| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Joaquin Rojas José | Caisse d'Epargne | 04:00:59 | |
| 2 | Giovanni Visconti | Quick Step | + 00 | |
| 3 | Philippe Gilbert | Française des Jeux | + 00 | |
| 4 | Sebastian Langeveld | Rabobank | + 00 | |
| 5 | Aitor Perez Arrieta | Extremadura | + 00 | |
| 6 | Manuele Mori | Scott - American Beef | + 00 | |
| 7 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 00 | |
| 8 | David Herrero | Xacobeo-Galicia | + 00 | |
| 9 | Gerben Löwik | Rabobank | + 00 | |
| 10 | Stijn Devolder | Quick Step | + 00 | |
| 11 | Stephan Schreck | Gerolsteiner | + 00 | |
| 12 | Antonio Colom | Astana | + 00 | |
| 13 | Haimar Zubeldia | Euskaltel-Euskadi | + 00 | |
| 14 | Oscar Pujol | Burgos Monumental | + 00 | |
| 15 | Jon Bru | Euskaltel-Euskadi | + 00 | |
| 16 | Jesus Rosendo Prado | Andalucia - Cajasur | + 00 | |
| 17 | Bram Tankink | Rabobank | + 00 | |
| 18 | Alberto Losada | Caisse d'Epargne | + 00 | |
| 19 | Arkaitz Durán | Scott - American Beef | + 00 | |
| 20 | David de La Fuente | Scott - American Beef | + 00 | |
| 21 | Ezequiel Mosquera | Xacobeo-Galicia | + 00 | |
| 22 | Manuel Ortega | Andalucia - Cajasur | + 00 | |
| 23 | Matteo Carrara | Quick Step | + 00 | |
| 24 | José Gomez | Scott - American Beef | + 00 | |
| 25 | Iban Mayoz | Xacobeo-Galicia | + 00 | |
| 26 | Kevin de Weert | Cofidis | + 00 | |
| 27 | Matthias Russ | Gerolsteiner | + 00 | |
| 28 | Gorka Verdugo | Euskaltel-Euskadi | + 00 | |
| 29 | Javier Aramendia | Euskaltel-Euskadi | + 00 | |
| 30 | Juan Olmo | Andalucia - Cajasur | + 00 | |
| 31 | Benoit Joachim | Astana | + 00 | |
| 32 | Javier Moreno | Andalucia - Cajasur | + 00 | |
| 33 | Ignacio Sarabia | Extremadura | + 00 | |
| 34 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 00 | |
| 35 | Francisco Pérez | Caisse d'Epargne | + 00 | |
| 36 | Tristan Valentin | Cofidis | + 00 | |
| 37 | Serafín Martinez | Xacobeo-Galicia | + 00 | |
| 38 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 00 | |
| 39 | Koos Moerenhout | Rabobank | + 00 | |
| 40 | Alberto Fernandez Sainz | Xacobeo-Galicia | + 00 | |
| 41 | Addy Engels | Quick Step | + 00 | |
| 42 | Grischa Niermann | Rabobank | + 00 | |
| 43 | Jakub Danacik | PSK Whirlpool - Author | + 00 | |
| 44 | Vladimir Karpets | Caisse d'Epargne | + 00 | |
| 45 | David Arroyo | Caisse d'Epargne | + 00 | |
| 46 | Christophe Mengin | Française des Jeux | + 00 | |
| 47 | Marc de Maar | Rabobank | + 00 | |
| 48 | Iñigo Landaluze | Euskaltel-Euskadi | + 00 | |
| 49 | Alessandro Proni | Quick Step | + 00 | |
| 50 | Benat Intxausti | Scott - American Beef | + 00 | |
| 51 | Hubert Schwab | Quick Step | + 00 | |
| 52 | David López | Caisse d'Epargne | + 00 | |
| 53 | Sergio Pardilla | Burgos Monumental | + 00 | |
| 54 | Rafael Valls | Scott - American Beef | + 00 | |
| 55 | Alejandro Valverde | Caisse d'Epargne | + 15 | + 15 |
| 56 | Ivan Velasco | Euskaltel-Euskadi | + 26 | + 26 |
| 57 | Joaquim Rodríguez | Caisse d'Epargne | + 01:18 | + 01:18 |
| 58 | Mathieu Heijboer | Cofidis | + 11:57 | + 11:57 |
| 59 | Nick Nuyens | Cofidis | + 11:57 | + 11:57 |
| 60 | Staf Scheirlinckx | Cofidis | + 11:57 | + 11:57 |
| 61 | Salvador Guardiola | + 11:57 | + 11:57 | |
| 62 | Thomas Frei | Astana | + 11:57 | + 11:57 |
| 63 | Yoann Offredo | Française des Jeux | + 11:57 | + 11:57 |
| 64 | Sandy Casar | Française des Jeux | + 11:57 | + 11:57 |
| 65 | Ronny Scholz | Gerolsteiner | + 11:57 | + 11:57 |
| 66 | Fumiyuki Beppu | Skil - Shimano | + 11:57 | + 11:57 |
| 67 | Maarten den Bakker | Skil - Shimano | + 11:57 | + 11:57 |
| 68 | José Casas Claudio | Andalucia - Cajasur | + 11:57 | + 11:57 |
| 69 | Vicente Toribio Jose | Burgos Monumental | + 11:57 | + 11:57 |
| 70 | Mickaël Delage | Française des Jeux | + 11:57 | + 11:57 |
| 71 | Pedro Gutierrez Alvarez | Burgos Monumental | + 11:57 | + 11:57 |
| 72 | Pablo Lastras | Caisse d'Epargne | + 11:57 | + 11:57 |
| 73 | Thierry Hupond | Skil - Shimano | + 11:57 | + 11:57 |
| 74 | Lars Vierbergen | Van Vliet - EBH - Elshof | + 11:57 | + 11:57 |
| 75 | David Francisco Delgado | Burgos Monumental | + 11:57 | + 11:57 |
| 76 | Josu Mondelo Diaz | Extremadura | + 11:57 | + 11:57 |
| 77 | Benjamin Noval | Astana | + 11:57 | + 11:57 |
| 78 | Albert Timmer | Skil - Shimano | + 11:57 | + 11:57 |
| 79 | Rick Flens | Rabobank | + 11:57 | + 11:57 |
| 80 | Gonzalo Rabuñal | Xacobeo-Galicia | + 11:57 | + 11:57 |
| 81 | Delio Fernandez | Xacobeo-Galicia | + 11:57 | + 11:57 |
| 82 | Volker Ordowski | Gerolsteiner | + 11:57 | + 11:57 |
| 83 | Sébastien Minard | Cofidis | + 11:57 | + 11:57 |
| 84 | Eduard Vorganov | Xacobeo-Galicia | + 11:57 | + 11:57 |
| 85 | Julien Mazet | Astana | + 11:57 | + 11:57 |
| 86 | Carlos Castaño | Xacobeo-Galicia | + 11:57 | + 11:57 |
| 87 | Lander Aperribay Aranda | Euskaltel-Euskadi | + 11:57 | + 11:57 |
| 88 | Josu Agirre Asegniloaza | Euskaltel-Euskadi | + 11:57 | + 11:57 |
| 89 | Manuel Garate Juan | Quick Step | + 11:57 | + 11:57 |
| 90 | Mauro Facci | Quick Step | + 11:57 | + 11:57 |
| 91 | Markus Fothen | Gerolsteiner | + 11:57 | + 11:57 |
| 92 | Jaume Rovira | Extremadura | + 11:57 | + 11:57 |
| 93 | Dmitriy Kozontchuk | Rabobank | + 11:57 | + 11:57 |
| 94 | Martin Mares | PSK Whirlpool - Author | + 11:57 | + 11:57 |
| 95 | Leopold König | PSK Whirlpool - Author | + 11:57 | + 11:57 |
| 96 | Steve Morabito | Astana | + 11:57 | + 11:57 |
| 97 | Vicente García José | Caisse d'Epargne | + 11:57 | + 11:57 |
| 98 | Joost van Leijen | Van Vliet - EBH - Elshof | + 11:57 | + 11:57 |
| 99 | Johnny Hoogerland | Van Vliet - EBH - Elshof | + 11:57 | + 11:57 |
| 100 | Tomas Vaitkus | Astana | + 23:20 | + 23:20 |
| 101 | René Haselbacher | Astana | + 23:20 | + 23:20 |
| 102 | Timothy Gudsell | Française des Jeux | + 23:20 | + 23:20 |
| 103 | Jeffrey Wiersma | Van Vliet - EBH - Elshof | + 23:20 | + 23:20 |
| 104 | Javier Iriarte | Burgos Monumental | + 23:20 | + 23:20 |
| 105 | Roy Curvers | Skil - Shimano | + 23:20 | + 23:20 |
| 106 | Frank Høj | Cofidis | + 23:20 | + 23:20 |
| 107 | Michiel Elijzen | Rabobank | + 23:20 | + 23:20 |
| 108 | Rik Verbrugghe | Cofidis | + 23:20 | + 23:20 |
| 109 | Clément Lhotellerie | Skil - Shimano | + 23:20 | + 23:20 |
| 110 | Piet Rooijakkers | Skil - Shimano | + 23:20 | + 23:20 |
| 111 | Diego Gallego | Burgos Monumental | + 23:20 | + 23:20 |
| 112 | Jose Terciado Francisco | Extremadura | + 23:20 | + 23:20 |
| 113 | Emmanuel van Ruitenbeek | Van Vliet - EBH - Elshof | + 23:20 | + 23:20 |
| 114 | Thomas Fothen | Gerolsteiner | + 23:20 | + 23:20 |
| 115 | Robert Förster | Gerolsteiner | + 23:20 | + 23:20 |
| 116 | Gonzalo Zambrano | Extremadura | + 23:20 | + 23:20 |
| 117 | Javier Estrada Juan | Andalucia - Cajasur | + 23:20 | + 23:20 |
| 118 | Rikke Dijkxhoorn | Van Vliet - EBH - Elshof | + 23:20 | + 23:20 |
| 119 | Martin Mata Cabello | Burgos Monumental | + 23:20 | + 23:20 |
| 120 | Jesus Cobelo Fojo | Xacobeo-Galicia | + 23:20 | + 23:20 |
| 121 | Gert Steegmans | Quick Step | + 23:20 | + 23:20 |
| 122 | Koen de Kort | Astana | + 23:20 | + 23:20 |
| 123 | Israel Pérez | Extremadura | + 23:20 | + 23:20 |
| 124 | Javier Ramirez Torres Jesus | Extremadura | + 23:20 | + 23:20 |
| 125 | Frantisek Kloucek | PSK Whirlpool - Author | + 41:24 | + 41:24 |
| 126 | Radek Becka | PSK Whirlpool - Author | + 41:24 | + 41:24 |
| 127 | Vojtech Dlouhy | PSK Whirlpool - Author | + 41:24 | + 41:24 |
| 128 | Fabien Bacquet | Skil - Shimano | + 42:20 | + 42:20 |