| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Francisco Pérez | Caisse d'Epargne - Illes Balears | 04:16:41 | |
| 2 | Ricardo Serrano | Kaiku | + 07 | + 07 |
| 3 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 07 | + 07 |
| 4 | Allan Davis | Astana - Würth Team | + 19 | + 19 |
| 5 | Francisco Ventoso | Saunier Duval - Prodir | + 19 | + 19 |
| 6 | Heinrich Haussler | Gerolsteiner | + 20 | + 20 |
| 7 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | + 20 | + 20 |
| 8 | Damiano Cunego | Lampre-Fondital | + 20 | + 20 |
| 9 | Adrian Palomares | Kaiku | + 20 | + 20 |
| 10 | Dionisio Galparsoro | Kaiku | + 20 | + 20 |
| 11 | Aitor Galdos | Ceramica Panaria - Navigare | + 20 | + 20 |
| 12 | Peter Wrolich | Gerolsteiner | + 20 | + 20 |
| 13 | Javier Benitez | Grupo Nicolas Mateos | + 20 | + 20 |
| 14 | Iván Gutiérrez | Caisse d'Epargne - Illes Balears | + 20 | + 20 |
| 15 | Luis Pasamontes | Unibet.com | + 20 | + 20 |
| 16 | Carlos Dominguez Juan | Unibet.com | + 20 | + 20 |
| 17 | Giuliano Figueras | Lampre-Fondital | + 20 | + 20 |
| 18 | Juan Olmo | Andalucia - Paul Versan | + 20 | + 20 |
| 19 | Laurens ten Dam | Unibet.com | + 20 | + 20 |
| 20 | Cayetano Juliá José | Caisse d'Epargne - Illes Balears | + 20 | + 20 |
| 21 | Antonio Banos Ballester Jose | 3 Molinos Resort | + 20 | + 20 |
| 22 | Antonio Pecharroman Jose | Comunidad Valenciana | + 20 | + 20 |
| 23 | Sylwester Szmyd | Lampre-Fondital | + 28 | + 28 |
| 24 | Thorwald Veneberg | Rabobank | + 28 | + 28 |
| 25 | Carlos Garcia Quesada | Unibet.com | + 28 | + 28 |
| 26 | Francisco Cabello | Andalucia - Paul Versan | + 37 | + 37 |
| 27 | José Casas Claudio | Comunidad Valenciana | + 01:03 | + 01:03 |
| 28 | Ángel Edo | Andalucia - Paul Versan | + 01:13 | + 01:13 |
| 29 | Beat Zberg | Gerolsteiner | + 01:17 | + 01:17 |
| 30 | Jose Terciado Francisco | Relax - GAM | + 01:37 | + 01:37 |
| 31 | Javier Ramirez | Astana - Würth Team | + 03:16 | + 03:16 |
| 32 | David Etxebarria | Astana - Würth Team | + 03:16 | + 03:16 |
| 33 | Angel Vicioso | Astana - Würth Team | + 03:16 | + 03:16 |
| 34 | Michael Rasmussen | Rabobank | + 03:16 | + 03:16 |
| 35 | David de La Fuente | Saunier Duval - Prodir | + 04:54 | + 04:54 |
| 36 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 04:54 | + 04:54 |
| 37 | Antonio Serrano Marcos | Astana - Würth Team | + 05:31 | + 05:31 |
| 38 | Alexandr Kolobnev | Rabobank | + 06:44 | + 06:44 |
| 39 | Marco Marzano | Lampre-Fondital | + 06:44 | + 06:44 |
| 40 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 06:44 | + 06:44 |
| 41 | Raul Garcia de Mateos | Relax - GAM | + 06:44 | + 06:44 |
| 42 | Fernando Serrano | Kaiku | + 08:53 | + 08:53 |
| 43 | Nacor Burgos | Relax - GAM | + 08:53 | + 08:53 |
| 44 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 08:53 | + 08:53 |
| 45 | Pieter Weening | Rabobank | + 08:53 | + 08:53 |
| 46 | Carlos Abellan Ossenbach | Astana - Würth Team | + 08:53 | + 08:53 |
| 47 | Theo Eltink | Rabobank | + 08:53 | + 08:53 |
| 48 | José Martínez Francisco | Andalucia - Paul Versan | + 08:53 | + 08:53 |
| 49 | Georg Totschnig | Gerolsteiner | + 08:53 | + 08:53 |
| 50 | Manuel Ortega | Andalucia - Paul Versan | + 08:53 | + 08:53 |
| 51 | Mikel Pradera | Caisse d'Epargne - Illes Balears | + 08:53 | + 08:53 |
| 52 | Manuel Vazquez | Andalucia - Paul Versan | + 08:53 | + 08:53 |
| 53 | Ignacio Sarabia | Spiuk - Extremadura | + 08:53 | + 08:53 |
| 54 | Juan Gomis Lopez | Comunidad Valenciana | + 08:53 | + 08:53 |
| 55 | Oscar Garcia-casarrubios | Relax - GAM | + 08:53 | + 08:53 |
| 56 | Ivan Santos Martinez | Astana - Würth Team | + 08:53 | + 08:53 |
| 57 | Vicente Peiro Marqueno | Comunidad Valenciana | + 08:53 | + 08:53 |
| 58 | Ezequiel Mosquera | Comunidad Valenciana | + 08:53 | + 08:53 |
| 59 | Carlos Fernandez Mora Juan | Grupo Nicolas Mateos | + 10:14 | + 10:14 |
| 60 | Kurt van de Wouwer | Unibet.com | + 10:14 | + 10:14 |
| 61 | Frédéric Gabriel | Unibet.com | + 10:14 | + 10:14 |
| 62 | Ruben Lorca Jimenez | 3 Molinos Resort | + 10:14 | + 10:14 |