| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Óscar Freire | Rabobank | 03:41:12 | |
| 2 | Isaac Gálvez | Illes Balears - Caisse d'Epargne | + 00 | |
| 3 | Dimitri de Fauw | Quick Step | + 00 | |
| 4 | Erik Zabel | T-Mobile Team | + 00 | |
| 5 | Unai Elorriaga Zubiaur | + 00 | ||
| 6 | Vidal Celis Zabala | Orbea | + 00 | |
| 7 | Mikel Gaztanaga | Catalunya - Angel Mir | + 00 | |
| 8 | Olaf Pollack | T-Mobile Team | + 00 | |
| 9 | David Muñoz | Comunidad Valenciana | + 00 | |
| 10 | Alejandro Valverde | Illes Balears - Caisse d'Epargne | + 00 | |
| 11 | Andreas Klier | Discovery Channel | + 00 | |
| 12 | Vicente Reynès | Illes Balears - Caisse d'Epargne | + 00 | |
| 13 | Daniel Moreno | Relax - Fuenlabarda | + 00 | |
| 14 | Antonio Colom | Illes Balears - Caisse d'Epargne | + 00 | |
| 15 | Ricardo Serrano | Kaiku | + 00 | |
| 16 | Steven de Jongh | Rabobank | + 00 | |
| 17 | Martin Elmiger | Phonak Hearing Systems | + 00 | |
| 18 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 00 | |
| 19 | Aitor Perez Arrieta | Spiuk | + 00 | |
| 20 | Luis Pasamontes | Relax - Fuenlabarda | + 00 | |
| 21 | Carlos Castaño | Andalucia - Paul Versan | + 00 | |
| 22 | Pablo Urtasun | Kaiku | + 00 | |
| 23 | Ángel Martin Miguel | Phonak Hearing Systems | + 00 | |
| 24 | Antonio Miguel Parra | Catalunya - Angel Mir | + 00 | |
| 25 | Mikel Artetxe | Euskaltel-Euskadi | + 00 | |
| 26 | Javier Cherro Molina | Comunidad Valenciana | + 00 | |
| 27 | Ángel Edo | Saunier Duval - Prodir | + 00 | |
| 28 | Jordi Berenguer Ferrer | Catalunya - Angel Mir | + 00 | |
| 29 | Jorge Ferrio Luque | Spiuk | + 00 | |
| 30 | Jorge Azanza | Kaiku | + 00 | |
| 31 | Ángel Gómez | Saunier Duval - Prodir | + 00 | |
| 32 | Jon Bru | Kaiku | + 00 | |
| 33 | Iker Camaño | Euskaltel-Euskadi | + 00 | |
| 34 | Adolfo Garcia Quesada | Comunidad Valenciana | + 00 | |
| 35 | Adrian Bonilla | Comunidad Valenciana | + 00 | |
| 36 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 00 | |
| 37 | Pedro Romero Ocampo | Spiuk | + 00 | |
| 38 | Adrian Palomares | Kaiku | + 00 | |
| 39 | Luis Perez Romero | Relax - Fuenlabarda | + 00 | |
| 40 | Antonio Pastor Roldan Juan | Andalucia - Paul Versan | + 00 | |
| 41 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 00 | |
| 42 | Gorka Arrizabalaga Agirre | Orbea | + 00 | |
| 43 | Jaume Rovira | Andalucia - Paul Versan | + 00 | |
| 44 | Javier Benitez | Relax - Fuenlabarda | + 00 | |
| 45 | Eloy Teruel | + 00 | ||
| 46 | Bert Grabsch | Phonak Hearing Systems | + 00 | |
| 47 | Iban Mayoz | Relax - Fuenlabarda | + 00 | |
| 48 | Xabier Zandio | Illes Balears - Caisse d'Epargne | + 00 | |
| 49 | Manuel Gomes Colinas Victor | Andalucia - Paul Versan | + 00 | |
| 50 | David de La Fuente | Saunier Duval - Prodir | + 00 | |
| 51 | Antonio Olmo | Comunidad Valenciana | + 00 | |
| 52 | Antonio Tauler Llull | Illes Balears - Caisse d'Epargne | + 00 | |
| 53 | Christian Werner | T-Mobile Team | + 00 | |
| 54 | Rafael Macarron | Spiuk | + 00 | |
| 55 | Miguel Alzamora Riera | + 00 | ||
| 56 | Rory Sutherland | Rabobank | + 00 | |
| 57 | Raul Garcia de Mateos | Relax - Fuenlabarda | + 00 | |
| 58 | Rolf Aldag | T-Mobile Team | + 00 | |
| 59 | Gerben Löwik | Rabobank | + 00 | |
| 60 | Rodrigo Garcia Rena | Kaiku | + 00 | |
| 61 | Ignacio Gutierrez | Phonak Hearing Systems | + 00 | |
| 62 | Axetza Pena Iza | Euskaltel-Euskadi | + 00 | |
| 63 | Javier Pascual Llorente | Comunidad Valenciana | + 00 | |
| 64 | Julen Zubero Aldekoa | Orbea | + 00 | |
| 65 | Aaron Villegas Trapaga | Orbea | + 00 | |
| 66 | Sebastian Franco | + 00 | ||
| 67 | Luis Martinez Jose | Comunidad Valenciana | + 00 | |
| 68 | Johann Tschopp | Phonak Hearing Systems | + 00 | |
| 69 | Alan Perez Lezaun | Orbea | + 00 | |
| 70 | Mathew Hayman | Rabobank | + 00 | |
| 71 | Igor Anton | Euskaltel-Euskadi | + 00 | |
| 72 | Carlos Torrent | Catalunya - Angel Mir | + 00 | |
| 73 | Xavier Tondó | Catalunya - Angel Mir | + 00 | |
| 74 | Theo Eltink | Rabobank | + 00 | |
| 75 | Iker Flores | Euskaltel-Euskadi | + 00 | |
| 76 | Enrique Gutiérrez José | Phonak Hearing Systems | + 00 | |
| 77 | Iker Mezo Askargorta | Orbea | + 00 | |
| 78 | David Fernandez | Andalucia - Paul Versan | + 00 | |
| 79 | Daniel Schnider | Phonak Hearing Systems | + 00 | |
| 80 | Angel Rodriguez Garcia | Spiuk | + 00 | |
| 81 | Efrain Gutierrez Sanchez | Andalucia - Paul Versan | + 00 | |
| 82 | Fernando Torres Martin | Spiuk | + 00 | |
| 83 | Tadej Valjavec | Phonak Hearing Systems | + 00 | |
| 84 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 00 | |
| 85 | Marc Lotz | Quick Step | + 00 | |
| 86 | Manuel Garate Juan | Saunier Duval - Prodir | + 00 | |
| 87 | Manuel Diaz Armas Dailos | Orbea | + 00 | |
| 88 | José Martínez Francisco | Andalucia - Paul Versan | + 00 | |
| 89 | Ezequiel Mosquera | Kaiku | + 00 | |
| 90 | Alberto Rodriguez | Catalunya - Angel Mir | + 00 | |
| 91 | Cristian Moreni | Quick Step | + 00 | |
| 92 | Tomasz Nose | Phonak Hearing Systems | + 00 | |
| 93 | Oliver Zaugg | Saunier Duval - Prodir | + 00 | |
| 94 | Jan Schaffrath | T-Mobile Team | + 00 | |
| 95 | Imanol Erviti | Illes Balears - Caisse d'Epargne | + 00 | |
| 96 | Sergio Dominguez | Spiuk | + 00 | |
| 97 | Steffen Wesemann | T-Mobile Team | + 00 | |
| 98 | Alberto Benitez Jose | Spiuk | + 00 | |
| 99 | Joan Llaneras Rosello | + 00 | ||
| 100 | Stephan Schreck | T-Mobile Team | + 00 | |
| 101 | Maarten den Bakker | Rabobank | + 00 | |
| 102 | Luengo Celaya Anton | Euskaltel-Euskadi | + 00 | |
| 103 | Rubén Plaza | Comunidad Valenciana | + 00 | |
| 104 | Ruben Lobato | Saunier Duval - Prodir | + 00 | |
| 105 | David Bernabeu | Comunidad Valenciana | + 00 | |
| 106 | Ángel Casero | Comunidad Valenciana | + 00 | |
| 107 | Moisés Dueñas | Relax - Fuenlabarda | + 00 | |
| 108 | Patrik Sinkewitz | Quick Step | + 00 | |
| 109 | Andoni Aranaga Akzune | Kaiku | + 00 | |
| 110 | Iker Leonet Iza | Illes Balears - Caisse d'Epargne | + 00 | |
| 111 | Paolo Bettini | Quick Step | + 00 | |
| 112 | David Herrero | Euskaltel-Euskadi | + 00 | |
| 113 | Joseba Agirrezabala | + 00 | ||
| 114 | Jesus Buendia Romero | + 00 | ||
| 115 | Antonio Garrido Jose | Quick Step | + 00 | |
| 116 | Rik Verbrugghe | Quick Step | + 00 | |
| 117 | Antonio Pecharroman Jose | Quick Step | + 00 | |
| 118 | Miguel Mercado Juan | Quick Step | + 00 | |
| 119 | Gorka Amuriza Gumucio | Orbea | + 00 | |
| 120 | Mads Christensen | Quick Step | + 00 | |
| 121 | Alexandr Kolobnev | Rabobank | + 00 | |
| 122 | Aitor Alonso Granados | + 00 | ||
| 123 | Javier Ruiz de Larrinaga | Kaiku | + 00 | |
| 124 | Jorge Sanchez Pimienta | Spiuk | + 00 | |
| 125 | Íñigo Cuesta | Saunier Duval - Prodir | + 00 | |
| 126 | Alberto Lopez | Euskaltel-Euskadi | + 00 | |
| 127 | José Gomez | Saunier Duval - Prodir | + 00 | |
| 128 | Karsten Kroon | Rabobank | + 00 | |
| 129 | David Canada | Saunier Duval - Prodir | + 00 | |
| 130 | Nicolas Fritsch | Saunier Duval - Prodir | + 00 | |
| 131 | Roberto Laiseka | Euskaltel-Euskadi | + 00 | |
| 132 | Alfonso Rodriguez Garcia | Spiuk | + 00 | |
| 133 | Xavier Florencio | Relax - Fuenlabarda | + 00 | |
| 134 | Antonio Lopez Gil Jose | Kaiku | + 00 | |
| 135 | Guillermo Ferrer Garcia | + 00 | ||
| 136 | David Navas Chica | Illes Balears - Caisse d'Epargne | + 00 | |
| 137 | José Lara Francisco | T-Mobile Team | + 00 | |
| 138 | Torsten Hiekmann | T-Mobile Team | + 00 | |
| 139 | Marc Wauters | Rabobank | + 00 | |
| 140 | Angel Vallejo Dominquez | Relax - Fuenlabarda | + 35 | + 35 |
| 141 | Josep Jufré | Relax - Fuenlabarda | + 01:41 | + 01:41 |