| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Isaac Gálvez | Caisse d'Epargne - Illes Balears | 03:45:53 | |
| 2 | Robert Förster | Gerolsteiner | + 00 | |
| 3 | Paolo Bettini | Quick Step - Innergetic | + 00 | |
| 4 | Francesco Chicchi | Quick Step - Innergetic | + 00 | |
| 5 | Antonio Flecha Juan | Rabobank | + 00 | |
| 6 | Luca Paolini | Liquigas | + 00 | |
| 7 | Jesus Del Nero Montes | 3 Molinos Resort | + 00 | |
| 8 | Lloyd Mondory | AG2R Prévoyance | + 00 | |
| 9 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 00 | |
| 10 | Alberto Benito Guerrero | 3 Molinos Resort | + 00 | |
| 11 | Javier Benitez | Grupo Nicolas Mateos | + 00 | |
| 12 | Martin Elmiger | Phonak Hearing Systems | + 00 | |
| 13 | Oscar Grau Jorda | Vina Magna - Cropu | + 00 | |
| 14 | Francisco Ventoso | Saunier Duval - Prodir | + 00 | |
| 15 | Sascha Urweider | Phonak Hearing Systems | + 00 | |
| 16 | Ivan Terenine | Omnibike Dynamo Moscow | + 00 | |
| 17 | Heinrich Haussler | Gerolsteiner | + 00 | |
| 18 | Constantino Zaballa | Caisse d'Epargne - Illes Balears | + 00 | |
| 19 | Jorge Azanza | Kaiku | + 00 | |
| 20 | Henk Vogels | Davitamon - Lotto | + 00 | |
| 21 | Luis Marichalar Pedro | Andalucia - Paul Versan | + 00 | |
| 22 | David Navas Chica | AG2R Prévoyance | + 00 | |
| 23 | Mathew Hayman | Rabobank | + 00 | |
| 24 | Marcus Burghardt | T-Mobile Team | + 00 | |
| 25 | David Muñoz | Comunidad Valenciana | + 00 | |
| 26 | Rodrigo Garcia Rena | Kaiku | + 00 | |
| 27 | Stefan Schumacher | Gerolsteiner | + 00 | |
| 28 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 00 | |
| 29 | Pablo Urtasun | Kaiku | + 00 | |
| 30 | Joseba Albizu Lizaso | Euskaltel-Euskadi | + 00 | |
| 31 | Gregory Rast | Phonak Hearing Systems | + 00 | |
| 32 | Fränk Schleck | Team CSC | + 00 | |
| 33 | Adrian Palomares | Kaiku | + 00 | |
| 34 | Carlos Castaño | Kaiku | + 00 | |
| 35 | Bram de Groot | Rabobank | + 00 | |
| 36 | Alexey Markov | Caisse d'Epargne - Illes Balears | + 00 | |
| 37 | Ángel Edo | Andalucia - Paul Versan | + 00 | |
| 38 | Kjell Carlström | Liquigas | + 00 | |
| 39 | Nicola Loda | Liquigas | + 00 | |
| 40 | Pedro Horrillo | Rabobank | + 00 | |
| 41 | Yuriy Krivtsov | AG2R Prévoyance | + 00 | |
| 42 | Ignacio Gutierrez | Phonak Hearing Systems | + 00 | |
| 43 | Francisco Cabello | Andalucia - Paul Versan | + 00 | |
| 44 | Javier Mejias | Saunier Duval - Prodir | + 00 | |
| 45 | Manuel Vazquez | Andalucia - Paul Versan | + 00 | |
| 46 | David Bernabeu | Comunidad Valenciana | + 00 | |
| 47 | Luis Arrieta José | AG2R Prévoyance | + 00 | |
| 48 | Koldo Fernandez | Euskaltel-Euskadi | + 00 | |
| 49 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 00 | |
| 50 | Diego Milan | Grupo Nicolas Mateos | + 00 | |
| 51 | Josep Jufré | Davitamon - Lotto | + 00 | |
| 52 | Manuel Ortega | Andalucia - Paul Versan | + 00 | |
| 53 | Eduard Vorganov | Omnibike Dynamo Moscow | + 00 | |
| 54 | Gerardo Fernandez | Vina Magna - Cropu | + 00 | |
| 55 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 00 | |
| 56 | Theo Eltink | Rabobank | + 00 | |
| 57 | Vicente Ballester Martinez | Comunidad Valenciana | + 00 | |
| 58 | David Kopp | Gerolsteiner | + 00 | |
| 59 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 00 | |
| 60 | Juan Gomis Lopez | Comunidad Valenciana | + 00 | |
| 61 | Samuel Dumoulin | AG2R Prévoyance | + 00 | |
| 62 | Mikel Pradera | Caisse d'Epargne - Illes Balears | + 00 | |
| 63 | Antonio Tauler Llull | 3 Molinos Resort | + 00 | |
| 64 | Sergio Herrero | Vina Magna - Cropu | + 00 | |
| 65 | Sergei Ivanov | T-Mobile Team | + 00 | |
| 66 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 00 | |
| 67 | Alexandre Moos | Phonak Hearing Systems | + 00 | |
| 68 | Imanol Erviti | Caisse d'Epargne - Illes Balears | + 00 | |
| 69 | Enrique Gutiérrez José | Phonak Hearing Systems | + 00 | |
| 70 | Jorge García Marín | Relax - GAM | + 00 | |
| 71 | Carlos Torrent | Vina Magna - Cropu | + 00 | |
| 72 | Koos Moerenhout | Phonak Hearing Systems | + 00 | |
| 73 | Francisco Pérez | Caisse d'Epargne - Illes Balears | + 00 | |
| 74 | Manuel Lloret | Comunidad Valenciana | + 00 | |
| 75 | Mario Aerts | Davitamon - Lotto | + 00 | |
| 76 | Christian Vande Velde | Team CSC | + 00 | |
| 77 | Joseba Zubeldia | Euskaltel-Euskadi | + 00 | |
| 78 | Oscar Garcia-casarrubios | Relax - GAM | + 00 | |
| 79 | Jesus Tendero Marcos | Vina Magna - Cropu | + 00 | |
| 80 | Andy Schleck | Team CSC | + 00 | |
| 81 | Charles Dionne | Saunier Duval - Prodir | + 00 | |
| 82 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 00 | |
| 83 | Lorenzo Bernucci | T-Mobile Team | + 00 | |
| 84 | Andreas Klier | T-Mobile Team | + 00 | |
| 85 | Marcel Strauss | Gerolsteiner | + 00 | |
| 86 | Oleg Chuzhda | Comunidad Valenciana | + 00 | |
| 87 | Santos Gonzalez | 3 Molinos Resort | + 00 | |
| 88 | Luis Perez Romero | Andalucia - Paul Versan | + 00 | |
| 89 | David de La Fuente | Saunier Duval - Prodir | + 00 | |
| 90 | Juan Olmo | Andalucia - Paul Versan | + 00 | |
| 91 | Joseba Agirrezabala | Grupo Nicolas Mateos | + 00 | |
| 92 | Gorka Verdugo | Euskaltel-Euskadi | + 00 | |
| 93 | Rafael Casero Moreno | 3 Molinos Resort | + 00 | |
| 94 | Ivan Gilmartin | Kaiku | + 00 | |
| 95 | Mikel Astarloza | AG2R Prévoyance | + 00 | |
| 96 | Steve Zamperi | Phonak Hearing Systems | + 00 | |
| 97 | Isidro Cerrato Lopez | 3 Molinos Resort | + 00 | |
| 98 | Luengo Celaya Anton | Euskaltel-Euskadi | + 00 | |
| 99 | Jorge Capitan Peregina | Vina Magna - Cropu | + 00 | |
| 100 | Iker Flores | Euskaltel-Euskadi | + 00 | |
| 101 | Julian Sanchez | Comunidad Valenciana | + 00 | |
| 102 | Hubert Schwab | Quick Step - Innergetic | + 00 | |
| 103 | Michael Albasini | Liquigas | + 00 | |
| 104 | Marco Milesi | Liquigas | + 00 | |
| 105 | Vincenzo Nibali | Liquigas | + 00 | |
| 106 | Viacheslav Vilkov | Omnibike Dynamo Moscow | + 00 | |
| 107 | Javier Ruiz de Larrinaga | Kaiku | + 00 | |
| 108 | Iban Iriondo Uranga | Euskaltel-Euskadi | + 00 | |
| 109 | Johan Vansummeren | Davitamon - Lotto | + 00 | |
| 110 | Fernando Serrano | Kaiku | + 00 | |
| 111 | Jesus Buendia Romero | 3 Molinos Resort | + 00 | |
| 112 | Steffen Wesemann | T-Mobile Team | + 00 | |
| 113 | Inigo Chaurreau | AG2R Prévoyance | + 00 | |
| 114 | Israel Nunez Baticon | Kaiku | + 00 | |
| 115 | Wim Vansevenant | Davitamon - Lotto | + 00 | |
| 116 | Patrick Mccarty Jonathan | Phonak Hearing Systems | + 00 | |
| 117 | Javier Moreno | Grupo Nicolas Mateos | + 00 | |
| 118 | Matthias Russ | Gerolsteiner | + 00 | |
| 119 | Antonio Olmo | Comunidad Valenciana | + 00 | |
| 120 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 00 | |
| 121 | Carlos Zarate | Saunier Duval - Prodir | + 00 | |
| 122 | Peter van Petegem | Davitamon - Lotto | + 00 | |
| 123 | Serge Baguet | Quick Step - Innergetic | + 00 | |
| 124 | Diego Gallego | Vina Magna - Cropu | + 00 | |
| 125 | Sergio Pardilla | Vina Magna - Cropu | + 00 | |
| 126 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 00 | |
| 127 | Yury Trofimov | Omnibike Dynamo Moscow | + 00 | |
| 128 | José Abril Merino Juan | Vina Magna - Cropu | + 00 | |
| 129 | Alberto Benitez Jose | Saunier Duval - Prodir | + 00 | |
| 130 | Linus Gerdemann | T-Mobile Team | + 00 | |
| 131 | Scott Davis | T-Mobile Team | + 00 | |
| 132 | Alexis Rodriguez | 3 Molinos Resort | + 00 | |
| 133 | Peter Luttenberger | Team CSC | + 00 | |
| 134 | Mario Almagro Valero Jose | Relax - GAM | + 00 | |
| 135 | Joost Posthuma | Rabobank | + 00 | |
| 136 | Jean-patrick Nazon | AG2R Prévoyance | + 00 | |
| 137 | Jose Herrada | Vina Magna - Cropu | + 00 | |
| 138 | Daniele Nardello | T-Mobile Team | + 00 | |
| 139 | Mario de Sarraga Orviz | Relax - GAM | + 00 | |
| 140 | Luis Martinez Jose | Comunidad Valenciana | + 00 | |
| 141 | Franco Pellizotti | Liquigas | + 00 | |
| 142 | Cayetano Juliá José | Caisse d'Epargne - Illes Balears | + 00 | |
| 143 | Iker Leonet Iza | Caisse d'Epargne - Illes Balears | + 00 | |
| 144 | Wouter Weylandt | Quick Step - Innergetic | + 00 | |
| 145 | Vladimir Miholjevic | Liquigas | + 00 | |
| 146 | Arkaitz Durán | Saunier Duval - Prodir | + 00 | |
| 147 | Íñigo Cuesta | Team CSC | + 00 | |
| 148 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 00 | |
| 149 | Michael Boogerd | Rabobank | + 00 | |
| 150 | Jorge Ferrio Luque | 3 Molinos Resort | + 00 | |
| 151 | Manuel Garate Juan | Quick Step - Innergetic | + 00 | |
| 152 | Filippo Pozzato | Quick Step - Innergetic | + 00 | |
| 153 | Adrian Bonilla | Comunidad Valenciana | + 00 | |
| 154 | Thomas Dekker | Rabobank | + 00 | |
| 155 | Beat Zberg | Gerolsteiner | + 00 | |
| 156 | Marc Wauters | Rabobank | + 00 | |
| 157 | Andrea Peron | Team CSC | + 00 | |
| 158 | Sven Montgomery | Gerolsteiner | + 00 | |
| 159 | Ivan Santaromita | Quick Step - Innergetic | + 00 | |
| 160 | Ronny Scholz | Gerolsteiner | + 00 | |
| 161 | Wim van Huffel | Davitamon - Lotto | + 00 | |
| 162 | Joan Horrach | Caisse d'Epargne - Illes Balears | + 00 | |
| 163 | Ivan Seledkov | Omnibike Dynamo Moscow | + 00 | |
| 164 | Niels Scheuneman | Rabobank | + 00 | |
| 165 | Hugo Pena Victor | Phonak Hearing Systems | + 00 | |
| 166 | Jesús Hernández | Relax - GAM | + 00 | |
| 167 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 00 | |
| 168 | Davide Vigano | Quick Step - Innergetic | + 27 | + 27 |
| 169 | Kim Kirchen | T-Mobile Team | + 33 | + 33 |
| 170 | Bernhard Kohl | T-Mobile Team | + 36 | + 36 |
| 171 | Jens Voigt | Team CSC | + 51 | + 51 |
| 172 | Andrey Klyuev | Omnibike Dynamo Moscow | + 51 | + 51 |
| 173 | Torsten Hiekmann | Gerolsteiner | + 51 | + 51 |
| 174 | Jose Terciado Francisco | Relax - GAM | + 51 | + 51 |
| 175 | Dario Cioni | Liquigas | + 51 | + 51 |
| 176 | Davide Bramati | Quick Step - Innergetic | + 51 | + 51 |
| 177 | Ruben Lobato | Saunier Duval - Prodir | + 51 | + 51 |
| 178 | José Cobo Juan | Saunier Duval - Prodir | + 51 | + 51 |
| 179 | Vladislav Borisov | Omnibike Dynamo Moscow | + 51 | + 51 |
| 180 | Carlos Fernandez Mora Juan | Grupo Nicolas Mateos | + 51 | + 51 |
| 181 | Piotr Mazur | Saunier Duval - Prodir | + 02:01 | + 02:01 |
| 182 | Antonio Lopez Gil Jose | Kaiku | + 03:05 | + 03:05 |
| 183 | Rafael Martinez Castillo Jose | Relax - GAM | + 08:51 | + 08:51 |
| 184 | José Lara Francisco | Andalucia - Paul Versan | + 08:51 | + 08:51 |