| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Thomas Dekker | Rabobank | 03:55:43 | |
| 2 | Vladimir Gusev | Discovery Channel | + 02 | + 02 |
| 3 | Alberto Fernandez | Saunier Duval - Prodir | + 02 | + 02 |
| 4 | Ezequiel Mosquera | Karpin-Galicia | + 02 | + 02 |
| 5 | León Sánchez Luis | Caisse d'Epargne | + 07 | + 07 |
| 6 | David de La Fuente | Saunier Duval - Prodir | + 10 | + 10 |
| 7 | Lorenzo Bernucci | T-Mobile Team | + 12 | + 12 |
| 8 | Adrian Bonilla | Fuerteventura - Canarias | + 12 | + 12 |
| 9 | Stijn Devolder | Discovery Channel | + 12 | + 12 |
| 10 | Vicente Reynès | Caisse d'Epargne | + 12 | + 12 |
| 11 | Jorge Ferrio Luque | Andalucia - Cajasur | + 12 | + 12 |
| 12 | Pieter Weening | Rabobank | + 12 | + 12 |
| 13 | Matthias Russ | Gerolsteiner | + 16 | + 16 |
| 14 | Gustavo Dominguez Lemos | Karpin-Galicia | + 16 | + 16 |
| 15 | Alberto Contador | Discovery Channel | + 16 | + 16 |
| 16 | Carlos Barredo | Quick Step - Innergetic | + 16 | + 16 |
| 17 | Luengo Celaya Anton | Euskaltel-Euskadi | + 16 | + 16 |
| 18 | Daniel Moreno | Relax - GAM | + 16 | + 16 |
| 19 | Antonio Colom | Astana | + 16 | + 16 |
| 20 | Jesús Hernández | Relax - GAM | + 39 | + 39 |
| 21 | Remmert Wielinga | Saunier Duval - Prodir | + 39 | + 39 |
| 22 | Patrik Sinkewitz | T-Mobile Team | + 39 | + 39 |
| 23 | Tim Klinger | Gerolsteiner | + 39 | + 39 |
| 24 | Thomas Ziegler | T-Mobile Team | + 39 | + 39 |
| 25 | Joan Llaneras Rosello | + 39 | + 39 | |
| 26 | Daniel Navarro | Astana | + 39 | + 39 |
| 27 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 39 | + 39 |
| 28 | Linus Gerdemann | T-Mobile Team | + 39 | + 39 |
| 29 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 39 | + 39 |
| 30 | Diego Gallego | Vina Magna - Cropu | + 39 | + 39 |
| 31 | Jorge Azanza | Euskaltel-Euskadi | + 54 | + 54 |
| 32 | Francisco Pérez | Caisse d'Epargne | + 57 | + 57 |
| 33 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 57 | + 57 |
| 34 | Fernando Torres Martin | Spiuk - Extremadura | + 01:00 | + 01:00 |
| 35 | Javier Etxarri | Grupo Nicolas Mateos | + 01:04 | + 01:04 |
| 36 | David Martin Peribanez | Vina Magna - Cropu | + 01:04 | + 01:04 |
| 37 | Josu Mondelo Diaz | Spiuk - Extremadura | + 01:06 | + 01:06 |
| 38 | Aitor Hernández | Euskaltel-Euskadi | + 01:08 | + 01:08 |
| 39 | Oscar Garcia-casarrubios | Relax - GAM | + 01:08 | + 01:08 |
| 40 | Antonio Redondo Jose | Astana | + 01:12 | + 01:12 |
| 41 | Vincenzo Nibali | Liquigas | + 01:19 | + 01:19 |
| 42 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 43 | Markel Irizar | Euskaltel-Euskadi | + 01:22 | + 01:22 |
| 44 | Juan Olmo | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 45 | José Oroz Juan | Orbea - Laukiz F.T. | + 01:29 | + 01:29 |
| 46 | Alejandro Valverde | Caisse d'Epargne | + 01:33 | + 01:33 |
| 47 | Danilo Di Luca | Liquigas | + 01:43 | + 01:43 |
| 48 | Ivan Santaromita | Quick Step - Innergetic | + 01:43 | + 01:43 |
| 49 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 01:43 | + 01:43 |
| 50 | Erik Zabel | Team Milram | + 01:43 | + 01:43 |
| 51 | Marcus Burghardt | T-Mobile Team | + 01:43 | + 01:43 |
| 52 | Joaquin Rojas José | Caisse d'Epargne | + 01:43 | + 01:43 |
| 53 | Iker Mezo Askargorta | Orbea - Laukiz F.T. | + 01:55 | + 01:55 |
| 54 | David Bernabeu | Fuerteventura - Canarias | + 02:26 | + 02:26 |
| 55 | Roberto Alvarez Martin Luis | Vina Magna - Cropu | + 02:32 | + 02:32 |
| 56 | Steve Cummings | Discovery Channel | + 02:52 | + 02:52 |
| 57 | Trent Lowe | Discovery Channel | + 02:52 | + 02:52 |
| 58 | Luis Rubiera José | Discovery Channel | + 02:53 | + 02:53 |
| 59 | Pablo Lastras | Caisse d'Epargne | + 02:55 | + 02:55 |
| 60 | Kevin Seeldraeyers | Quick Step - Innergetic | + 02:55 | + 02:55 |
| 61 | Christian Knees | Team Milram | + 02:58 | + 02:58 |
| 62 | Antonio Olmo | Andalucia - Cajasur | + 03:23 | + 03:23 |
| 63 | Joseba Zubeldia | Euskaltel-Euskadi | + 03:48 | + 03:48 |
| 64 | Joost Posthuma | Rabobank | + 05:06 | + 05:06 |
| 65 | Koos Moerenhout | Rabobank | + 05:06 | + 05:06 |
| 66 | Francisco Mancebo | Relax - GAM | + 05:06 | + 05:06 |
| 67 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 05:06 | + 05:06 |
| 68 | Patrick Calcagni | Liquigas | + 05:26 | + 05:26 |
| 69 | Manuel Garate Juan | Quick Step - Innergetic | + 05:26 | + 05:26 |
| 70 | Adrian Palomares | Fuerteventura - Canarias | + 05:41 | + 05:41 |
| 71 | Alessandro Spezialetti | Liquigas | + 06:37 | + 06:37 |
| 72 | Manuel Calvente | Agritubel | + 10:55 | + 10:55 |
| 73 | Luis Pérez Rodríguez | Andalucia - Cajasur | + 10:55 | + 10:55 |
| 74 | Oleg Chuzhda | Fuerteventura - Canarias | + 10:55 | + 10:55 |
| 75 | Pavel Padrnos | Discovery Channel | + 10:55 | + 10:55 |
| 76 | Enrico Poitschke | Team Milram | + 10:55 | + 10:55 |
| 77 | Gorka Amuriza Gumucio | Grupo Nicolas Mateos | + 10:55 | + 10:55 |
| 78 | Antonio Flecha Juan | Rabobank | + 10:55 | + 10:55 |
| 79 | Antonio Tauler Llull | + 13:06 | + 13:06 | |
| 80 | David Muntaner | + 13:06 | + 13:06 | |
| 81 | Luis Perez Romero | Andalucia - Cajasur | + 13:49 | + 13:49 |
| 82 | Aaron Villegas Trapaga | Orbea - Laukiz F.T. | + 13:49 | + 13:49 |
| 83 | Alberto Rodriguez | Vina Magna - Cropu | + 13:49 | + 13:49 |
| 84 | Thomas Fothen | Gerolsteiner | + 13:49 | + 13:49 |
| 85 | Martin Müller | Team Milram | + 13:49 | + 13:49 |
| 86 | Maxim Gourov | Astana | + 13:49 | + 13:49 |
| 87 | Igor Abakoumov | Astana | + 13:49 | + 13:49 |
| 88 | David García Dapena | Karpin-Galicia | + 13:49 | + 13:49 |
| 89 | Angel Vallejo Dominquez | Relax - GAM | + 13:49 | + 13:49 |
| 90 | Iban Iriondo Uranga | Euskaltel-Euskadi | + 13:49 | + 13:49 |
| 91 | Moisés Dueñas | Agritubel | + 13:49 | + 13:49 |
| 92 | Manuel Lloret | Fuerteventura - Canarias | + 13:49 | + 13:49 |
| 93 | Roman Troncoso | Karpin-Galicia | + 13:49 | + 13:49 |
| 94 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 13:49 | + 13:49 |
| 95 | Eloy Teruel | Grupo Nicolas Mateos | + 13:49 | + 13:49 |
| 96 | Max van Heeswijk | Rabobank | + 13:49 | + 13:49 |
| 97 | Angel Vicioso | Relax - GAM | + 13:49 | + 13:49 |
| 98 | Eduardo Gonzalo Ramirez | Agritubel | + 13:49 | + 13:49 |
| 99 | Marc de Maar | Rabobank | + 13:49 | + 13:49 |
| 100 | Gerben Löwik | Rabobank | + 13:49 | + 13:49 |
| 101 | Matej Jurco | Team Milram | + 13:49 | + 13:49 |
| 102 | Carlo Westphal | Gerolsteiner | + 13:49 | + 13:49 |
| 103 | Ignacio Sarabia | Spiuk - Extremadura | + 13:49 | + 13:49 |
| 104 | Johannes Fröhlinger | Gerolsteiner | + 13:49 | + 13:49 |
| 105 | Andreas Klier | T-Mobile Team | + 13:49 | + 13:49 |
| 106 | David Millar | Saunier Duval - Prodir | + 13:49 | + 13:49 |
| 107 | Jose Herrada | Vina Magna - Cropu | + 13:49 | + 13:49 |
| 108 | Kevin Hulsmans | Quick Step - Innergetic | + 16:42 | + 16:42 |
| 109 | Davide Vigano | Quick Step - Innergetic | + 16:42 | + 16:42 |
| 110 | Jan Hruska | Relax - GAM | + 16:42 | + 16:42 |
| 111 | Manuel Ortega | Andalucia - Cajasur | + 16:42 | + 16:42 |
| 112 | Stefan Schumacher | Gerolsteiner | + 16:42 | + 16:42 |
| 113 | Israel Pérez | Spiuk - Extremadura | + 16:42 | + 16:42 |
| 114 | Isidro Nozal Vega | Karpin-Galicia | + 17:59 | + 17:59 |
| 115 | Enrique Salgueiro | Karpin-Galicia | + 20:15 | + 20:15 |
| 116 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 21:51 | + 21:51 |
| 117 | Tomas Vaitkus | Discovery Channel | + 25:19 | + 25:19 |
| 118 | Raul Alarcon | Saunier Duval - Prodir | + 25:31 | + 25:31 |
| 119 | Servais Knaven | T-Mobile Team | + 25:31 | + 25:31 |
| 120 | Niki Terpstra | Team Milram | + 25:31 | + 25:31 |
| 121 | Bernhard Eisel | T-Mobile Team | + 25:31 | + 25:31 |
| 122 | Marcel Sieberg | Team Milram | + 25:31 | + 25:31 |
| 123 | Jesus Del Nero Montes | Saunier Duval - Prodir | + 25:31 | + 25:31 |
| 124 | Carlos Torrent | Vina Magna - Cropu | + 25:31 | + 25:31 |
| 125 | Alexey Kolessov | Astana | + 25:31 | + 25:31 |
| 126 | Antonio Banos Ballester Jose | Grupo Nicolas Mateos | + 25:31 | + 25:31 |
| 127 | Sergei Ivanov | Astana | + 25:31 | + 25:31 |
| 128 | Joaquin Sobrino | Relax - GAM | + 25:31 | + 25:31 |
| 129 | Alan Perez Lezaun | Euskaltel-Euskadi | + 25:31 | + 25:31 |
| 130 | Koen de Kort | Astana | + 25:31 | + 25:31 |
| 131 | Bert Grabsch | T-Mobile Team | + 25:31 | + 25:31 |
| 132 | Roberto Barrientos Fernandez | Orbea - Laukiz F.T. | + 25:31 | + 25:31 |
| 133 | David Belda | Fuerteventura - Canarias | + 25:31 | + 25:31 |
| 134 | Pedro Horrillo | Rabobank | + 25:31 | + 25:31 |
| 135 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 25:31 | + 25:31 |
| 136 | Egoitz Murgoitio Rekalde | Grupo Nicolas Mateos | + 25:31 | + 25:31 |
| 137 | Julien Mazet | Astana | + 25:31 | + 25:31 |
| 138 | Iván Melero | Orbea - Laukiz F.T. | + 25:31 | + 25:31 |
| 139 | Jurgen van Goolen | Discovery Channel | + 25:31 | + 25:31 |
| 140 | Josu Agirre Asegniloaza | Orbea - Laukiz F.T. | + 25:31 | + 25:31 |
| 141 | William Walker | Rabobank | + 25:31 | + 25:31 |
| 142 | Joseba Zumeta Etxabe | Orbea - Laukiz F.T. | + 25:31 | + 25:31 |
| 143 | Scott Davis | T-Mobile Team | + 25:31 | + 25:31 |
| 144 | Unai Uribarri | Euskaltel-Euskadi | + 25:31 | + 25:31 |
| 145 | Miguel Alzamora Riera | + 25:31 | + 25:31 | |
| 146 | Brad Armstrong | Orbea - Laukiz F.T. | + 25:31 | + 25:31 |
| 147 | Sebastian Schwager | Team Milram | + 25:31 | + 25:31 |
| 148 | Iker Flores | Fuerteventura - Canarias | + 25:31 | + 25:31 |
| 149 | Eduard Vorganov | Karpin-Galicia | + 25:31 | + 25:31 |
| 150 | Sebastien Siedler | Team Milram | + 25:31 | + 25:31 |
| 151 | Rubens Bertogliati | Saunier Duval - Prodir | + 25:31 | + 25:31 |
| 152 | Tom Stamsnijder | Gerolsteiner | + 25:31 | + 25:31 |
| 153 | Antonio Arroyo Ramirez Jose | Spiuk - Extremadura | + 25:31 | + 25:31 |
| 154 | Dennis Haueisen | Team Milram | + 25:31 | + 25:31 |
| 155 | Antonio Lopez Gil Jose | Andalucia - Cajasur | + 25:31 | + 25:31 |
| 156 | David Abal Diego | Karpin-Galicia | + 25:31 | + 25:31 |
| 157 | Gonzalo Rabuñal | Karpin-Galicia | + 25:31 | + 25:31 |