| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Stijn Devolder | Quick Step | 06:24:02 | |
| 2 | Nick Nuyens | Cofidis | + 15 | + 15 |
| 3 | Antonio Flecha Juan | Rabobank | + 15 | + 15 |
| 4 | Alessandro Ballan | Lampre | + 21 | + 21 |
| 5 | George Hincapie | Team Columbia | + 21 | + 21 |
| 6 | Filippo Pozzato | Liquigas | + 21 | + 21 |
| 7 | Asle Arvesen Kurt | Team CSC - Saxo Bank | + 21 | + 21 |
| 8 | Greg van Avermaet | Silence - Lotto | + 21 | + 21 |
| 9 | Simon Spilak | Lampre | + 21 | + 21 |
| 10 | Allan Johansen | Team Designa Køkken | + 21 | + 21 |
| 11 | Bernhard Eisel | Team Columbia | + 21 | + 21 |
| 12 | Martijn Maaskant | Garmin-Chipotle p/b H30 | + 21 | + 21 |
| 13 | Gregory Rast | Astana | + 21 | + 21 |
| 14 | Niki Terpstra | Team Milram | + 21 | + 21 |
| 15 | Philippe Gilbert | Française des Jeux | + 21 | + 21 |
| 16 | Dmitriy Muravyev | Astana | + 21 | + 21 |
| 17 | Tom Boonen | Quick Step | + 21 | + 21 |
| 18 | Sebastian Langeveld | Rabobank | + 21 | + 21 |
| 19 | Leif Hoste | Silence - Lotto | + 21 | + 21 |
| 20 | Andreas Klier | Team Columbia | + 21 | + 21 |
| 21 | Maarten Tjallingii | Silence - Lotto | + 21 | + 21 |
| 22 | Martin Elmiger | AG2R La Mondiale | + 21 | + 21 |
| 23 | Fabian Cancellara | Team CSC - Saxo Bank | + 21 | + 21 |
| 24 | Carlos Barredo | Quick Step | + 21 | + 21 |
| 25 | Janek Tombak | Mitsubishi - Jartazi | + 21 | + 21 |
| 26 | Frédéric Guesdon | Française des Jeux | + 43 | + 43 |
| 27 | Thor Hushovd | Crédit Agricole | + 03:18 | + 03:18 |
| 28 | Kurt Hovelynck | Topsport Vlaanderen | + 03:18 | + 03:18 |
| 29 | Pedro Horrillo | Rabobank | + 03:18 | + 03:18 |
| 30 | Sylvain Chavanel | Cofidis | + 03:18 | + 03:18 |
| 31 | Rik Verbrugghe | Cofidis | + 03:18 | + 03:18 |
| 32 | Roger Hammond | Team Columbia | + 03:18 | + 03:18 |
| 33 | Christophe Mengin | Française des Jeux | + 03:18 | + 03:18 |
| 34 | Allan Davis | Mitsubishi - Jartazi | + 03:18 | + 03:18 |
| 35 | Bert de Waele | Landbouwkrediet - Tönissteiner | + 03:18 | + 03:18 |
| 36 | Sergei Ivanov | Astana | + 03:18 | + 03:18 |
| 37 | Manuel Quinziato | Liquigas | + 03:18 | + 03:18 |
| 38 | Marco Marcato | Cycle Collstrop | + 03:18 | + 03:18 |
| 39 | Bram Tankink | Rabobank | + 03:18 | + 03:18 |
| 40 | Óscar Freire | Rabobank | + 03:18 | + 03:18 |
| 41 | Karsten Kroon | Team CSC - Saxo Bank | + 03:29 | + 03:29 |
| 42 | David Kopp | Cycle Collstrop | + 09:14 | + 09:14 |
| 43 | Magnus Bäckstedt | Garmin-Chipotle p/b H30 | + 09:14 | + 09:14 |
| 44 | Peter Wrolich | Gerolsteiner | + 09:14 | + 09:14 |
| 45 | Kevin de Weert | Cofidis | + 09:14 | + 09:14 |
| 46 | Frederik Willems | Liquigas | + 09:14 | + 09:14 |
| 47 | Roy Sentjens | Silence - Lotto | + 09:14 | + 09:14 |
| 48 | Vicente Reynès | Team Columbia | + 09:14 | + 09:14 |
| 49 | Michal Golas | Cycle Collstrop | + 09:14 | + 09:14 |
| 50 | José Oroz Juan | Euskaltel-Euskadi | + 09:14 | + 09:14 |
| 51 | Bastiaan Giling | Cycle Collstrop | + 09:14 | + 09:14 |
| 52 | Floris Goesinnen | Skil - Shimano | + 09:14 | + 09:14 |
| 53 | Ralf Grabsch | Team Milram | + 09:14 | + 09:14 |
| 54 | Tyler Farrar | Garmin-Chipotle p/b H30 | + 09:14 | + 09:14 |
| 55 | Frank Høj | Cofidis | + 09:14 | + 09:14 |
| 56 | Staf Scheirlinckx | Cofidis | + 09:14 | + 09:14 |
| 57 | Paolo Longo Borghini | Barloworld | + 09:14 | + 09:14 |
| 58 | Matti Breschel | Team CSC - Saxo Bank | + 09:14 | + 09:14 |
| 59 | Gennady Mikhailov | Mitsubishi - Jartazi | + 09:14 | + 09:14 |
| 60 | Matteo Tosatto | Quick Step | + 09:14 | + 09:14 |
| 61 | Gert Steegmans | Quick Step | + 09:14 | + 09:14 |
| 62 | Fabio Baldato | Lampre | + 10:55 | + 10:55 |
| 63 | Baden Cooke | Barloworld | + 14:55 | + 14:55 |
| 64 | Bert Grabsch | Team Columbia | + 15:14 | + 15:14 |
| 65 | Vicente García José | Caisse d'Epargne | + 17:35 | + 17:35 |
| 66 | Ermanno Capelli | Scott - American Beef | + 17:35 | + 17:35 |
| 67 | Aleksandr Kuschynski | Liquigas | + 17:35 | + 17:35 |
| 68 | Erik Zabel | Team Milram | + 17:35 | + 17:35 |
| 69 | Jan Kuyckx | Landbouwkrediet - Tönissteiner | + 17:35 | + 17:35 |
| 70 | Marcel Sieberg | Team Columbia | + 17:35 | + 17:35 |
| 71 | Geert Verheyen | Mitsubishi - Jartazi | + 17:35 | + 17:35 |
| 72 | Christian Knees | Team Milram | + 17:35 | + 17:35 |
| 73 | Ian Stannard | Landbouwkrediet - Tönissteiner | + 17:35 | + 17:35 |
| 74 | Imanol Erviti | Caisse d'Epargne | + 17:35 | + 17:35 |
| 75 | Stijn Vandenbergh | AG2R La Mondiale | + 17:35 | + 17:35 |
| 76 | Jesus Del Nero Montes | Scott - American Beef | + 17:35 | + 17:35 |
| 77 | René Haselbacher | Astana | + 17:35 | + 17:35 |
| 78 | László Bodrogi | Crédit Agricole | + 17:35 | + 17:35 |
| 79 | Luciano Pagliarini | Scott - American Beef | + 17:35 | + 17:35 |
| 80 | Mathieu Drujon | Caisse d'Epargne | + 17:35 | + 17:35 |
| 81 | Preben van Hecke | Topsport Vlaanderen | + 17:35 | + 17:35 |
| 82 | Ryder Hesjedal | Garmin-Chipotle p/b H30 | + 17:35 | + 17:35 |
| 83 | Patrick Calcagni | Barloworld | + 17:35 | + 17:35 |
| 84 | Paolo Fornaciari | Lampre | + 17:35 | + 17:35 |
| 85 | Marco Bandiera | Lampre | + 17:35 | + 17:35 |
| 86 | Marcus Ljungqvist | Team CSC - Saxo Bank | + 17:35 | + 17:35 |
| 87 | Markel Irizar | Euskaltel-Euskadi | + 17:35 | + 17:35 |
| 88 | Yoann Offredo | Française des Jeux | + 17:35 | + 17:35 |
| 89 | Mirko Selvaggi | Cycle Collstrop | + 17:35 | + 17:35 |
| 90 | Murilo Fischer | Liquigas | + 17:35 | + 17:35 |
| 91 | Heinrich Haussler | Gerolsteiner | + 17:35 | + 17:35 |
| 92 | Sven Krauss | Gerolsteiner | + 17:35 | + 17:35 |
| 93 | Fabio Sabatini | Team Milram | + 17:35 | + 17:35 |
| 94 | Alexandre Pichot | Bouygues Telecom | + 17:35 | + 17:35 |
| 95 | Matthieu Ladagnous | Française des Jeux | + 17:35 | + 17:35 |
| 96 | Mickaël Delage | Française des Jeux | + 17:35 | + 17:35 |
| 97 | Wim de Vocht | Silence - Lotto | + 17:35 | + 17:35 |
| 98 | Wim Vansevenant | Silence - Lotto | + 17:35 | + 17:35 |
| 99 | Sébastien Minard | Cofidis | + 17:35 | + 17:35 |
| 100 | Maarten Wynants | Quick Step | + 17:35 | + 17:35 |
| 101 | Wilfried Cretskens | Quick Step | + 17:35 | + 17:35 |