| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Iban Mayo | Euskaltel-Euskadi | 03:48:25 | |
| 2 | Ricardo Serrano | Kaiku | + 46 | + 46 |
| 3 | Igor Anton | Euskaltel-Euskadi | + 54 | + 54 |
| 4 | David Bernabeu | Comunidad Valenciana | + 01:02 | + 01:02 |
| 5 | Antonio Pecharroman Jose | Comunidad Valenciana | + 01:05 | + 01:05 |
| 6 | Luengo Celaya Anton | Euskaltel-Euskadi | + 01:20 | + 01:20 |
| 7 | José Martínez Francisco | Andalucia - Paul Versan | + 01:28 | + 01:28 |
| 8 | Julian Sanchez | Comunidad Valenciana | + 01:34 | + 01:34 |
| 9 | Rubén Plaza | Comunidad Valenciana | + 01:40 | + 01:40 |
| 10 | Ezequiel Mosquera | Comunidad Valenciana | + 01:40 | + 01:40 |
| 11 | Alexis Rodriguez | 3 Molinos Resort | + 01:45 | + 01:45 |
| 12 | Enrique Salgueiro | Spiuk - Extremadura | + 01:53 | + 01:53 |
| 13 | Miguel Galindo Jose | Relax - GAM | + 01:53 | + 01:53 |
| 14 | Marco Fertonani | Caisse d'Epargne - Illes Balears | + 01:53 | + 01:53 |
| 15 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | + 02:01 | + 02:01 |
| 16 | Jorge García Marín | Relax - GAM | + 02:01 | + 02:01 |
| 17 | Ruben Lobato | Saunier Duval - Prodir | + 02:24 | + 02:24 |
| 18 | Iker Camaño | Euskaltel-Euskadi | + 02:24 | + 02:24 |
| 19 | Michael Lange | Team TIAA - CREF | + 02:33 | + 02:33 |
| 20 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 02:38 | + 02:38 |
| 21 | Ivan Velasco | Orbea | + 02:45 | + 02:45 |
| 22 | Julen Zubero Aldekoa | Orbea | + 03:20 | + 03:20 |
| 23 | Vladimir Karpets | Caisse d'Epargne - Illes Balears | + 03:22 | + 03:22 |
| 24 | David López | Euskaltel-Euskadi | + 03:25 | + 03:25 |
| 25 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 03:52 | + 03:52 |
| 26 | Alberto Rodriguez | Massi | + 03:56 | + 03:56 |
| 27 | Ignacio Sarabia | Spiuk - Extremadura | + 04:07 | + 04:07 |
| 28 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 04:16 | + 04:16 |
| 29 | Eladio Sánchez | Astana - Würth Team | + 04:25 | + 04:25 |
| 30 | Roberto Alvarez Martin Luis | Vina Magna - Cropu | + 04:25 | + 04:25 |
| 31 | Nicolas Fritsch | Saunier Duval - Prodir | + 05:02 | + 05:02 |
| 32 | Joseba Zumeta Etxabe | Orbea | + 05:10 | + 05:10 |
| 33 | Inigo Lazkano Iriondo | Orbea | + 05:12 | + 05:12 |
| 34 | Mathieu Perget | Caisse d'Epargne - Illes Balears | + 05:54 | + 05:54 |
| 35 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 06:19 | + 06:19 |
| 36 | Miyataka Shimizu | Cycle Racing Team Vang | + 06:36 | + 06:36 |
| 37 | Antonio Cosme Fraile | Vina Magna - Cropu | + 07:29 | + 07:29 |
| 38 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 08:16 | + 08:16 |
| 39 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 08:16 | + 08:16 |
| 40 | Danny Pate | Team TIAA - CREF | + 08:16 | + 08:16 |
| 41 | Raul Garcia de Mateos | Relax - GAM | + 10:27 | + 10:27 |