| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | David Arroyo | Caisse d'Epargne | 03:50:12 | |
| 2 | José Cobo Juan | Scott - American Beef | + 06 | + 06 |
| 3 | Sergio Pardilla | Burgos Monumental | + 26 | + 26 |
| 4 | David López | Caisse d'Epargne | + 55 | + 55 |
| 5 | Joaquim Rodríguez | Caisse d'Epargne | + 01:00 | + 01:00 |
| 6 | José Rujano | Caisse d'Epargne | + 01:10 | + 01:10 |
| 7 | Francisco Pérez | Caisse d'Epargne | + 01:20 | + 01:20 |
| 8 | Manuel Calvente | Contentpolis - Murcia | + 01:21 | + 01:21 |
| 9 | Ignacio Sarabia | Extremadura | + 01:25 | + 01:25 |
| 10 | Gorka Verdugo | Euskaltel-Euskadi | + 01:39 | + 01:39 |
| 11 | Luis Pasamontes | Caisse d'Epargne | + 01:49 | + 01:49 |
| 12 | Mikel Nieve | Orbea - Oreka SDA | + 01:53 | + 01:53 |
| 13 | Pedro Gutierrez Alvarez | Burgos Monumental | + 02:01 | + 02:01 |
| 14 | David Martin | Orbea - Oreka SDA | + 02:01 | + 02:01 |
| 15 | Antonio Piedra | Andalucia - Cajasur | + 02:01 | + 02:01 |
| 16 | José Gomez | Scott - American Beef | + 02:07 | + 02:07 |
| 17 | Julien Loubet | AG2R La Mondiale | + 02:07 | + 02:07 |
| 18 | Antonio Redondo Jose | Andalucia - Cajasur | + 02:12 | + 02:12 |
| 19 | Yauhen Sobal | Tinkoff Credit Systems | + 02:30 | + 02:30 |
| 20 | Rinaldo Nocentini | AG2R La Mondiale | + 02:35 | + 02:35 |
| 21 | Oscar Pujol | Burgos Monumental | + 02:38 | + 02:38 |
| 22 | Amets Txurruka | Euskaltel-Euskadi | + 02:42 | + 02:42 |
| 23 | Jonathan Castroviejo | Orbea - Oreka SDA | + 02:48 | + 02:48 |
| 24 | Enrique Salgueiro | Extremadura | + 02:52 | + 02:52 |
| 25 | Leopold König | PSK Whirlpool - Author | + 03:00 | + 03:00 |
| 26 | Serafín Martinez | Xacobeo-Galicia | + 03:02 | + 03:02 |
| 27 | Roman Troncoso | Xacobeo-Galicia | + 03:02 | + 03:02 |
| 28 | Ricardo Serrano | Tinkoff Credit Systems | + 03:17 | + 03:17 |
| 29 | Julian Sanchez | Contentpolis - Murcia | + 03:24 | + 03:24 |
| 30 | David de La Fuente | Scott - American Beef | + 03:31 | + 03:31 |
| 31 | Manuel Vazquez | Contentpolis - Murcia | + 03:31 | + 03:31 |
| 32 | Francisco Torrella Gomez | Contentpolis - Murcia | + 03:49 | + 03:49 |
| 33 | Marlon Perez | Caisse d'Epargne | + 04:02 | + 04:02 |
| 34 | Ezequiel Mosquera | Xacobeo-Galicia | + 04:03 | + 04:03 |
| 35 | Diego Gallego | Burgos Monumental | + 04:05 | + 04:05 |
| 36 | Igor Anton | Euskaltel-Euskadi | + 04:08 | + 04:08 |
| 37 | Aitor Olano Orbegozo | Orbea - Oreka SDA | + 04:22 | + 04:22 |
| 38 | Evgeni Petrov | Tinkoff Credit Systems | + 04:28 | + 04:28 |
| 39 | Yukiya Arashiro | Meitan Hompo - GDR | + 04:30 | + 04:30 |
| 40 | Aitor Hernández | Euskaltel-Euskadi | + 04:32 | + 04:32 |
| 41 | Javier Chacon Quesada | Contentpolis - Murcia | + 04:32 | + 04:32 |
| 42 | Rodrigo Garcia Rena | Extremadura | + 04:32 | + 04:32 |
| 43 | Javier Etxarri | Contentpolis - Murcia | + 04:41 | + 04:41 |
| 44 | Wout Poels | P3Transfer - Batavus | + 04:47 | + 04:47 |
| 45 | José Oroz Juan | Euskaltel-Euskadi | + 04:50 | + 04:50 |
| 46 | Jose Terciado Francisco | Extremadura | + 05:08 | + 05:08 |
| 47 | Serguei Klimov | Tinkoff Credit Systems | + 05:15 | + 05:15 |
| 48 | Jose Ruiz Sanchez | Andalucia - Cajasur | + 05:17 | + 05:17 |
| 49 | David Herrero | Xacobeo-Galicia | + 05:24 | + 05:24 |
| 50 | Imanol Erviti | Caisse d'Epargne | + 05:44 | + 05:44 |
| 51 | Daniel Sesma Sorbet | Orbea - Oreka SDA | + 06:05 | + 06:05 |
| 52 | Iván Melero | Orbea - Oreka SDA | + 06:05 | + 06:05 |
| 53 | David Francisco Delgado | Burgos Monumental | + 06:16 | + 06:16 |
| 54 | Markel Irizar | Euskaltel-Euskadi | + 07:05 | + 07:05 |
| 55 | Jesus Del Nero Montes | Scott - American Beef | + 07:05 | + 07:05 |
| 56 | Ruben Lobato | Scott - American Beef | + 07:05 | + 07:05 |
| 57 | Miguel Minguez | Orbea - Oreka SDA | + 07:05 | + 07:05 |
| 58 | Israel Pérez | Extremadura | + 07:07 | + 07:07 |
| 59 | Miyataka Shimizu | Meitan Hompo - GDR | + 07:15 | + 07:15 |
| 60 | Gustavo Dominguez Lemos | Xacobeo-Galicia | + 07:32 | + 07:32 |
| 61 | Gustavo Veloso | Xacobeo-Galicia | + 07:54 | + 07:54 |
| 62 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 08:24 | + 08:24 |
| 63 | Iker Camaño | Scott - American Beef | + 08:24 | + 08:24 |
| 64 | José Martínez Francisco | Andalucia - Cajasur | + 08:24 | + 08:24 |
| 65 | Manuel Ortega | Andalucia - Cajasur | + 08:24 | + 08:24 |
| 66 | Martin Mata Cabello | Burgos Monumental | + 08:24 | + 08:24 |
| 67 | Alberto Fernandez | Scott - American Beef | + 08:24 | + 08:24 |
| 68 | Walter Pedraza | Tinkoff Credit Systems | + 08:24 | + 08:24 |
| 69 | Avelino Antuna Coro Andres | Burgos Monumental | + 08:24 | + 08:24 |
| 70 | Pavel Brutt | Tinkoff Credit Systems | + 08:28 | + 08:28 |
| 71 | Alexander Gottfried | Tinkoff Credit Systems | + 08:32 | + 08:32 |
| 72 | Unai Uribarri | Orbea - Oreka SDA | + 08:35 | + 08:35 |
| 73 | Antonio Carrasco Jose | Andalucia - Cajasur | + 08:37 | + 08:37 |
| 74 | Jon Bru | Euskaltel-Euskadi | + 10:45 | + 10:45 |
| 75 | David Abal Diego | Xacobeo-Galicia | + 10:45 | + 10:45 |
| 76 | Eritz Ruiz | Orbea - Oreka SDA | + 15:40 | + 15:40 |
| 77 | Jesus Rosendo Prado | Andalucia - Cajasur | + 15:40 | + 15:40 |
| 78 | Joan Horrach | Caisse d'Epargne | + 15:40 | + 15:40 |
| 79 | Stanislav Kozubek | PSK Whirlpool - Author | + 15:40 | + 15:40 |
| 80 | Tomas Buchacek | PSK Whirlpool - Author | + 15:40 | + 15:40 |
| 81 | Sondre Sørtveit | Team Sparebanken Vest | + 15:40 | + 15:40 |
| 82 | Alexander Khatuntsev | Tinkoff Credit Systems | + 15:40 | + 15:40 |
| 83 | Jorge Sanchez Pimienta | Contentpolis - Murcia | + 15:40 | + 15:40 |
| 84 | Sergio Domínguez Muñoz | Contentpolis - Murcia | + 15:40 | + 15:40 |
| 85 | Alberto Fernandez Sainz | Xacobeo-Galicia | + 15:40 | + 15:40 |
| 86 | Stéphane Poulhiès | AG2R La Mondiale | + 16:03 | + 16:03 |
| 87 | Cédric Pineau | AG2R La Mondiale | + 16:03 | + 16:03 |
| 88 | Reinier Honig | P3Transfer - Batavus | + 16:06 | + 16:06 |
| 89 | Nikita Eskov | Tinkoff Credit Systems | + 16:16 | + 16:16 |
| 90 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 16:16 | + 16:16 |
| 91 | Morten Hegreberg | Team Sparebanken Vest | + 16:50 | + 16:50 |