| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Igor Anton | Euskaltel-Euskadi | 03:48:58 | |
| 2 | Xavier Tondó | Andalucía - Cajasur | + 08 | + 08 |
| 3 | Freddy Montana | Boyaca es para Vivirla | + 09 | + 09 |
| 4 | David Arroyo | Caisse d'Epargne | + 10 | + 10 |
| 5 | Benat Intxausti | Fuji-Servetto | + 17 | + 17 |
| 6 | Patrik Sinkewitz | PSK Whirlpool - Author | + 25 | + 25 |
| 7 | Nairo Quintana | Boyaca es para Vivirla | + 36 | + 36 |
| 8 | David de La Fuente | Fuji-Servetto | + 44 | + 44 |
| 9 | Arkaitz Durán | Fuji-Servetto | + 51 | + 51 |
| 10 | Guillaume Pont | EQA - Meitan Hompo - GDR | + 55 | + 55 |
| 11 | David Herrero | Xacobeo-Galicia | + 01:02 | + 01:02 |
| 12 | Walter Pedraza | SP Tableware - Gatsoulis Bikes | + 01:11 | + 01:11 |
| 13 | Gorka Verdugo | Euskaltel-Euskadi | + 01:14 | + 01:14 |
| 14 | Martin Mares | PSK Whirlpool - Author | + 01:16 | + 01:16 |
| 15 | Eduard Prades | Andorra - GrandValira | + 01:16 | + 01:16 |
| 16 | Iván Melero | Burgos Monumental - Castilla y Leon | + 01:18 | + 01:18 |
| 17 | Rafael Valls | Burgos Monumental - Castilla y Leon | + 01:22 | + 01:22 |
| 18 | Ezequiel Mosquera | Xacobeo-Galicia | + 01:24 | + 01:24 |
| 19 | Fabio Duarte | Colombia es Pasion-Coldeportes | + 01:25 | + 01:25 |
| 20 | Manuel Vazquez | Contentpolis - Ampo | + 01:28 | + 01:28 |
| 21 | Edwin Parra | Boyaca es para Vivirla | + 01:28 | + 01:28 |
| 22 | Mikel Nieve | Euskaltel-Euskadi | + 01:28 | + 01:28 |
| 23 | Raul Santamarta Valvuena | Burgos Monumental - Castilla y Leon | + 01:28 | + 01:28 |
| 24 | Jonathan Castroviejo | Orbea | + 01:32 | + 01:32 |
| 25 | Robinson Chalapud | Colombia es Pasion-Coldeportes | + 01:37 | + 01:37 |
| 26 | Jose Herrada | Contentpolis - Ampo | + 01:43 | + 01:43 |
| 27 | Miguel Minguez | Orbea | + 01:45 | + 01:45 |
| 28 | Adrian Palomares | Contentpolis - Ampo | + 01:48 | + 01:48 |
| 29 | Francisco Pérez | Caisse d'Epargne | + 01:58 | + 01:58 |
| 30 | Marcos Garcia | Xacobeo-Galicia | + 01:58 | + 01:58 |
| 31 | Alex Cano | Colombia es Pasion-Coldeportes | + 01:58 | + 01:58 |
| 32 | Romain Sicard | Orbea | + 02:00 | + 02:00 |
| 33 | Joaquim Rodríguez | Caisse d'Epargne | + 02:17 | + 02:17 |
| 34 | Alexei Shchebelin | SP Tableware - Gatsoulis Bikes | + 02:19 | + 02:19 |
| 35 | Byron Guama | Burgos Monumental - Castilla y Leon | + 02:21 | + 02:21 |
| 36 | Javier Etxarri | Contentpolis - Ampo | + 02:22 | + 02:22 |
| 37 | David Belda | Boyaca es para Vivirla | + 02:27 | + 02:27 |
| 38 | Javier Ramirez | Andalucía - Cajasur | + 02:31 | + 02:31 |
| 39 | Gregor Gazvoda | EQA - Meitan Hompo - GDR | + 02:31 | + 02:31 |
| 40 | Miyataka Shimizu | EQA - Meitan Hompo - GDR | + 02:31 | + 02:31 |
| 41 | Julian Sanchez | Contentpolis - Ampo | + 02:31 | + 02:31 |
| 42 | Sergio Escobar Roure | Andorra - GrandValira | + 02:34 | + 02:34 |
| 43 | David García Dapena | Xacobeo-Galicia | + 02:40 | + 02:40 |
| 44 | Pedro Merino Criado | Fuji-Servetto | + 02:43 | + 02:43 |
| 45 | Jose Ruiz Sanchez | Andalucía - Cajasur | + 02:43 | + 02:43 |
| 46 | Sebastien Ivars | EQA - Meitan Hompo - GDR | + 02:43 | + 02:43 |
| 47 | Mikel Landa | Orbea | + 02:43 | + 02:43 |
| 48 | Oscar Garcia-casarrubios | Contentpolis - Ampo | + 02:43 | + 02:43 |
| 49 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 02:53 | + 02:53 |
| 50 | José Cobo Juan | Fuji-Servetto | + 02:53 | + 02:53 |
| 51 | Eduard Vorganov | Xacobeo-Galicia | + 02:53 | + 02:53 |
| 52 | Alberto Fernandez | Fuji-Servetto | + 02:53 | + 02:53 |
| 53 | Jaume Rovira | Andorra - GrandValira | + 02:53 | + 02:53 |
| 54 | Raul Garcia de Mateos | Andorra - GrandValira | + 02:53 | + 02:53 |
| 55 | Ion Izagirre | Orbea | + 03:01 | + 03:01 |
| 56 | Alejandro Serna Toro | Boyaca es para Vivirla | + 03:01 | + 03:01 |
| 57 | Diego Gallego | Burgos Monumental - Castilla y Leon | + 03:07 | + 03:07 |
| 58 | Angel Vallejo Dominquez | Andorra - GrandValira | + 03:10 | + 03:10 |
| 59 | Jorge Azanza | Euskaltel-Euskadi | + 03:11 | + 03:11 |
| 60 | José Martínez Francisco | Andalucía - Cajasur | + 03:21 | + 03:21 |
| 61 | Andoni Blazquez Berasarte | Orbea | + 03:30 | + 03:30 |
| 62 | Ricardo Garcia | Orbea | + 03:45 | + 03:45 |
| 63 | Alejandro Ramirez | Colombia es Pasion-Coldeportes | + 03:52 | + 03:52 |
| 64 | Dmitri Puzanov | Andorra - GrandValira | + 04:02 | + 04:02 |
| 65 | Gustavo Dominguez Lemos | Xacobeo-Galicia | + 04:02 | + 04:02 |
| 66 | Jesus Rosendo Prado | Andalucía - Cajasur | + 04:12 | + 04:12 |
| 67 | Aitor Perez Arrieta | Contentpolis - Ampo | + 04:15 | + 04:15 |
| 68 | Ángel Gómez | Fuji-Servetto | + 04:17 | + 04:17 |
| 69 | Alberto Fernandez Sainz | Xacobeo-Galicia | + 04:35 | + 04:35 |
| 70 | Mathieu Perget | Caisse d'Epargne | + 04:51 | + 04:51 |
| 71 | Gustavo Veloso | Xacobeo-Galicia | + 04:51 | + 04:51 |
| 72 | Xabier Zandio | Caisse d'Epargne | + 04:51 | + 04:51 |
| 73 | Antonio Carrasco Jose | Andalucía - Cajasur | + 04:51 | + 04:51 |
| 74 | Nariyuki Masuda | EQA - Meitan Hompo - GDR | + 05:00 | + 05:00 |
| 75 | Javier Estrada Juan | Andalucía - Cajasur | + 05:22 | + 05:22 |
| 76 | Mathieu Drujon | Caisse d'Epargne | + 05:28 | + 05:28 |
| 77 | Arnold Jeannesson | Caisse d'Epargne | + 05:36 | + 05:36 |
| 78 | Mikel Ilundain Tirapu | Orbea | + 06:22 | + 06:22 |
| 79 | Anastasios Kourmpetis | SP Tableware - Gatsoulis Bikes | + 06:22 | + 06:22 |
| 80 | Delio Fernandez | Xacobeo-Galicia | + 06:23 | + 06:23 |
| 81 | Manuel Ortega | Andalucía - Cajasur | + 06:33 | + 06:33 |
| 82 | David Francisco Delgado | Burgos Monumental - Castilla y Leon | + 06:45 | + 06:45 |
| 83 | Eritz Ruiz | Orbea | + 07:09 | + 07:09 |
| 84 | Daniel Sesma Sorbet | Orbea | + 07:09 | + 07:09 |
| 85 | Tomas Buchacek | PSK Whirlpool - Author | + 07:14 | + 07:14 |
| 86 | Frantisek Kloucek | PSK Whirlpool - Author | + 07:14 | + 07:14 |
| 87 | Georgios Karatzios | SP Tableware - Gatsoulis Bikes | + 07:14 | + 07:14 |
| 88 | Aitor Aznar Torres | Andorra - GrandValira | + 07:44 | + 07:44 |
| 89 | Martin Montenegro Adaro Jorge | Andalucía - Cajasur | + 07:49 | + 07:49 |
| 90 | Michael Rodriguez | Boyaca es para Vivirla | + 08:01 | + 08:01 |
| 91 | Antonio Olmo | Boyaca es para Vivirla | + 08:01 | + 08:01 |
| 92 | Wilson Marentes | Colombia es Pasion-Coldeportes | + 09:30 | + 09:30 |
| 93 | Andres Ardila Cano Fader | Colombia es Pasion-Coldeportes | + 09:35 | + 09:35 |
| 94 | Alonso Cano Jairo | Colombia es Pasion-Coldeportes | + 09:35 | + 09:35 |
| 95 | Pablo Urtasun | Euskaltel-Euskadi | + 10:00 | + 10:00 |
| 96 | Iñaki Isasi | Euskaltel-Euskadi | + 10:00 | + 10:00 |
| 97 | José Oroz Juan | Euskaltel-Euskadi | + 10:00 | + 10:00 |
| 98 | Lluis Mas | Burgos Monumental - Castilla y Leon | + 10:07 | + 10:07 |
| 99 | Iban Mayoz | Xacobeo-Galicia | + 10:20 | + 10:20 |
| 100 | Sergio Carrasco Garcia | Andalucía - Cajasur | + 10:24 | + 10:24 |