| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Pierrick Fedrigo | Bouygues Telecom | 05:42:44 | |
| 2 | Alessandro Ballan | Lampre | + 00 | |
| 3 | David López | Caisse d'Epargne | + 03 | + 03 |
| 4 | Allan Davis | Mitsubishi - Jartazi | + 13 | + 13 |
| 5 | Joaquin Rojas José | Caisse d'Epargne | + 13 | + 13 |
| 6 | Arnaud Gérard | Française des Jeux | + 13 | + 13 |
| 7 | Greg van Avermaet | Silence - Lotto | + 13 | + 13 |
| 8 | Romain Feillu | Agritubel | + 13 | + 13 |
| 9 | Geoffroy Lequatre | Agritubel | + 13 | + 13 |
| 10 | Manuele Mori | Scott - American Beef | + 13 | + 13 |
| 11 | Lloyd Mondory | AG2R La Mondiale | + 13 | + 13 |
| 12 | Peter Velits | Team Milram | + 13 | + 13 |
| 13 | Gregory Rast | Astana | + 13 | + 13 |
| 14 | Pablo Lastras | Caisse d'Epargne | + 13 | + 13 |
| 15 | Mikaël Chérel | Française des Jeux | + 13 | + 13 |
| 16 | Jérôme Pineau | Bouygues Telecom | + 13 | + 13 |
| 17 | Murilo Fischer | Liquigas | + 13 | + 13 |
| 18 | Roman Kireyev | Astana | + 13 | + 13 |
| 19 | Michael Barry | Team Columbia | + 13 | + 13 |
| 20 | Fabian Wegmann | Gerolsteiner | + 13 | + 13 |
| 21 | Antonio Flecha Juan | Rabobank | + 13 | + 13 |
| 22 | Benoît Vaugrenard | Française des Jeux | + 13 | + 13 |
| 23 | Olivier Kaisen | Silence - Lotto | + 13 | + 13 |
| 24 | Josep Jufré | Scott - American Beef | + 13 | + 13 |
| 25 | Giovanni Visconti | Quick Step | + 13 | + 13 |
| 26 | Julien Mazet | Astana | + 13 | + 13 |
| 27 | Wim van Huffel | Silence - Lotto | + 13 | + 13 |
| 28 | Jonathan Hivert | Crédit Agricole | + 13 | + 13 |
| 29 | Alexandre Botcharov | Crédit Agricole | + 13 | + 13 |
| 30 | David de La Fuente | Scott - American Beef | + 13 | + 13 |
| 31 | Haimar Zubeldia | Euskaltel-Euskadi | + 13 | + 13 |
| 32 | Nick Nuyens | Cofidis | + 13 | + 13 |
| 33 | Sébastien Hinault | Crédit Agricole | + 13 | + 13 |
| 34 | Anthony Roux | Française des Jeux | + 13 | + 13 |
| 35 | Andrea Noè | Liquigas | + 13 | + 13 |
| 36 | Damiano Cunego | Lampre | + 13 | + 13 |
| 37 | Rinaldo Nocentini | AG2R La Mondiale | + 13 | + 13 |
| 38 | Cedric Coutouly | Agritubel | + 13 | + 13 |
| 39 | Robert Gesink | Rabobank | + 13 | + 13 |
| 40 | Nicolas Vogondy | Agritubel | + 13 | + 13 |
| 41 | Mathieu Perget | Caisse d'Epargne | + 20 | + 20 |
| 42 | Anthony Charteau | Caisse d'Epargne | + 20 | + 20 |
| 43 | Guillaume Levarlet | Française des Jeux | + 39 | + 39 |
| 44 | Alessandro Proni | Quick Step | + 01:04 | + 01:04 |
| 45 | Sergei Yakovlev | Astana | + 04:20 | + 04:20 |
| 46 | Janek Tombak | Mitsubishi - Jartazi | + 04:20 | + 04:20 |
| 47 | William Bonnet | Crédit Agricole | + 04:20 | + 04:20 |
| 48 | Filippo Pozzato | Liquigas | + 04:20 | + 04:20 |
| 49 | Lasse Bøchman | Glud & Marstrand - Horsens | + 04:20 | + 04:20 |
| 50 | Markel Irizar | Euskaltel-Euskadi | + 04:20 | + 04:20 |
| 51 | Bart Dockx | Silence - Lotto | + 04:20 | + 04:20 |
| 52 | Dominique Cornu | Silence - Lotto | + 04:20 | + 04:20 |
| 53 | Renaud Dion | AG2R La Mondiale | + 04:20 | + 04:20 |
| 54 | Pedro Horrillo | Rabobank | + 04:20 | + 04:20 |
| 55 | Iker Camaño | Scott - American Beef | + 04:20 | + 04:20 |
| 56 | Kevin Seeldraeyers | Quick Step | + 04:20 | + 04:20 |
| 57 | Markus Zberg | Gerolsteiner | + 04:20 | + 04:20 |
| 58 | Michael Schär | Astana | + 04:20 | + 04:20 |
| 59 | Sylvain Chavanel | Cofidis | + 04:20 | + 04:20 |
| 60 | Sébastien Minard | Cofidis | + 04:20 | + 04:20 |
| 61 | David Canada | Scott - American Beef | + 04:20 | + 04:20 |
| 62 | Franco Pellizotti | Liquigas | + 04:20 | + 04:20 |
| 63 | Ángel Gómez | Scott - American Beef | + 04:20 | + 04:20 |
| 64 | Imanol Erviti | Caisse d'Epargne | + 04:20 | + 04:20 |
| 65 | Jean-marc Marino | Crédit Agricole | + 04:20 | + 04:20 |
| 66 | Frédéric Guesdon | Française des Jeux | + 04:20 | + 04:20 |
| 67 | Rigoberto Uran | Caisse d'Epargne | + 04:20 | + 04:20 |
| 68 | Dmitriy Kozontchuk | Rabobank | + 04:20 | + 04:20 |
| 69 | Karsten Kroon | Team CSC - Saxo Bank | + 04:20 | + 04:20 |
| 70 | José Oroz Juan | Euskaltel-Euskadi | + 06:10 | + 06:10 |
| 71 | Thomas Voeckler | Bouygues Telecom | + 07:52 | + 07:52 |
| 72 | Alessandro Vanotti | Liquigas | + 07:52 | + 07:52 |
| 73 | Kjell Carlström | Liquigas | + 07:52 | + 07:52 |
| 74 | Maryan Hary | Cofidis | + 07:52 | + 07:52 |
| 75 | Christophe Le Mével | Crédit Agricole | + 07:52 | + 07:52 |
| 76 | Bauke Mollema | Rabobank | + 07:52 | + 07:52 |
| 77 | Peter Wrolich | Gerolsteiner | + 09:09 | + 09:09 |
| 78 | Ralf Grabsch | Team Milram | + 09:09 | + 09:09 |
| 79 | Alexandr Pliuschin | AG2R La Mondiale | + 09:09 | + 09:09 |
| 80 | Tom Stamsnijder | Gerolsteiner | + 09:09 | + 09:09 |
| 81 | Jon Bru | Euskaltel-Euskadi | + 09:09 | + 09:09 |
| 82 | Iñaki Isasi | Euskaltel-Euskadi | + 09:09 | + 09:09 |
| 83 | Jorge Azanza | Euskaltel-Euskadi | + 09:09 | + 09:09 |
| 84 | Kevin de Weert | Cofidis | + 09:09 | + 09:09 |
| 85 | Roy Sentjens | Silence - Lotto | + 09:09 | + 09:09 |
| 86 | Xavier Florencio | Bouygues Telecom | + 09:09 | + 09:09 |