| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Tom Boonen | Quick Step - Innergetic | 04:55:36 | |
| 2 | Fabian Cancellara | Team CSC | + 00 | |
| 3 | Marcus Burghardt | T-Mobile Team | + 00 | |
| 4 | Manuel Quinziato | Liquigas | + 00 | |
| 5 | Allan Johansen | Team CSC | + 42 | + 42 |
| 6 | Roy Sentjens | Predictor - Lotto | + 46 | + 46 |
| 7 | Philippe Gilbert | Française des Jeux | + 46 | + 46 |
| 8 | Baden Cooke | Unibet.com | + 46 | + 46 |
| 9 | Stuart O'grady | Team CSC | + 46 | + 46 |
| 10 | Alessandro Ballan | Lampre-Fondital | + 46 | + 46 |
| 11 | Sergei Ivanov | Astana | + 46 | + 46 |
| 12 | Óscar Freire | Rabobank | + 46 | + 46 |
| 13 | Stijn Devolder | Discovery Channel | + 46 | + 46 |
| 14 | Michael Boogerd | Rabobank | + 56 | + 56 |
| 15 | Murilo Fischer | Liquigas | + 02:25 | + 02:25 |
| 16 | Staf Scheirlinckx | Cofidis | + 02:25 | + 02:25 |
| 17 | Simone Masciarelli | Acqua e Sapone | + 02:25 | + 02:25 |
| 18 | Arnaud Coyot | Unibet.com | + 02:25 | + 02:25 |
| 19 | Martin Elmiger | AG2R Prévoyance | + 02:25 | + 02:25 |
| 20 | Bert de Backer | Navigators Insurance Cycling Team | + 02:25 | + 02:25 |
| 21 | Peter van Petegem | Quick Step - Innergetic | + 02:25 | + 02:25 |
| 22 | Andy Cappelle | Landbouwkrediet - Tönissteiner | + 02:25 | + 02:25 |
| 23 | Roberto Petito | Liquigas | + 02:25 | + 02:25 |
| 24 | Paolo Bettini | Quick Step - Innergetic | + 02:25 | + 02:25 |
| 25 | David Kopp | Gerolsteiner | + 04:22 | + 04:22 |
| 26 | Roger Hammond | T-Mobile Team | + 04:22 | + 04:22 |
| 27 | Michael Schär | Astana | + 04:22 | + 04:22 |
| 28 | Dmitriy Muravyev | Astana | + 04:22 | + 04:22 |
| 29 | Erik Zabel | Team Milram | + 04:22 | + 04:22 |
| 30 | Igor Abakoumov | Astana | + 04:22 | + 04:22 |
| 31 | Gabriele Balducci | Acqua e Sapone | + 04:22 | + 04:22 |
| 32 | Tomas Vaitkus | Discovery Channel | + 04:22 | + 04:22 |
| 33 | Renaud Dion | AG2R Prévoyance | + 04:22 | + 04:22 |
| 34 | Nikolas Maes | Chocolade Jacques - Topsport Vlaand | + 04:22 | + 04:22 |
| 35 | Luke Roberts | Team CSC | + 04:22 | + 04:22 |
| 36 | Fabio Baldato | Lampre-Fondital | + 04:22 | + 04:22 |
| 37 | Jimmy Casper | Unibet.com | + 04:22 | + 04:22 |
| 38 | Maarten den Bakker | Skil - Shimano | + 04:22 | + 04:22 |
| 39 | Bert Roesems | Predictor - Lotto | + 04:22 | + 04:22 |
| 40 | Gianni Meersman | Discovery Channel | + 04:22 | + 04:22 |
| 41 | Léon van Bon | Rabobank | + 04:22 | + 04:22 |
| 42 | Frédéric Guesdon | Française des Jeux | + 04:22 | + 04:22 |
| 43 | Steve Cummings | Discovery Channel | + 04:22 | + 04:22 |
| 44 | Daniele Bennati | Lampre-Fondital | + 04:22 | + 04:22 |
| 45 | Steven de Jongh | Quick Step - Innergetic | + 04:22 | + 04:22 |
| 46 | Leif Hoste | Predictor - Lotto | + 04:27 | + 04:27 |
| 47 | Wim Vansevenant | Predictor - Lotto | + 06:42 | + 06:42 |
| 48 | Wim de Vocht | Predictor - Lotto | + 06:42 | + 06:42 |
| 49 | Gerben Löwik | Rabobank | + 06:42 | + 06:42 |
| 50 | Daniel Lloyd | DFL - Cyclingnews - Litespeed | + 06:42 | + 06:42 |
| 51 | Kevin Hulsmans | Quick Step - Innergetic | + 06:42 | + 06:42 |
| 52 | Sven Krauss | Gerolsteiner | + 11:42 | + 11:42 |
| 53 | Fumiyuki Beppu | Discovery Channel | + 11:42 | + 11:42 |
| 54 | Floris Goesinnen | Skil - Shimano | + 11:42 | + 11:42 |
| 55 | Tom Stamsnijder | Gerolsteiner | + 11:42 | + 11:42 |
| 56 | Niki Terpstra | Team Milram | + 11:42 | + 11:42 |
| 57 | Stefano Cavallari | Acqua e Sapone | + 11:42 | + 11:42 |
| 58 | László Bodrogi | Crédit Agricole | + 11:42 | + 11:42 |
| 59 | Jörg Ludewig | Team Wiesenhof - Felt | + 11:42 | + 11:42 |
| 60 | Bastiaan Giling | Team Wiesenhof - Felt | + 11:42 | + 11:42 |
| 61 | Stefan van Dijk | Team Wiesenhof - Felt | + 11:42 | + 11:42 |
| 62 | Kurt Hovelynck | Chocolade Jacques - Topsport Vlaand | + 11:42 | + 11:42 |
| 63 | Aart Vierhouten | Skil - Shimano | + 11:42 | + 11:42 |
| 64 | Jan Kuyckx | Landbouwkrediet - Tönissteiner | + 11:42 | + 11:42 |
| 65 | Filip Meirhaeghe | Landbouwkrediet - Tönissteiner | + 11:42 | + 11:42 |
| 66 | Vytautas Kaupas | Jartazi - Promo Fashion | + 11:42 | + 11:42 |
| 67 | Thomas Fothen | Gerolsteiner | + 11:42 | + 11:42 |
| 68 | Rony Martias | Bouygues Telecom | + 11:42 | + 11:42 |
| 69 | Franck Renier | Bouygues Telecom | + 11:42 | + 11:42 |
| 70 | Ludovic Auger | Française des Jeux | + 11:42 | + 11:42 |
| 71 | Maarten Tjallingii | Skil - Shimano | + 11:42 | + 11:42 |
| 72 | Bert Grabsch | T-Mobile Team | + 11:42 | + 11:42 |
| 73 | Bernhard Eisel | T-Mobile Team | + 11:42 | + 11:42 |
| 74 | Fabian Wegmann | Gerolsteiner | + 11:42 | + 11:42 |
| 75 | Marcus Ljungqvist | Team CSC | + 11:42 | + 11:42 |
| 76 | Felix Odebrecht | Team Wiesenhof - Felt | + 11:42 | + 11:42 |
| 77 | Matti Breschel | Team CSC | + 11:42 | + 11:42 |
| 78 | Massimiliano Mori | Lampre-Fondital | + 11:42 | + 11:42 |
| 79 | Enrico Franzoi | Lampre-Fondital | + 11:42 | + 11:42 |
| 80 | Martin Müller | Team Milram | + 11:42 | + 11:42 |
| 81 | Enrico Poitschke | Team Milram | + 11:42 | + 11:42 |
| 82 | Vincent Jérôme | Bouygues Telecom | + 11:42 | + 11:42 |
| 83 | Marcel Sieberg | Team Milram | + 11:42 | + 11:42 |
| 84 | Matthew Wilson | Unibet.com | + 11:42 | + 11:42 |
| 85 | Artur Gajek | Team Wiesenhof - Felt | + 11:42 | + 11:42 |
| 86 | Hilton Clarke | Navigators Insurance Cycling Team | + 11:42 | + 11:42 |
| 87 | Nico Mattan | DFL - Cyclingnews - Litespeed | + 11:42 | + 11:42 |
| 88 | Frédéric Amorison | Landbouwkrediet - Tönissteiner | + 11:42 | + 11:42 |
| 89 | Greg van Avermaet | Predictor - Lotto | + 11:42 | + 11:42 |
| 90 | William Bonnet | Crédit Agricole | + 11:42 | + 11:42 |
| 91 | Koen de Kort | Astana | + 11:42 | + 11:42 |
| 92 | Pedro Horrillo | Rabobank | + 11:42 | + 11:42 |
| 93 | Sébastien Hinault | Crédit Agricole | + 11:42 | + 11:42 |
| 94 | Benoit Joachim | Astana | + 11:42 | + 11:42 |
| 95 | Gennady Mikhailov | Astana | + 11:42 | + 11:42 |
| 96 | Daniele Righi | Lampre-Fondital | + 11:42 | + 11:42 |
| 97 | Sébastien Minard | Cofidis | + 11:42 | + 11:42 |
| 98 | Jonathan Hivert | Crédit Agricole | + 11:42 | + 11:42 |
| 99 | Kevin van Impe | Quick Step - Innergetic | + 11:42 | + 11:42 |