00 | |
| 26 | Benjamin Levecot | R.A.G.T. Semences | + 00 | |
| 27 | Patrik Sinkewitz | Quick Step | + 00 | |
| 28 | Alessandro Bertolini | Domina Vacanze | + 00 | |
| 29 | Lars Bak | Team CSC | + 00 | |
| 30 | Thomas Löfkvist | Française des Jeux | + 00 | |
| 31 | Christophe Brandt | Davitamon - Lotto | + 00 | |
| 32 | Matthieu Sprick | Bouygues Telecom | + 00 | |
| 33 | Nico Mattan | Davitamon - Lotto | + 00 | |
| 34 | Ruben Lobato | Saunier Duval - Prodir | + 00 | |
| 35 | Serhiy Honchar | Domina Vacanze | + 00 | |
| 36 | Kim Kirchen | Fassa Bortolo | + 00 | |
| 37 | Alexandre Moos | Phonak Hearing Systems | + 00 | |
| 38 | Didier Rous | Bouygues Telecom | + 00 | |
| 39 | Benoît Salmon | Agritubel | + 00 | |
| 40 | Michael Boogerd | Rabobank | + 00 | |
| 41 | Mirko Celestino | Domina Vacanze | + 00 | |
| 42 | Cyril Dessel | AG2R Prévoyance | + 00 | |
| 43 | Fabian Jeker | Saunier Duval - Prodir | + 00 | |
| 44 | Christophe Agnolutto | Agritubel | + 00 | |
| 45 | Massimo Codol | Fassa Bortolo | + 00 | |
| 46 | Christophe Moreau | Crédit Agricole | + 00 | |
| 47 | David Herrero | Euskaltel-Euskadi | + 00 | |
| 48 | Alessandro Ballan | Lampre-Caffita | + 00 | |
| 49 | Nicolas Portal | AG2R Prévoyance | + 00 | |
| 50 | Stéphane Bergès | Agritubel | + 00 | |
| 51 | Guido Trentin | Cofidis | + 00 | |
| 52 | Simon Gerrans | AG2R Prévoyance | + 00 | |
| 53 | Kanstantsin Sivtsov | Fassa Bortolo | + 00 | |
| 54 | Cédric Vasseur | Cofidis | + 00 | |
| 55 | Pieter Weening | Rabobank | + 00 | |
| 56 | Stéphane Goubert | AG2R Prévoyance | + 00 | |
| 57 | Nick Nuyens | Quick Step | + 00 | |
| 58 | Sylvain Chavanel | Cofidis | + 00 | |
| 59 | Sergio Barbero | Naturino - Sapore di Mare | + 00 | |
| 60 | Yoann Le Boulanger | R.A.G.T. Semences | + 00 | |
| 61 | Damien Nazon | Crédit Agricole | + 00 | |
| 62 | Andrea Moletta | Gerolsteiner | + 00 | |
| 63 | Sergio Paulinho | Liberty Seguros - Würth Team | + 00 | |
| 64 | Michael Rogers | Quick Step | + 00 | |
| 65 | Thomas Dekker | Rabobank | + 00 | |
| 66 | Stefano Garzelli | Liquigas - Bianchi | + 16 | + 16 |
| 67 | Daniel Navarro | Liberty Seguros - Würth Team | + 42 | + 42 |
| 68 | Gregory Habeaux | Landbouwkrediet - Colnago | + 42 | + 42 |
| 69 | Joost Posthuma | Rabobank | + 42 | + 42 |
| 70 | Paolo Bossoni | Fassa Bortolo | + 42 | + 42 |
| 71 | Ludovic Martin | R.A.G.T. Semences | + 42 | + 42 |
| 72 | Maxime Monfort | Landbouwkrediet - Colnago | + 42 | + 42 |
| 73 | Ludovic Turpin | AG2R Prévoyance | + 42 | + 42 |
| 74 | Aurelien Clerc | Phonak Hearing Systems | + 01:50 | + 01:50 |
| 75 | Giovanni Visconti | Domina Vacanze | + 01:50 | + 01:50 |
| 76 | Mario de Sarraga Orviz | Naturino - Sapore di Mare | + 01:50 | + 01:50 |
| 77 | Nicolas Fritsch | Saunier Duval - Prodir | + 01:50 | + 01:50 |
| 78 | Sébastien Hinault | Crédit Agricole | + 01:50 | + 01:50 |
| 79 | Freddy Bichot | Française des Jeux | + 01:50 | + 01:50 |
| 80 | Eric Berthou | R.A.G.T. Semences | + 01:50 | + 01:50 |
| 81 | Björn Leukemans | Davitamon - Lotto | + 01:50 | + 01:50 |
| 82 | Theo Eltink | Rabobank | + 01:50 | + 01:50 |
| 83 | Lilian Jegou | Française des Jeux | + 01:50 | + 01:50 |
| 84 | Fred Rodriguez | Davitamon - Lotto | + 01:50 | + 01:50 |
| 85 | Patrice Halgand | Crédit Agricole | + 01:50 | + 01:50 |
| 86 | Alexandre Vinokourov | T-Mobile Team | + 02:45 | + 02:45 |
| 87 | Sergei Yakovlev | T-Mobile Team | + 02:45 | + 02:45 |
| 88 | Gianluca Bortolami | Lampre-Caffita | + 02:45 | + 02:45 |
| 89 | Christophe Detilloux | Française des Jeux | + 02:45 | + 02:45 |
| 90 | Andrej Hauptman | Fassa Bortolo | + 02:45 | + 02:45 |
| 91 | Steve Zamperi | Phonak Hearing Systems | + 02:45 | + 02:45 |
| 92 | Nicolas Jalabert | Phonak Hearing Systems | + 02:45 | + 02:45 |
| 93 | Fabian Wegmann | Gerolsteiner | + 03:20 | + 03:20 |
| 94 | Volodymyr Bileka | Discovery Channel | + 04:00 | + 04:00 |
| 95 | Andriy Grivko | Domina Vacanze | + 04:00 | + 04:00 |
| 96 | Wim Vansevenant | Davitamon - Lotto | + 04:00 | + 04:00 |
| 97 | Kjell Carlström | Liquigas - Bianchi | + 05:17 | + 05:17 |
| 98 | Imanol Erviti | Illes Balears - Caisse d'Epargne | + 06:21 | + 06:21 |
| 99 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 06:21 | + 06:21 |