| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | José Haedo Juan | Team CSC - Saxo Bank | 04:22:46 | |
| 2 | Óscar Freire | Rabobank | + 00 | |
| 3 | Graeme Brown | Rabobank | + 00 | |
| 4 | Koldo Fernandez | Euskaltel-Euskadi | + 00 | |
| 5 | Joaquin Rojas José | Caisse d'Epargne | + 00 | |
| 6 | Giuseppe Palumbo | Acqua e Sapone - Caffe Mokambo | + 00 | |
| 7 | Francisco Ventoso | Andalucia - Cajasur | + 00 | |
| 8 | Edgar Pinto | Benfica | + 00 | |
| 9 | Francisco Mourón Juan | Xacobeo-Galicia | + 00 | |
| 10 | Rafael Rodriguez Segarra | Contentpolis - Murcia | + 00 | |
| 11 | Nikolai Trusov | Tinkoff Credit Systems | + 00 | |
| 12 | Xabat Ochotorena | Extremadura | + 00 | |
| 13 | Massimiliano Gentili | Acqua e Sapone - Caffe Mokambo | + 00 | |
| 14 | Alexander Serov | Tinkoff Credit Systems | + 00 | |
| 15 | Arnaud Coyot | Caisse d'Epargne | + 00 | |
| 16 | Rui Costa | Benfica | + 00 | |
| 17 | Matthieu Sprick | Bouygues Telecom | + 00 | |
| 18 | Pablo Urtasun | Liberty Seguros | + 00 | |
| 19 | Antunes Quiterio Cesar | Liberty Seguros | + 00 | |
| 20 | Pedro Goncalves | Benfica | + 00 | |
| 21 | Jesus Rosendo Prado | Andalucia - Cajasur | + 00 | |
| 22 | Diego Milan | Acqua e Sapone - Caffe Mokambo | + 00 | |
| 23 | Francisco Pérez | Caisse d'Epargne | + 00 | |
| 24 | Alexander Khatuntsev | Tinkoff Credit Systems | + 00 | |
| 25 | Serafín Martinez | Xacobeo-Galicia | + 00 | |
| 26 | Gustavo Veloso | Xacobeo-Galicia | + 00 | |
| 27 | Aitor Perez Arrieta | Extremadura | + 00 | |
| 28 | Manuel Ortega | Andalucia - Cajasur | + 00 | |
| 29 | Mikel Pradera | Benfica | + 00 | |
| 30 | Jaume Rovira | Extremadura | + 00 | |
| 31 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 32 | Rafael Serrano Fernandez | Contentpolis - Murcia | + 00 | |
| 33 | Oscar Pujol | Burgos Monumental | + 00 | |
| 34 | Eladio Sánchez | Orbea - Oreka SDA | + 00 | |
| 35 | Yury Trofimov | Bouygues Telecom | + 00 | |
| 36 | Rui Sousa | Liberty Seguros | + 00 | |
| 37 | Walter Pedraza | Tinkoff Credit Systems | + 00 | |
| 38 | Evgeni Petrov | Tinkoff Credit Systems | + 00 | |
| 39 | Pablo Lastras | Caisse d'Epargne | + 00 | |
| 40 | Ruben Reig Conejero | Contentpolis - Murcia | + 00 | |
| 41 | Iván Melero | Orbea - Oreka SDA | + 00 | |
| 42 | Pedro Gutierrez Alvarez | Burgos Monumental | + 00 | |
| 43 | Pedro Horrillo | Rabobank | + 00 | |
| 44 | Vasil Kiryienka | Tinkoff Credit Systems | + 00 | |
| 45 | Vicente Toribio Jose | Burgos Monumental | + 00 | |
| 46 | Luis Pasamontes | Caisse d'Epargne | + 00 | |
| 47 | Hélder Miranda | Benfica | + 00 | |
| 48 | Michael Blaudzun | Team CSC - Saxo Bank | + 00 | |
| 49 | Raul Santamarta Valvuena | Burgos Monumental | + 00 | |
| 50 | Mikel Astarloza | Euskaltel-Euskadi | + 00 | |
| 51 | Jorge Azanza | Euskaltel-Euskadi | + 00 | |
| 52 | Dario Andriotto | Acqua e Sapone - Caffe Mokambo | + 00 | |
| 53 | Massimo Codol | Acqua e Sapone - Caffe Mokambo | + 00 | |
| 54 | Nuno Ribeiro | Liberty Seguros | + 00 | |
| 55 | Campo Jesus Antonio Manuel | Liberty Seguros | + 00 | |
| 56 | David Martin | Orbea - Oreka SDA | + 00 | |
| 57 | Hernani Broco | Liberty Seguros | + 00 | |
| 58 | Antonio Piedra | Andalucia - Cajasur | + 00 | |
| 59 | Stef Clement | Bouygues Telecom | + 00 | |
| 60 | Jonathan Castroviejo | Orbea - Oreka SDA | + 00 | |
| 61 | Avelino Antuna Coro Andres | Burgos Monumental | + 00 | |
| 62 | Joan Horrach | Caisse d'Epargne | + 00 | |
| 63 | Samuel Sánchez | Euskaltel-Euskadi | + 00 | |
| 64 | Mikel Nieve | Orbea - Oreka SDA | + 00 | |
| 65 | Eduard Vorganov | Xacobeo-Galicia | + 00 | |
| 66 | Jorge Sanchez Pimienta | Contentpolis - Murcia | + 00 | |
| 67 | Denis Menchov | Rabobank | + 00 | |
| 68 | Jose Terciado Francisco | Extremadura | + 00 | |
| 69 | Javier Ramirez Torres Jesus | Extremadura | + 00 | |
| 70 | José Rujano | Caisse d'Epargne | + 00 | |
| 71 | Alberto Rodriguez | Contentpolis - Murcia | + 00 | |
| 72 | David Francisco Delgado | Burgos Monumental | + 00 | |
| 73 | Ignacio Sarabia | Extremadura | + 00 | |
| 74 | Jose Mendes | Benfica | + 14 | + 14 |
| 75 | Koldo Gil | Liberty Seguros | + 14 | + 14 |
| 76 | Adrian Palomares | Contentpolis - Murcia | + 14 | + 14 |
| 77 | Danail Petrov | Benfica | + 14 | + 14 |
| 78 | Jurgen van Goolen | Team CSC - Saxo Bank | + 14 | + 14 |
| 79 | Jon Bru | Euskaltel-Euskadi | + 14 | + 14 |
| 80 | Vladimir Isaichev | Xacobeo-Galicia | + 14 | + 14 |
| 81 | Roman Troncoso | Xacobeo-Galicia | + 14 | + 14 |
| 82 | Bram de Groot | Rabobank | + 14 | + 14 |
| 83 | Alexandr Kolobnev | Team CSC - Saxo Bank | + 14 | + 14 |
| 84 | Serguei Klimov | Tinkoff Credit Systems | + 14 | + 14 |
| 85 | Iñaki Isasi | Euskaltel-Euskadi | + 14 | + 14 |
| 86 | Carlos Sastre | Team CSC - Saxo Bank | + 14 | + 14 |
| 87 | Íñigo Cuesta | Team CSC - Saxo Bank | + 14 | + 14 |
| 88 | Antonio Lopez Gil Jose | Andalucia - Cajasur | + 14 | + 14 |
| 89 | Mario Costa | Benfica | + 35 | + 35 |
| 90 | Javier Iriarte | Burgos Monumental | + 35 | + 35 |
| 91 | Gonzalo Rabuñal | Xacobeo-Galicia | + 35 | + 35 |
| 92 | Alejandro Paleo | Xacobeo-Galicia | + 35 | + 35 |
| 93 | Francesco Masciarelli | Acqua e Sapone - Caffe Mokambo | + 35 | + 35 |
| 94 | Kasper Klostergaard | Team CSC - Saxo Bank | + 35 | + 35 |
| 95 | Bradley Mcgee | Team CSC - Saxo Bank | + 41 | + 41 |
| 96 | Javier Moreno | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 97 | Enrique Mata Cabello | Burgos Monumental | + 01:22 | + 01:22 |
| 98 | Josu Agirre Asegniloaza | Euskaltel-Euskadi | + 01:38 | + 01:38 |
| 99 | Oleg Chuzhda | Contentpolis - Murcia | + 02:29 | + 02:29 |
| 100 | Antonio Carrasco Jose | Andalucia - Cajasur | + 02:38 | + 02:38 |
| 101 | Ivan Velasco | Euskaltel-Euskadi | + 03:03 | + 03:03 |
| 102 | Josu Mondelo Diaz | Extremadura | + 03:14 | + 03:14 |
| 103 | Ricardo Serrano | Tinkoff Credit Systems | + 03:17 | + 03:17 |
| 104 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 03:17 | + 03:17 |
| 105 | Branislau Samoilau | Acqua e Sapone - Caffe Mokambo | + 03:17 | + 03:17 |
| 106 | Carlos Torrent | Extremadura | + 04:14 | + 04:14 |