| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Paolo Bettini | Quick Step - Innergetic | 06:09:06 | |
| 2 | Samuel Sánchez | Euskaltel-Euskadi | + 08 | + 08 |
| 3 | Fabian Wegmann | Gerolsteiner | + 08 | + 08 |
| 4 | Cristian Moreni | Cofidis | + 14 | + 14 |
| 5 | Davide Rebellin | Gerolsteiner | + 46 | + 46 |
| 6 | Matteo Carrara | Lampre-Fondital | + 46 | + 46 |
| 7 | Fränk Schleck | Team CSC | + 46 | + 46 |
| 8 | Michael Boogerd | Rabobank | + 48 | + 48 |
| 9 | Danilo Di Luca | Liquigas | + 02:32 | + 02:32 |
| 10 | Andrea Pagoto | Ceramica Panaria - Navigare | + 03:53 | + 03:53 |
| 11 | Ruggero Marzoli | + 04:03 | + 04:03 | |
| 12 | Mikhaylo Khalilov | Team LPR | + 04:03 | + 04:03 |
| 13 | Fabio Sacchi | Team Milram | + 04:03 | + 04:03 |
| 14 | Andrea Moletta | Gerolsteiner | + 04:03 | + 04:03 |
| 15 | Vladimir Gusev | Discovery Channel | + 04:03 | + 04:03 |
| 16 | Staf Scheirlinckx | Cofidis | + 04:03 | + 04:03 |
| 17 | Vicente Reynès | Caisse d'Epargne - Illes Balears | + 04:03 | + 04:03 |
| 18 | Daniele Nardello | T-Mobile Team | + 04:03 | + 04:03 |
| 19 | Mirko Celestino | Team Milram | + 04:03 | + 04:03 |
| 20 | Igor Anton | Euskaltel-Euskadi | + 04:03 | + 04:03 |
| 21 | Vladimir Efimkin | Caisse d'Epargne - Illes Balears | + 04:03 | + 04:03 |
| 22 | Gerben Löwik | Rabobank | + 04:03 | + 04:03 |
| 23 | Alexandr Kolobnev | Rabobank | + 04:03 | + 04:03 |
| 24 | Xavier Florencio | Bouygues Telecom | + 04:03 | + 04:03 |
| 25 | Niklas Axelsson | Selle Italia - Serramenti | + 04:03 | + 04:03 |
| 26 | Asle Arvesen Kurt | Team CSC | + 04:03 | + 04:03 |
| 27 | Alexander Arekeev | Acqua e Sapone - Caffe Mokambo | + 04:03 | + 04:03 |
| 28 | Oliver Zaugg | Saunier Duval - Prodir | + 04:03 | + 04:03 |
| 29 | Pedro Arreitunandia | Barloworld | + 04:03 | + 04:03 |
| 30 | Daniele de Paoli | Team LPR | + 04:03 | + 04:03 |
| 31 | Stéphane Goubert | AG2R Prévoyance | + 04:03 | + 04:03 |
| 32 | Cédric Vasseur | Quick Step - Innergetic | + 04:03 | + 04:03 |
| 33 | Pieter Weening | Rabobank | + 04:03 | + 04:03 |
| 34 | John Gadret | AG2R Prévoyance | + 04:03 | + 04:03 |
| 35 | Marco Pinotti | Saunier Duval - Prodir | + 04:03 | + 04:03 |
| 36 | Matteo Tosatto | Quick Step - Innergetic | + 04:03 | + 04:03 |
| 37 | Íñigo Cuesta | Team CSC | + 04:03 | + 04:03 |
| 38 | Sylwester Szmyd | Lampre-Fondital | + 04:10 | + 04:10 |
| 39 | Andrea Peron | Team CSC | + 04:10 | + 04:10 |
| 40 | Francesco Bellotti | Crédit Agricole | + 04:10 | + 04:10 |
| 41 | Pablo Lastras | Caisse d'Epargne - Illes Balears | + 04:10 | + 04:10 |
| 42 | Filippo Pozzato | Quick Step - Innergetic | + 04:13 | + 04:13 |
| 43 | Alexandre Botcharov | Crédit Agricole | + 04:13 | + 04:13 |
| 44 | Nicolas Vogondy | Crédit Agricole | + 04:13 | + 04:13 |
| 45 | Hubert Schwab | Quick Step - Innergetic | + 04:13 | + 04:13 |
| 46 | Luca Mazzanti | Ceramica Panaria - Navigare | + 04:13 | + 04:13 |
| 47 | Maxime Monfort | Cofidis | + 04:41 | + 04:41 |
| 48 | David Canada | Saunier Duval - Prodir | + 04:42 | + 04:42 |
| 49 | Mauro Santambrogio | Lampre-Fondital | + 04:42 | + 04:42 |
| 50 | Riccardo Riccò | Saunier Duval - Prodir | + 04:42 | + 04:42 |
| 51 | Theo Eltink | Rabobank | + 05:00 | + 05:00 |
| 52 | Santo Anzà | Selle Italia - Serramenti | + 05:00 | + 05:00 |
| 53 | Karsten Kroon | Team CSC | + 05:00 | + 05:00 |
| 54 | Domenico Pozzovivo | Ceramica Panaria - Navigare | + 06:04 | + 06:04 |
| 55 | Cadel Evans | Davitamon - Lotto | + 06:23 | + 06:23 |
| 56 | Alessandro Ballan | Lampre-Fondital | + 06:23 | + 06:23 |
| 57 | Georg Totschnig | Gerolsteiner | + 07:20 | + 07:20 |
| 58 | Philip Deignan | AG2R Prévoyance | + 08:00 | + 08:00 |
| 59 | Andrea Noè | Liquigas | + 08:00 | + 08:00 |
| 60 | Wim van Huffel | Davitamon - Lotto | + 10:34 | + 10:34 |
| 61 | Stijn Devolder | Discovery Channel | + 10:34 | + 10:34 |
| 62 | Volodymir Gustov | Team CSC | + 10:34 | + 10:34 |
| 63 | Simone Masciarelli | Acqua e Sapone - Caffe Mokambo | + 10:34 | + 10:34 |
| 64 | Andrea Masciarelli | Acqua e Sapone - Caffe Mokambo | + 10:34 | + 10:34 |
| 65 | Benoît Poilvet | Crédit Agricole | + 13:18 | + 13:18 |
| 66 | Alessandro Vanotti | Team Milram | + 14:17 | + 14:17 |
| 67 | Giovanni Visconti | Team Milram | + 15:40 | + 15:40 |
| 68 | Andriy Grivko | Team Milram | + 15:40 | + 15:40 |
| 69 | Matej Jurco | Team Milram | + 15:40 | + 15:40 |
| 70 | Ivan Santaromita | Quick Step - Innergetic | + 15:40 | + 15:40 |
| 71 | Christophe Riblon | AG2R Prévoyance | + 15:40 | + 15:40 |
| 72 | Fumiyuki Beppu | Discovery Channel | + 15:40 | + 15:40 |
| 73 | Michael Schär | Phonak Hearing Systems | + 15:40 | + 15:40 |
| 74 | Christophe Le Mével | Crédit Agricole | + 15:40 | + 15:40 |
| 75 | Guido Trentin | Saunier Duval - Prodir | + 15:40 | + 15:40 |
| 76 | Philippe Schnyder | Selle Italia - Serramenti | + 15:40 | + 15:40 |
| 77 | Sergio Barbero | Selle Italia - Serramenti | + 15:40 | + 15:40 |
| 78 | Steve Morabito | Phonak Hearing Systems | + 15:40 | + 15:40 |
| 79 | Preben van Hecke | Davitamon - Lotto | + 15:40 | + 15:40 |
| 80 | Sven Krauss | Gerolsteiner | + 15:40 | + 15:40 |
| 81 | Morris Possoni | Lampre-Fondital | + 15:40 | + 15:40 |
| 82 | Volodymyr Bileka | Discovery Channel | + 15:40 | + 15:40 |
| 83 | Lorenzo Bernucci | T-Mobile Team | + 15:40 | + 15:40 |
| 84 | Michael Rogers | T-Mobile Team | + 15:40 | + 15:40 |
| 85 | Carlos Barredo | Astana - Würth Team | + 15:40 | + 15:40 |
| 86 | Iñaki Isasi | Euskaltel-Euskadi | + 15:40 | + 15:40 |
| 87 | Gregory Rast | Phonak Hearing Systems | + 15:40 | + 15:40 |
| 88 | Chris Horner | Davitamon - Lotto | + 15:40 | + 15:40 |
| 89 | Amaël Moinard | Cofidis | + 15:40 | + 15:40 |
| 90 | Yoann Le Boulanger | Bouygues Telecom | + 15:40 | + 15:40 |
| 91 | Yuriy Metlushenko | Team LPR | + 15:40 | + 15:40 |
| 92 | Javier Mejias | Saunier Duval - Prodir | + 15:40 | + 15:40 |
| 93 | Dario Cioni | Liquigas | + 15:40 | + 15:40 |
| 94 | Davide Vigano | Quick Step - Innergetic | + 15:40 | + 15:40 |
| 95 | Lars Bak | Team CSC | + 16:02 | + 16:02 |
| 96 | Gene Bates | Team LPR | + 16:44 | + 16:44 |
| 97 | Diego Caccia | Barloworld | + 16:44 | + 16:44 |