| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Tom Boonen | Quick Step | 06:22:00 | |
| 2 | Andreas Klier | Discovery Channel | + 35 | + 35 |
| 3 | Peter van Petegem | Davitamon - Lotto | + 40 | + 40 |
| 4 | Erik Zabel | T-Mobile Team | + 40 | + 40 |
| 5 | Roberto Petito | Fassa Bortolo | + 40 | + 40 |
| 6 | Alessandro Ballan | Lampre-Caffita | + 40 | + 40 |
| 7 | George Hincapie | Discovery Channel | + 01:42 | + 01:42 |
| 8 | Léon van Bon | Davitamon - Lotto | + 01:42 | + 01:42 |
| 9 | Sergei Ivanov | T-Mobile Team | + 01:42 | + 01:42 |
| 10 | Vladimir Gusev | Team CSC | + 01:42 | + 01:42 |
| 11 | Karsten Kroon | Rabobank | + 01:42 | + 01:42 |
| 12 | Antonio Flecha Juan | Fassa Bortolo | + 01:42 | + 01:42 |
| 13 | Bernhard Eisel | Française des Jeux | + 02:04 | + 02:04 |
| 14 | Fabio Baldato | Fassa Bortolo | + 02:04 | + 02:04 |
| 15 | Allan Johansen | Team CSC | + 02:04 | + 02:04 |
| 16 | Stuart O'grady | Cofidis | + 02:04 | + 02:04 |
| 17 | Nico Mattan | Davitamon - Lotto | + 02:04 | + 02:04 |
| 18 | Mirko Celestino | Domina Vacanze | + 02:04 | + 02:04 |
| 19 | Bert de Waele | Landbouwkrediet - Colnago | + 02:04 | + 02:04 |
| 20 | Marcus Ljungqvist | Liquigas - Bianchi | + 02:04 | + 02:04 |
| 21 | Nick Nuyens | Quick Step | + 02:04 | + 02:04 |
| 22 | Frédéric Guesdon | Française des Jeux | + 02:04 | + 02:04 |
| 23 | Leif Hoste | Discovery Channel | + 02:04 | + 02:04 |
| 24 | Erik Dekker | Rabobank | + 02:04 | + 02:04 |
| 25 | Bert Grabsch | Phonak Hearing Systems | + 02:04 | + 02:04 |
| 26 | Marc Lotz | Quick Step | + 02:04 | + 02:04 |
| 27 | Rolf Aldag | T-Mobile Team | + 02:04 | + 02:04 |
| 28 | Lance Armstrong | Discovery Channel | + 02:04 | + 02:04 |
| 29 | Frank Høj | Gerolsteiner | + 03:25 | + 03:25 |
| 30 | Constantino Zaballa | Saunier Duval - Prodir | + 03:25 | + 03:25 |
| 31 | Thor Hushovd | Crédit Agricole | + 03:25 | + 03:25 |
| 32 | Markus Zberg | Gerolsteiner | + 04:32 | + 04:32 |
| 33 | Staf Scheirlinckx | Cofidis | + 04:32 | + 04:32 |
| 34 | Martin Elmiger | Phonak Hearing Systems | + 04:32 | + 04:32 |
| 35 | Stijn Devolder | Discovery Channel | + 04:32 | + 04:32 |
| 36 | Uros Murn | Phonak Hearing Systems | + 06:25 | + 06:25 |
| 37 | Lars Michaelsen | Team CSC | + 06:25 | + 06:25 |
| 38 | Wilfried Cretskens | Quick Step | + 06:25 | + 06:25 |
| 39 | Aart Vierhouten | Davitamon - Lotto | + 06:25 | + 06:25 |
| 40 | Anthony Geslin | Bouygues Telecom | + 06:25 | + 06:25 |
| 41 | Carlos Barredo | Liberty Seguros - Würth Team | + 06:25 | + 06:25 |
| 42 | Iñigo Landaluze | Euskaltel-Euskadi | + 06:25 | + 06:25 |
| 43 | Filippo Pozzato | Quick Step | + 06:25 | + 06:25 |
| 44 | Sebastian Lang | Gerolsteiner | + 06:25 | + 06:25 |
| 45 | Geert Verheyen | Landbouwkrediet - Colnago | + 06:25 | + 06:25 |
| 46 | Steven de Jongh | Rabobank | + 06:25 | + 06:25 |
| 47 | Mathew Hayman | Rabobank | + 06:25 | + 06:25 |
| 48 | Bram Tankink | Quick Step | + 06:25 | + 06:25 |
| 49 | Christophe Detilloux | Française des Jeux | + 06:25 | + 06:25 |
| 50 | Gianluca Bortolami | Lampre-Caffita | + 06:25 | + 06:25 |
| 51 | David Canada | Saunier Duval - Prodir | + 06:25 | + 06:25 |
| 52 | Roger Hammond | Discovery Channel | + 06:25 | + 06:25 |
| 53 | Daniele Bennati | Lampre-Caffita | + 06:25 | + 06:25 |
| 54 | Luke Roberts | Team CSC | + 06:25 | + 06:25 |
| 55 | Marc Wauters | Rabobank | + 06:25 | + 06:25 |
| 56 | Viatcheslav Ekimov | Discovery Channel | + 06:25 | + 06:25 |
| 57 | Tomas Vaitkus | AG2R Prévoyance | + 06:40 | + 06:40 |
| 58 | Peter Wrolich | Gerolsteiner | + 07:40 | + 07:40 |
| 59 | Franck Renier | Bouygues Telecom | + 09:52 | + 09:52 |
| 60 | Axetza Pena Iza | Euskaltel-Euskadi | + 09:52 | + 09:52 |
| 61 | Magnus Bäckstedt | Liquigas - Bianchi | + 10:21 | + 10:21 |
| 62 | Fabian Cancellara | Fassa Bortolo | + 10:21 | + 10:21 |
| 63 | Stephan Schreck | T-Mobile Team | + 10:21 | + 10:21 |
| 64 | Kevin Hulsmans | Quick Step | + 10:21 | + 10:21 |
| 65 | Marcus Burghardt | T-Mobile Team | + 10:21 | + 10:21 |
| 66 | Alexandre Usov | AG2R Prévoyance | + 10:26 | + 10:26 |
| 67 | Johan Coenen | MrBookmaker - Sports Tech | + 11:40 | + 11:40 |
| 68 | Kristof Trouve | MrBookmaker - Sports Tech | + 11:40 | + 11:40 |
| 69 | Andrea Tafi | Saunier Duval - Prodir | + 11:40 | + 11:40 |
| 70 | Gregory Rast | Phonak Hearing Systems | + 13:19 | + 13:19 |
| 71 | Laurent Brochard | Bouygues Telecom | + 13:19 | + 13:19 |
| 72 | Ralf Grabsch | Team Wiesenhof | + 13:19 | + 13:19 |
| 73 | Mirco Lorenzetto | Domina Vacanze | + 13:19 | + 13:19 |
| 74 | Jaan Kirsipuu | Crédit Agricole | + 13:19 | + 13:19 |
| 75 | Rafael Nuritdinov | Domina Vacanze | + 13:19 | + 13:19 |
| 76 | Aurelien Clerc | Phonak Hearing Systems | + 13:19 | + 13:19 |
| 77 | László Bodrogi | Crédit Agricole | + 13:19 | + 13:19 |
| 78 | Andrus Aug | Fassa Bortolo | + 13:19 | + 13:19 |
| 79 | Matej Jurco | Domina Vacanze | + 13:19 | + 13:19 |
| 80 | Mauro Gerosa | Liquigas - Bianchi | + 13:19 | + 13:19 |
| 81 | Bradley Wiggins | Crédit Agricole | + 13:19 | + 13:19 |
| 82 | Ignacio Gutierrez | Phonak Hearing Systems | + 13:19 | + 13:19 |
| 83 | Maarten den Bakker | Rabobank | + 13:19 | + 13:19 |
| 84 | Manuel Quinziato | Saunier Duval - Prodir | + 13:19 | + 13:19 |
| 85 | Erwin Thijs | MrBookmaker - Sports Tech | + 13:19 | + 13:19 |
| 86 | Lars Bak | Team CSC | + 13:19 | + 13:19 |
| 87 | Jimmy Casper | Cofidis | + 13:19 | + 13:19 |
| 88 | Pieter Ghyllebert | Chocolade Jacques - T-Interim | + 13:19 | + 13:19 |
| 89 | Heinrich Haussler | Gerolsteiner | + 13:19 | + 13:19 |
| 90 | David Boucher | MrBookmaker - Sports Tech | + 13:19 | + 13:19 |
| 91 | Christophe Mengin | Française des Jeux | + 13:19 | + 13:19 |
| 92 | Simon Gerrans | AG2R Prévoyance | + 13:19 | + 13:19 |
| 93 | Wim de Vocht | Davitamon - Lotto | + 13:19 | + 13:19 |
| 94 | Gianluca Sironi | Liquigas - Bianchi | + 13:19 | + 13:19 |
| 95 | Matthé Pronk | MrBookmaker - Sports Tech | + 13:19 | + 13:19 |
| 96 | Erki Pütsep | AG2R Prévoyance | + 13:19 | + 13:19 |
| 97 | Johan Verstrepen | Landbouwkrediet - Colnago | + 13:19 | + 13:19 |
| 98 | Jan Boven | Rabobank | + 13:19 | + 13:19 |
| 99 | Wesley van der Linden | Chocolade Jacques - T-Interim | + 13:19 | + 13:19 |
| 100 | Kevin van Impe | Chocolade Jacques - T-Interim | + 13:19 | + 13:19 |