| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Asle Arvesen Kurt | Team CSC - Saxo Bank | 04:57:03 | |
| 2 | David Kopp | Cycle Collstrop | + 05 | + 05 |
| 3 | Greg van Avermaet | Silence - Lotto | + 05 | + 05 |
| 4 | Thomas Voeckler | Bouygues Telecom | + 05 | + 05 |
| 5 | Janek Tombak | Mitsubishi - Jartazi | + 05 | + 05 |
| 6 | Bernhard Eisel | Team Columbia | + 26 | + 26 |
| 7 | Matti Breschel | Team CSC - Saxo Bank | + 01:20 | + 01:20 |
| 8 | Tom Boonen | Quick Step | + 01:20 | + 01:20 |
| 9 | Stijn Devolder | Quick Step | + 01:20 | + 01:20 |
| 10 | Staf Scheirlinckx | Cofidis | + 01:20 | + 01:20 |
| 11 | Michael Schär | Astana | + 01:20 | + 01:20 |
| 12 | Lars Bak | Team CSC - Saxo Bank | + 01:20 | + 01:20 |
| 13 | Leif Hoste | Silence - Lotto | + 01:20 | + 01:20 |
| 14 | Maarten Tjallingii | Silence - Lotto | + 01:20 | + 01:20 |
| 15 | Kristof Vandewalle | Topsport Vlaanderen | + 01:26 | + 01:26 |
| 16 | Fabian Cancellara | Team CSC - Saxo Bank | + 03:38 | + 03:38 |
| 17 | Simon Spilak | Lampre | + 03:38 | + 03:38 |
| 18 | Sergei Ivanov | Astana | + 04:15 | + 04:15 |
| 19 | Marcel Sieberg | Team Columbia | + 04:15 | + 04:15 |
| 20 | Tom Veelers | Skil - Shimano | + 04:15 | + 04:15 |
| 21 | Stefan van Dijk | Mitsubishi - Jartazi | + 04:15 | + 04:15 |
| 22 | Mickaël Delage | Française des Jeux | + 04:15 | + 04:15 |
| 23 | Arnaud Gérard | Française des Jeux | + 04:15 | + 04:15 |
| 24 | Gianni Meersman | Française des Jeux | + 04:15 | + 04:15 |
| 25 | Heinrich Haussler | Gerolsteiner | + 04:15 | + 04:15 |
| 26 | Aurelien Clerc | Bouygues Telecom | + 04:15 | + 04:15 |
| 27 | Roy Sentjens | Silence - Lotto | + 04:15 | + 04:15 |
| 28 | Raivis Belohvosciks | Scott - American Beef | + 04:15 | + 04:15 |
| 29 | Koen Barbe | Topsport Vlaanderen | + 04:15 | + 04:15 |
| 30 | Ralf Grabsch | Team Milram | + 04:15 | + 04:15 |
| 31 | Wilfried Cretskens | Quick Step | + 04:15 | + 04:15 |
| 32 | Gabriel Rasch | Crédit Agricole | + 04:15 | + 04:15 |
| 33 | Niki Terpstra | Team Milram | + 04:15 | + 04:15 |
| 34 | Paolo Longo Borghini | Barloworld | + 04:15 | + 04:15 |
| 35 | Gregory Rast | Astana | + 04:15 | + 04:15 |
| 36 | Filippo Pozzato | Liquigas | + 04:15 | + 04:15 |
| 37 | Frédéric Guesdon | Française des Jeux | + 04:15 | + 04:15 |
| 38 | Alessandro Ballan | Lampre | + 04:15 | + 04:15 |
| 39 | Anders Lund | Team CSC - Saxo Bank | + 04:15 | + 04:15 |
| 40 | Erik Zabel | Team Milram | + 04:15 | + 04:15 |
| 41 | Fabio Sabatini | Team Milram | + 04:15 | + 04:15 |
| 42 | Enrico Franzoi | Liquigas | + 04:15 | + 04:15 |
| 43 | Christophe Mengin | Française des Jeux | + 04:15 | + 04:15 |
| 44 | Tristan Valentin | Cofidis | + 04:15 | + 04:15 |
| 45 | Frédéric Amorison | Landbouwkrediet - Tönissteiner | + 04:15 | + 04:15 |
| 46 | Steven de Jongh | Quick Step | + 04:15 | + 04:15 |
| 47 | Marcus Ljungqvist | Team CSC - Saxo Bank | + 04:15 | + 04:15 |
| 48 | Steffen Wesemann | Cycle Collstrop | + 04:15 | + 04:15 |
| 49 | Rik Verbrugghe | Cofidis | + 04:15 | + 04:15 |
| 50 | Andreas Klier | Team Columbia | + 04:15 | + 04:15 |
| 51 | Matteo Tosatto | Quick Step | + 04:15 | + 04:15 |
| 52 | Sven Krauss | Gerolsteiner | + 04:15 | + 04:15 |
| 53 | Bert de Waele | Landbouwkrediet - Tönissteiner | + 04:15 | + 04:15 |
| 54 | David Boucher | Landbouwkrediet - Tönissteiner | + 04:15 | + 04:15 |
| 55 | Antonio Flecha Juan | Rabobank | + 04:15 | + 04:15 |
| 56 | Óscar Freire | Rabobank | + 04:15 | + 04:15 |
| 57 | Joost Posthuma | Rabobank | + 04:15 | + 04:15 |
| 58 | Dmitriy Muravyev | Astana | + 04:15 | + 04:15 |
| 59 | Markus Eichler | Team Milram | + 04:15 | + 04:15 |
| 60 | Ángel Gómez | Scott - American Beef | + 04:15 | + 04:15 |
| 61 | Tomas Vaitkus | Astana | + 04:15 | + 04:15 |
| 62 | Allan Johansen | Team Designa Køkken | + 04:15 | + 04:15 |
| 63 | Stuart O'grady | Team CSC - Saxo Bank | + 04:15 | + 04:15 |
| 64 | Bram Tankink | Rabobank | + 04:15 | + 04:15 |
| 65 | Sebastian Langeveld | Rabobank | + 04:15 | + 04:15 |
| 66 | Christian Knees | Team Milram | + 04:15 | + 04:15 |
| 67 | Gert Steegmans | Quick Step | + 04:15 | + 04:15 |
| 68 | Sébastien Hinault | Crédit Agricole | + 09:29 | + 09:29 |
| 69 | Roy Curvers | Skil - Shimano | + 09:50 | + 09:50 |
| 70 | Maarten den Bakker | Skil - Shimano | + 09:50 | + 09:50 |
| 71 | James Vanlandschoot | Mitsubishi - Jartazi | + 09:50 | + 09:50 |
| 72 | Floris Goesinnen | Skil - Shimano | + 09:50 | + 09:50 |
| 73 | Stijn Vandenbergh | AG2R La Mondiale | + 09:50 | + 09:50 |
| 74 | Wim de Vocht | Silence - Lotto | + 09:50 | + 09:50 |
| 75 | Bastiaan Giling | Cycle Collstrop | + 09:50 | + 09:50 |
| 76 | Matthé Pronk | Cycle Collstrop | + 09:50 | + 09:50 |
| 77 | Kristof de Zutter | Veranda's Willems | + 09:50 | + 09:50 |
| 78 | Jürgen Roelandts | Silence - Lotto | + 09:50 | + 09:50 |
| 79 | Stephan Schreck | Gerolsteiner | + 09:50 | + 09:50 |
| 80 | Fabio Baldato | Lampre | + 09:50 | + 09:50 |
| 81 | Manuel Quinziato | Liquigas | + 09:50 | + 09:50 |
| 82 | Mauro Da Dalto | Liquigas | + 09:50 | + 09:50 |
| 83 | Pedro Horrillo | Rabobank | + 09:50 | + 09:50 |
| 84 | Renaud Dion | AG2R La Mondiale | + 09:50 | + 09:50 |
| 85 | Arnaud Labbe | Bouygues Telecom | + 09:50 | + 09:50 |
| 86 | Nicolas Roche | Crédit Agricole | + 09:50 | + 09:50 |
| 87 | Sergey Lagutin | Cycle Collstrop | + 09:50 | + 09:50 |
| 88 | Max van Heeswijk | Veranda's Willems | + 09:50 | + 09:50 |
| 89 | Wouter Weylandt | Quick Step | + 09:50 | + 09:50 |