| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Theo Bos | Rabobank | 04:22:53 | |
| 2 | Mark Cavendish | Team HTC - Columbia | + 00 | |
| 3 | Graeme Brown | Rabobank | + 00 | |
| 4 | León Sánchez Luis | Caisse d'Epargne | + 00 | |
| 5 | Davide Appollonio | Cervelo TestTeam | + 00 | |
| 6 | Michal Golas | Vacansoleil | + 00 | |
| 7 | Martin Montenegro Adaro Jorge | Andalucía - Cajasur | + 00 | |
| 8 | Daniel Moreno | Omega Pharma-Lotto | + 00 | |
| 9 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 00 | |
| 10 | Jan Bakelants | Omega Pharma-Lotto | + 00 | |
| 11 | Rodrigo Garcia Rena | Xacobeo-Galicia | + 00 | |
| 12 | Matteo Carrara | Vacansoleil | + 00 | |
| 13 | Bartlomiej Matysiak | CCC Polsat Polkowice | + 00 | |
| 14 | Aleksejs Saramotins | Team HTC - Columbia | + 00 | |
| 15 | Sergey Lagutin | Vacansoleil | + 00 | |
| 16 | Mauricio Ardila | Rabobank | + 00 | |
| 17 | Mikel Landa | Orbea | + 00 | |
| 18 | Rob Ruijgh | Vacansoleil | + 00 | |
| 19 | Gustavo Dominguez Lemos | Xacobeo-Galicia | + 00 | |
| 20 | Christophe Brandt | Omega Pharma-Lotto | + 00 | |
| 21 | Jurgen van Goolen | Omega Pharma-Lotto | + 00 | |
| 22 | Manuel Vazquez | Andalucía - Cajasur | + 00 | |
| 23 | Serafín Martinez | Xacobeo-Galicia | + 00 | |
| 24 | Johannes Fröhlinger | Team Milram | + 00 | |
| 25 | Stefan Denifl | Cervelo TestTeam | + 00 | |
| 26 | Ion Izagirre | Orbea | + 00 | |
| 27 | Angel Vicioso | Andalucía - Cajasur | + 00 | |
| 28 | Gustavo Rodriguez Iglesias | Xacobeo-Galicia | + 00 | |
| 29 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 30 | Ricardo Garcia | Orbea | + 00 | |
| 31 | Christian Knees | Team Milram | + 00 | |
| 32 | Iván Gutiérrez | Caisse d'Epargne | + 00 | |
| 33 | Fabian Wegmann | Team Milram | + 08 | + 08 |
| 34 | Ezequiel Mosquera | Xacobeo-Galicia | + 12 | + 12 |
| 35 | Xavier Tondó | Cervelo TestTeam | + 12 | + 12 |
| 36 | Dmitriy Kozontchuk | Rabobank | + 16 | + 16 |
| 37 | Denis Menchov | Rabobank | + 16 | + 16 |
| 38 | Steven Kruijswijk | Rabobank | + 16 | + 16 |
| 39 | Pieter Weening | Rabobank | + 16 | + 16 |
| 40 | Iñaki Isasi | Euskaltel-Euskadi | + 21 | + 21 |
| 41 | Javier Aramendia | Euskaltel-Euskadi | + 21 | + 21 |
| 42 | Jurgen van den Broeck | Omega Pharma-Lotto | + 25 | + 25 |
| 43 | Linus Gerdemann | Team Milram | + 27 | + 27 |
| 44 | Paul Voss | Team Milram | + 27 | + 27 |
| 45 | Markus Fothen | Team Milram | + 33 | + 33 |
| 46 | Artur Gajek | Team Milram | + 33 | + 33 |
| 47 | Kamil Zielinski | CCC Polsat Polkowice | + 36 | + 36 |
| 48 | Dariusz Batek | CCC Polsat Polkowice | + 41 | + 41 |
| 49 | Wout Poels | Vacansoleil | + 41 | + 41 |
| 50 | Francis de Greef | Omega Pharma-Lotto | + 41 | + 41 |
| 51 | Luis Pasamontes | Caisse d'Epargne | + 41 | + 41 |
| 52 | Vicente Toribio Jose | Andalucía - Cajasur | + 41 | + 41 |
| 53 | José Cobo Juan | Caisse d'Epargne | + 41 | + 41 |
| 54 | Stéphane Rossetto | Vacansoleil | + 41 | + 41 |
| 55 | Thomas Löfkvist | Sky Professional Cycling Team | + 41 | + 41 |
| 56 | Delio Fernandez | Xacobeo-Galicia | + 41 | + 41 |
| 57 | Daniel Sesma Sorbet | Euskaltel-Euskadi | + 41 | + 41 |
| 58 | Jorge Azanza | Euskaltel-Euskadi | + 41 | + 41 |
| 59 | Vicente García José | Caisse d'Epargne | + 41 | + 41 |
| 60 | David López | Caisse d'Epargne | + 41 | + 41 |
| 61 | Vasil Kiryienka | Caisse d'Epargne | + 41 | + 41 |
| 62 | Gonzalo Rabuñal | Xacobeo-Galicia | + 41 | + 41 |
| 63 | Matthias Russ | Team Milram | + 41 | + 41 |
| 64 | Rasmus Guldhammer | Team HTC - Columbia | + 41 | + 41 |
| 65 | Miguel Minguez | Euskaltel-Euskadi | + 41 | + 41 |
| 66 | Marcel Wyss | Cervelo TestTeam | + 41 | + 41 |
| 67 | Maxime Monfort | Team HTC - Columbia | + 41 | + 41 |
| 68 | Vladimir Isaichev | Xacobeo-Galicia | + 41 | + 41 |
| 69 | Steve Cummings | Sky Professional Cycling Team | + 41 | + 41 |
| 70 | Adrian Honkisz | CCC Polsat Polkowice | + 41 | + 41 |
| 71 | Brice Feillu | Vacansoleil | + 41 | + 41 |
| 72 | Manuel Garate Juan | Rabobank | + 41 | + 41 |
| 73 | Philip Deignan | Cervelo TestTeam | + 41 | + 41 |
| 74 | Íñigo Cuesta | Cervelo TestTeam | + 41 | + 41 |
| 75 | Xabier Zabalo Imaz | Orbea | + 41 | + 41 |
| 76 | Sergio Carrasco Garcia | Andalucía - Cajasur | + 41 | + 41 |
| 77 | Frantisek Rabon | Team HTC - Columbia | + 01:25 | + 01:25 |
| 78 | Javier Estrada Juan | Andalucía - Cajasur | + 01:29 | + 01:29 |
| 79 | Igor Anton | Euskaltel-Euskadi | + 01:29 | + 01:29 |
| 80 | Marco Pinotti | Team HTC - Columbia | + 01:29 | + 01:29 |
| 81 | Patrick Gretsch | Team HTC - Columbia | + 01:29 | + 01:29 |
| 82 | Koldo Fernandez | Euskaltel-Euskadi | + 01:18 | + 01:18 |
| 83 | Silva Correia Joao Miguel | Cervelo TestTeam | + 08:34 | + 08:34 |
| 84 | Pablo Lechuga | Andalucía - Cajasur | + 08:34 | + 08:34 |
| 85 | Jaroslaw Rebiewski | CCC Polsat Polkowice | + 08:34 | + 08:34 |
| 86 | Stef Clement | Rabobank | + 08:34 | + 08:34 |
| 87 | Tomasz Kiendys | CCC Polsat Polkowice | + 08:34 | + 08:34 |
| 88 | Andoni Blazquez Berasarte | Orbea | + 08:34 | + 08:34 |
| 89 | Tomasz Lisowicz | CCC Polsat Polkowice | + 08:34 | + 08:34 |
| 90 | Noel Martin Infante | Orbea | + 08:34 | + 08:34 |
| 91 | Benat Urain Epelde | Orbea | + 08:34 | + 08:34 |