| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | David Bernabeu | Comunidad Valenciana | 03:47:24 | |
| 2 | Julian Sanchez | Comunidad Valenciana | + 01 | + 01 |
| 3 | Paolo Bettini | Quick Step - Innergetic | + 03 | + 03 |
| 4 | David Muñoz | Comunidad Valenciana | + 03 | + 03 |
| 5 | Koos Moerenhout | Phonak Hearing Systems | + 03 | + 03 |
| 6 | Fränk Schleck | Team CSC | + 03 | + 03 |
| 7 | Jon Bru | Kaiku | + 07 | + 07 |
| 8 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 07 | + 07 |
| 9 | Rodrigo Garcia Rena | Kaiku | + 09 | + 09 |
| 10 | Dario Cioni | Liquigas | + 13 | + 13 |
| 11 | Michael Boogerd | Rabobank | + 15 | + 15 |
| 12 | Linus Gerdemann | T-Mobile Team | + 15 | + 15 |
| 13 | Joseba Albizu Lizaso | Euskaltel-Euskadi | + 18 | + 18 |
| 14 | Ángel Gómez | Saunier Duval - Prodir | + 21 | + 21 |
| 15 | Manuel Lloret | Comunidad Valenciana | + 31 | + 31 |
| 16 | Thomas Dekker | Rabobank | + 31 | + 31 |
| 17 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | + 36 | + 36 |
| 18 | Jorge Azanza | Kaiku | + 46 | + 46 |
| 19 | Andy Schleck | Team CSC | + 48 | + 48 |
| 20 | Constantino Zaballa | Caisse d'Epargne - Illes Balears | + 51 | + 51 |
| 21 | Josep Jufré | Davitamon - Lotto | + 52 | + 52 |
| 22 | Mario Almagro Valero Jose | Relax - GAM | + 52 | + 52 |
| 23 | Joost Posthuma | Rabobank | + 52 | + 52 |
| 24 | Gorka Verdugo | Euskaltel-Euskadi | + 52 | + 52 |
| 25 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 52 | + 52 |
| 26 | Francisco Cabello | Andalucia - Paul Versan | + 52 | + 52 |
| 27 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 56 | + 56 |
| 28 | Gerardo Fernandez | Vina Magna - Cropu | + 58 | + 58 |
| 29 | Juan Gomis Lopez | Comunidad Valenciana | + 59 | + 59 |
| 30 | Jesús Hernández | Relax - GAM | + 59 | + 59 |
| 31 | Vicente Peiro Marqueno | Comunidad Valenciana | + 59 | + 59 |
| 32 | Vincenzo Nibali | Liquigas | + 01:02 | + 01:02 |
| 33 | Lorenzo Bernucci | T-Mobile Team | + 01:08 | + 01:08 |
| 34 | Luengo Celaya Anton | Euskaltel-Euskadi | + 01:17 | + 01:17 |
| 35 | Hubert Schwab | Quick Step - Innergetic | + 01:18 | + 01:18 |
| 36 | Johan Vansummeren | Davitamon - Lotto | + 01:19 | + 01:19 |
| 37 | Theo Eltink | Rabobank | + 01:24 | + 01:24 |
| 38 | Jesus Del Nero Montes | 3 Molinos Resort | + 01:24 | + 01:24 |
| 39 | Joseba Zubeldia | Euskaltel-Euskadi | + 01:24 | + 01:24 |
| 40 | Steve Zamperi | Phonak Hearing Systems | + 01:29 | + 01:29 |
| 41 | Luis Perez Romero | Andalucia - Paul Versan | + 01:43 | + 01:43 |
| 42 | Adrian Palomares | Kaiku | + 01:50 | + 01:50 |
| 43 | Patrick Mccarty Jonathan | Phonak Hearing Systems | + 01:57 | + 01:57 |
| 44 | Íñigo Cuesta | Team CSC | + 02:02 | + 02:02 |
| 45 | Ruben Oarbeascoa Ispizua | Kaiku | + 02:02 | + 02:02 |
| 46 | Francisco Pérez | Caisse d'Epargne - Illes Balears | + 02:11 | + 02:11 |
| 47 | Grischa Niermann | Rabobank | + 02:11 | + 02:11 |
| 48 | Ronny Scholz | Gerolsteiner | + 02:11 | + 02:11 |
| 49 | Alexandre Moos | Phonak Hearing Systems | + 02:44 | + 02:44 |
| 50 | Bernhard Kohl | T-Mobile Team | + 02:51 | + 02:51 |
| 51 | Luis Fernandez Oliveira | Phonak Hearing Systems | + 02:53 | + 02:53 |
| 52 | Filippo Pozzato | Quick Step - Innergetic | + 02:55 | + 02:55 |
| 53 | Iker Flores | Euskaltel-Euskadi | + 02:58 | + 02:58 |
| 54 | Jose Terciado Francisco | Relax - GAM | + 02:58 | + 02:58 |
| 55 | Matthias Russ | Gerolsteiner | + 03:23 | + 03:23 |
| 56 | Kim Kirchen | T-Mobile Team | + 03:25 | + 03:25 |
| 57 | Joan Horrach | Caisse d'Epargne - Illes Balears | + 03:47 | + 03:47 |
| 58 | Ángel Martin Miguel | Phonak Hearing Systems | + 03:47 | + 03:47 |
| 59 | José Gomez | Saunier Duval - Prodir | + 03:47 | + 03:47 |
| 60 | Adrian Bonilla | Comunidad Valenciana | + 03:47 | + 03:47 |
| 61 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 03:52 | + 03:52 |
| 62 | Thomas Ziegler | T-Mobile Team | + 04:13 | + 04:13 |
| 63 | Iñaki Isasi | Euskaltel-Euskadi | + 05:48 | + 05:48 |
| 64 | Hugo Pena Victor | Phonak Hearing Systems | + 13:02 | + 13:02 |
| 65 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 13:30 | + 13:30 |
| 66 | Volker Ordowski | Gerolsteiner | + 11:19 | + 11:19 |
| 67 | Sergio Herrero | Vina Magna - Cropu | + 11:19 | + 11:19 |
| 68 | Ignacio Gutierrez | Phonak Hearing Systems | + 11:19 | + 11:19 |
| 69 | Aitor Hernández | Euskaltel-Euskadi | + 11:19 | + 11:19 |
| 70 | Antonio Olmo | Comunidad Valenciana | + 11:19 | + 11:19 |
| 71 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 11:19 | + 11:19 |
| 72 | Javier Moreno | Grupo Nicolas Mateos | + 11:19 | + 11:19 |
| 73 | Bram de Groot | Rabobank | + 11:19 | + 11:19 |
| 74 | Alexandr Kolobnev | Rabobank | + 11:19 | + 11:19 |
| 75 | Antonio Flecha Juan | Rabobank | + 11:19 | + 11:19 |
| 76 | Jaume Rovira | Andalucia - Paul Versan | + 11:19 | + 11:19 |
| 77 | Juan Olmo | Andalucia - Paul Versan | + 11:19 | + 11:19 |
| 78 | Pieter Weening | Rabobank | + 11:19 | + 11:19 |
| 79 | Yury Trofimov | Omnibike Dynamo Moscow | + 11:19 | + 11:19 |
| 80 | Addy Engels | Quick Step - Innergetic | + 11:19 | + 11:19 |
| 81 | Serge Baguet | Quick Step - Innergetic | + 11:19 | + 11:19 |
| 82 | Leonardo Scarselli | Quick Step - Innergetic | + 11:19 | + 11:19 |
| 83 | Antonio Tauler Llull | 3 Molinos Resort | + 11:19 | + 11:19 |
| 84 | Jan Hruska | 3 Molinos Resort | + 11:19 | + 11:19 |
| 85 | Alberto Benitez Jose | Saunier Duval - Prodir | + 11:19 | + 11:19 |
| 86 | Alberto Fernandez | Saunier Duval - Prodir | + 11:19 | + 11:19 |
| 87 | Inigo Chaurreau | AG2R Prévoyance | + 11:19 | + 11:19 |
| 88 | Mikel Astarloza | AG2R Prévoyance | + 11:19 | + 11:19 |
| 89 | Oscar Garcia-casarrubios | Relax - GAM | + 11:19 | + 11:19 |
| 90 | Luis Arrieta José | AG2R Prévoyance | + 11:19 | + 11:19 |
| 91 | Antonio Berasategui | Kaiku | + 11:19 | + 11:19 |
| 92 | Carlos Castaño | Kaiku | + 11:19 | + 11:19 |
| 93 | Alberto Losada | Kaiku | + 11:19 | + 11:19 |
| 94 | Israel Nunez Baticon | Kaiku | + 11:19 | + 11:19 |
| 95 | Javier Benitez | Grupo Nicolas Mateos | + 15:16 | + 15:16 |
| 96 | Marc Wauters | Rabobank | + 15:16 | + 15:16 |
| 97 | Mario Aerts | Davitamon - Lotto | + 15:16 | + 15:16 |
| 98 | Wim van Huffel | Davitamon - Lotto | + 15:16 | + 15:16 |
| 99 | Andrea Peron | Team CSC | + 15:16 | + 15:16 |
| 100 | Christian Vande Velde | Team CSC | + 15:16 | + 15:16 |
| 101 | David Kopp | Gerolsteiner | + 15:16 | + 15:16 |
| 102 | Luis Martinez Jose | Comunidad Valenciana | + 15:16 | + 15:16 |
| 103 | Torsten Hiekmann | Gerolsteiner | + 15:16 | + 15:16 |
| 104 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 15:16 | + 15:16 |
| 105 | Stefan Schumacher | Gerolsteiner | + 15:16 | + 15:16 |
| 106 | Thomas Fothen | Gerolsteiner | + 15:16 | + 15:16 |
| 107 | Antonio Banos Ballester Jose | 3 Molinos Resort | + 15:16 | + 15:16 |
| 108 | Manuel Vazquez | Andalucia - Paul Versan | + 15:16 | + 15:16 |
| 109 | Jesus Buendia Romero | 3 Molinos Resort | + 15:16 | + 15:16 |
| 110 | Luis Marichalar Pedro | Andalucia - Paul Versan | + 15:16 | + 15:16 |
| 111 | Ruben Lorca Jimenez | 3 Molinos Resort | + 15:16 | + 15:16 |
| 112 | Jose Herrada | Vina Magna - Cropu | + 15:16 | + 15:16 |
| 113 | Isidro Cerrato Lopez | 3 Molinos Resort | + 15:16 | + 15:16 |
| 114 | Jorge Capitan Peregina | Vina Magna - Cropu | + 15:16 | + 15:16 |
| 115 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 15:16 | + 15:16 |
| 116 | Carlos Torrent | Vina Magna - Cropu | + 15:16 | + 15:16 |
| 117 | Vicente Ballester Martinez | Comunidad Valenciana | + 15:16 | + 15:16 |
| 118 | Viacheslav Vilkov | Omnibike Dynamo Moscow | + 15:16 | + 15:16 |
| 119 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 15:16 | + 15:16 |
| 120 | Yuriy Krivtsov | AG2R Prévoyance | + 15:16 | + 15:16 |
| 121 | Gilberto Simoni | Saunier Duval - Prodir | + 15:16 | + 15:16 |
| 122 | David Navas Chica | AG2R Prévoyance | + 15:16 | + 15:16 |
| 123 | Koldo Gil | Saunier Duval - Prodir | + 15:16 | + 15:16 |
| 124 | Jorge García Marín | Relax - GAM | + 15:16 | + 15:16 |
| 125 | Javier Mejias | Saunier Duval - Prodir | + 15:16 | + 15:16 |
| 126 | Arkaitz Durán | Saunier Duval - Prodir | + 15:16 | + 15:16 |
| 127 | David de La Fuente | Saunier Duval - Prodir | + 15:16 | + 15:16 |
| 128 | Pablo Lastras | Caisse d'Epargne - Illes Balears | + 28:29 | + 28:29 |
| 129 | Fernando Serrano | Kaiku | + 28:29 | + 28:29 |
| 130 | Steffen Wesemann | T-Mobile Team | + 28:29 | + 28:29 |
| 131 | Franco Pellizotti | Liquigas | + 28:29 | + 28:29 |
| 132 | Lloyd Mondory | AG2R Prévoyance | + 31:42 | + 31:42 |
| 133 | Joseba Agirrezabala | Grupo Nicolas Mateos | + 31:42 | + 31:42 |
| 134 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 31:42 | + 31:42 |
| 135 | Sergio Pardilla | Vina Magna - Cropu | + 31:42 | + 31:42 |
| 136 | Oscar Grau Jorda | Vina Magna - Cropu | + 31:42 | + 31:42 |
| 137 | Samuel Dumoulin | AG2R Prévoyance | + 31:42 | + 31:42 |
| 138 | Jesus Tendero Marcos | Vina Magna - Cropu | + 31:42 | + 31:42 |
| 139 | Jordi Riera Valls | 3 Molinos Resort | + 31:42 | + 31:42 |