| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | 06:21:32 | |
| 2 | Paolo Bettini | Quick Step - Innergetic | + 00 | |
| 3 | Damiano Cunego | Lampre-Fondital | + 00 | |
| 4 | Patrik Sinkewitz | T-Mobile Team | + 00 | |
| 5 | Michael Boogerd | Rabobank | + 00 | |
| 6 | Ángel Martin Miguel | Phonak Hearing Systems | + 00 | |
| 7 | Fränk Schleck | Team CSC | + 00 | |
| 8 | Chris Horner | Davitamon - Lotto | + 00 | |
| 9 | Danilo Di Luca | Liquigas | + 04 | + 04 |
| 10 | Ivan Basso | Team CSC | + 07 | + 07 |
| 11 | Andrey Kashechkin | Astana - Würth Team | + 12 | + 12 |
| 12 | Joaquim Rodríguez | Caisse d'Epargne - Illes Balears | + 24 | + 24 |
| 13 | David Etxebarria | Astana - Würth Team | + 28 | + 28 |
| 14 | Óscar Freire | Rabobank | + 29 | + 29 |
| 15 | Samuel Sánchez | Euskaltel-Euskadi | + 31 | + 31 |
| 16 | Franco Pellizotti | Liquigas | + 31 | + 31 |
| 17 | Andriy Grivko | Team Milram | + 31 | + 31 |
| 18 | Karsten Kroon | Team CSC | + 31 | + 31 |
| 19 | Alessandro Ballan | Lampre-Fondital | + 31 | + 31 |
| 20 | Thomas Dekker | Rabobank | + 31 | + 31 |
| 21 | Igor Astarloa | Barloworld | + 31 | + 31 |
| 22 | Gilberto Simoni | Saunier Duval - Prodir | + 45 | + 45 |
| 23 | Iban Mayo | Euskaltel-Euskadi | + 47 | + 47 |
| 24 | Matthias Kessler | T-Mobile Team | + 51 | + 51 |
| 25 | Pedro Arreitunandia | Barloworld | + 57 | + 57 |
| 26 | Giuliano Figueras | Lampre-Fondital | + 01:18 | + 01:18 |
| 27 | Francesco Bellotti | Crédit Agricole | + 01:21 | + 01:21 |
| 28 | Fabian Wegmann | Gerolsteiner | + 01:21 | + 01:21 |
| 29 | Gorazd Stangelj | Lampre-Fondital | + 01:21 | + 01:21 |
| 30 | Alexandre Vinokourov | Astana - Würth Team | + 01:31 | + 01:31 |
| 31 | Leonardo Bertagnolli | Cofidis | + 01:31 | + 01:31 |
| 32 | Stefano Garzelli | Liquigas | + 02:13 | + 02:13 |
| 33 | Axel Merckx | Phonak Hearing Systems | + 04:29 | + 04:29 |
| 34 | Didier Rous | Bouygues Telecom | + 04:33 | + 04:33 |
| 35 | Francisco Mancebo | AG2R Prévoyance | + 04:33 | + 04:33 |
| 36 | Ruben Lobato | Saunier Duval - Prodir | + 04:33 | + 04:33 |
| 37 | Vladimir Gusev | Discovery Channel | + 04:33 | + 04:33 |
| 38 | Philippe Gilbert | Française des Jeux | + 04:33 | + 04:33 |
| 39 | Eddy Mazzoleni | T-Mobile Team | + 04:33 | + 04:33 |
| 40 | Iker Camaño | Euskaltel-Euskadi | + 04:33 | + 04:33 |
| 41 | Björn Leukemans | Davitamon - Lotto | + 04:33 | + 04:33 |
| 42 | Serge Baguet | Quick Step - Innergetic | + 04:33 | + 04:33 |
| 43 | Bram Tankink | Quick Step - Innergetic | + 04:33 | + 04:33 |
| 44 | Jörg Jaksche | Astana - Würth Team | + 04:33 | + 04:33 |
| 45 | José Cobo Juan | Saunier Duval - Prodir | + 05:26 | + 05:26 |
| 46 | Sylvain Chavanel | Cofidis | + 06:58 | + 06:58 |
| 47 | Pietro Caucchioli | Crédit Agricole | + 07:31 | + 07:31 |
| 48 | Giampaolo Cheula | Barloworld | + 07:31 | + 07:31 |
| 49 | Dmitriy Fofonov | Crédit Agricole | + 09:53 | + 09:53 |
| 50 | Manuel Garate Juan | Quick Step - Innergetic | + 10:51 | + 10:51 |
| 51 | Jens Voigt | Team CSC | + 10:51 | + 10:51 |
| 52 | Christophe Moreau | AG2R Prévoyance | + 11:00 | + 11:00 |
| 53 | Beat Zberg | Gerolsteiner | + 11:00 | + 11:00 |
| 54 | Constantino Zaballa | Caisse d'Epargne - Illes Balears | + 11:00 | + 11:00 |
| 55 | David de La Fuente | Saunier Duval - Prodir | + 11:00 | + 11:00 |
| 56 | Erik Dekker | Rabobank | + 11:00 | + 11:00 |
| 57 | Luis Arrieta José | AG2R Prévoyance | + 11:00 | + 11:00 |
| 58 | Christophe Laurent | Agritubel | + 11:00 | + 11:00 |
| 59 | Walter Bénéteau | Bouygues Telecom | + 11:00 | + 11:00 |
| 60 | Alexandr Kolobnev | Rabobank | + 11:00 | + 11:00 |
| 61 | Johan Vansummeren | Davitamon - Lotto | + 11:00 | + 11:00 |
| 62 | Steve Zamperi | Phonak Hearing Systems | + 11:00 | + 11:00 |
| 63 | Maxim Iglinskiy | Team Milram | + 11:00 | + 11:00 |
| 64 | Joost Posthuma | Rabobank | + 11:00 | + 11:00 |
| 65 | Cédric Vasseur | Quick Step - Innergetic | + 11:00 | + 11:00 |
| 66 | Christophe Brandt | Davitamon - Lotto | + 11:00 | + 11:00 |
| 67 | Thomas Löfkvist | Française des Jeux | + 11:00 | + 11:00 |
| 68 | Mario Aerts | Davitamon - Lotto | + 11:00 | + 11:00 |
| 69 | Rik Verbrugghe | Cofidis | + 11:00 | + 11:00 |
| 70 | Pierrick Fedrigo | Bouygues Telecom | + 11:00 | + 11:00 |
| 71 | Laurens ten Dam | Unibet.com | + 11:00 | + 11:00 |
| 72 | Stéphane Goubert | AG2R Prévoyance | + 11:00 | + 11:00 |
| 73 | Matej Mugerli | Liquigas | + 11:00 | + 11:00 |
| 74 | José Azevedo | Discovery Channel | + 11:00 | + 11:00 |
| 75 | Rémi Pauriol | Crédit Agricole | + 11:00 | + 11:00 |
| 76 | Tadej Valjavec | Lampre-Fondital | + 11:00 | + 11:00 |
| 77 | Thierry Marichal | Cofidis | + 11:00 | + 11:00 |
| 78 | Bert de Waele | Landbouwkrediet - Colnago | + 11:00 | + 11:00 |
| 79 | Salvatore Commesso | Lampre-Fondital | + 11:00 | + 11:00 |
| 80 | Cadel Evans | Davitamon - Lotto | + 11:00 | + 11:00 |
| 81 | Alberto Contador | Astana - Würth Team | + 11:00 | + 11:00 |
| 82 | Angel Vicioso | Astana - Würth Team | + 11:00 | + 11:00 |
| 83 | Uros Murn | Phonak Hearing Systems | + 11:00 | + 11:00 |
| 84 | Evgeni Petrov | Lampre-Fondital | + 11:00 | + 11:00 |
| 85 | Antonio Flecha Juan | Rabobank | + 11:00 | + 11:00 |
| 86 | Benoît Salmon | Agritubel | + 11:00 | + 11:00 |
| 87 | Steve Morabito | Phonak Hearing Systems | + 16:36 | + 16:36 |
| 88 | Benoit Joachim | Discovery Channel | + 17:25 | + 17:25 |
| 89 | Maarten den Bakker | Team Milram | + 17:25 | + 17:25 |
| 90 | Johan Coenen | Unibet.com | + 17:25 | + 17:25 |
| 91 | Serge Pauwels | Chocolade Jacques - Topsport Vlaand | + 17:25 | + 17:25 |
| 92 | Christophe Le Mével | Crédit Agricole | + 17:25 | + 17:25 |
| 93 | Josep Jufré | Davitamon - Lotto | + 17:25 | + 17:25 |
| 94 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 17:25 | + 17:25 |
| 95 | Jérôme Pineau | Bouygues Telecom | + 17:25 | + 17:25 |
| 96 | Patrick Calcagni | Liquigas | + 17:25 | + 17:25 |
| 97 | Ryan Cox | Barloworld | + 17:25 | + 17:25 |
| 98 | Steven Kleynen | Landbouwkrediet - Colnago | + 17:25 | + 17:25 |
| 99 | Iñaki Isasi | Euskaltel-Euskadi | + 17:25 | + 17:25 |
| 100 | Michael Rogers | T-Mobile Team | + 17:25 | + 17:25 |
| 101 | Carlos Sastre | Team CSC | + 17:25 | + 17:25 |
| 102 | Antonio Serrano Marcos | Astana - Würth Team | + 17:25 | + 17:25 |
| 103 | Addy Engels | Quick Step - Innergetic | + 17:25 | + 17:25 |
| 104 | Matej Jurco | Team Milram | + 17:25 | + 17:25 |
| 105 | Frederic Finot | Française des Jeux | + 17:25 | + 17:25 |