| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Fabian Cancellara | Team CSC | 06:07:54 | |
| 2 | Tom Boonen | Quick Step - Innergetic | + 01:49 | + 01:49 |
| 3 | Alessandro Ballan | Lampre-Fondital | + 01:49 | + 01:49 |
| 4 | Antonio Flecha Juan | Rabobank | + 01:49 | + 01:49 |
| 5 | Bernhard Eisel | Française des Jeux | + 03:25 | + 03:25 |
| 6 | Steffen Wesemann | T-Mobile Team | + 05:35 | + 05:35 |
| 7 | Frédéric Guesdon | Française des Jeux | + 06:31 | + 06:31 |
| 8 | Bert Roesems | Davitamon - Lotto | + 06:44 | + 06:44 |
| 9 | Christophe Mengin | Française des Jeux | + 06:44 | + 06:44 |
| 10 | Staf Scheirlinckx | Cofidis | + 06:45 | + 06:45 |
| 11 | Pedro Horrillo | Rabobank | + 06:49 | + 06:49 |
| 12 | Erik Zabel | Team Milram | + 06:49 | + 06:49 |
| 13 | Steven de Jongh | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 14 | Léon van Bon | Davitamon - Lotto | + 06:49 | + 06:49 |
| 15 | Filippo Pozzato | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 16 | Aart Vierhouten | Skil - Shimano | + 06:49 | + 06:49 |
| 17 | Baden Cooke | Unibet.com | + 06:49 | + 06:49 |
| 18 | Martin Elmiger | Phonak Hearing Systems | + 06:49 | + 06:49 |
| 19 | Lars Michaelsen | Team CSC | + 06:49 | + 06:49 |
| 20 | Marco Serpellini | Unibet.com | + 06:49 | + 06:49 |
| 21 | Anthony Geslin | Bouygues Telecom | + 06:49 | + 06:49 |
| 22 | Marcus Burghardt | T-Mobile Team | + 06:49 | + 06:49 |
| 23 | Mathew Hayman | Rabobank | + 06:49 | + 06:49 |
| 24 | Roger Hammond | Discovery Channel | + 06:49 | + 06:49 |
| 25 | Jimmy Casper | Cofidis | + 06:49 | + 06:49 |
| 26 | Asle Arvesen Kurt | Team CSC | + 06:49 | + 06:49 |
| 27 | Enrico Poitschke | Team Milram | + 06:49 | + 06:49 |
| 28 | Henk Vogels | Davitamon - Lotto | + 06:49 | + 06:49 |
| 29 | Arnaud Labbe | Bouygues Telecom | + 06:49 | + 06:49 |
| 30 | Ralf Grabsch | Team Milram | + 06:49 | + 06:49 |
| 31 | Allan Johansen | Team CSC | + 06:49 | + 06:49 |
| 32 | Nico Mattan | Davitamon - Lotto | + 06:49 | + 06:49 |
| 33 | Jeremy Hunt | Unibet.com | + 06:49 | + 06:49 |
| 34 | Marco Milesi | Liquigas | + 06:49 | + 06:49 |
| 35 | Kevin Hulsmans | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 36 | Nicolas Portal | Caisse d'Epargne - Illes Balears | + 06:49 | + 06:49 |
| 37 | Marc Wauters | Rabobank | + 06:49 | + 06:49 |
| 38 | Andy Flickinger | Bouygues Telecom | + 06:49 | + 06:49 |
| 39 | Christophe Laurent | Agritubel | + 06:49 | + 06:49 |
| 40 | Frank Høj | Gerolsteiner | + 06:49 | + 06:49 |
| 41 | Aivaras Baranauskas | Agritubel | + 06:49 | + 06:49 |
| 42 | Andreas Klier | T-Mobile Team | + 06:49 | + 06:49 |
| 43 | Marcus Ljungqvist | Team CSC | + 06:49 | + 06:49 |
| 44 | Servais Knaven | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 45 | Alessandro Cortinovis | Team Milram | + 06:49 | + 06:49 |
| 46 | Martin Müller | Team Milram | + 06:49 | + 06:49 |
| 47 | Jean-patrick Nazon | AG2R Prévoyance | + 06:49 | + 06:49 |
| 48 | Jimmy Engoulvent | Crédit Agricole | + 06:49 | + 06:49 |
| 49 | Bradley Wiggins | Cofidis | + 06:49 | + 06:49 |
| 50 | Imanol Erviti | Caisse d'Epargne - Illes Balears | + 06:49 | + 06:49 |
| 51 | Vicente García José | Caisse d'Epargne - Illes Balears | + 06:49 | + 06:49 |
| 52 | Wilfried Cretskens | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 53 | Cedric Coutouly | Agritubel | + 06:49 | + 06:49 |
| 54 | Wim Vansevenant | Davitamon - Lotto | + 06:49 | + 06:49 |
| 55 | Paolo Fornaciari | Lampre-Fondital | + 06:49 | + 06:49 |
| 56 | Enrico Franzoi | Lampre-Fondital | + 06:49 | + 06:49 |
| 57 | Nick Nuyens | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 58 | Sébastien Hinault | Crédit Agricole | + 06:49 | + 06:49 |
| 59 | Kevin van Impe | Quick Step - Innergetic | + 06:49 | + 06:49 |
| 60 | Marc de Maar | Rabobank | + 07:24 | + 07:24 |
| 61 | Gert Steegmans | Davitamon - Lotto | + 09:32 | + 09:32 |
| 62 | László Bodrogi | Crédit Agricole | + 10:53 | + 10:53 |
| 63 | Jan Boven | Rabobank | + 11:18 | + 11:18 |
| 64 | Tomas Vaitkus | AG2R Prévoyance | + 13:13 | + 13:13 |
| 65 | Sebastian Langeveld | Skil - Shimano | + 15:58 | + 15:58 |
| 66 | Matthew Wilson | Unibet.com | + 15:58 | + 15:58 |
| 67 | Vicente Reynès | Caisse d'Epargne - Illes Balears | + 16:44 | + 16:44 |
| 68 | David Kopp | Gerolsteiner | + 19:07 | + 19:07 |
| 69 | Robert Hunter | Phonak Hearing Systems | + 19:20 | + 19:20 |
| 70 | Gustav Larsson | Française des Jeux | + 19:20 | + 19:20 |
| 71 | Erki Pütsep | AG2R Prévoyance | + 19:20 | + 19:20 |
| 72 | Yuriy Metlushenko | Team LPR | + 19:20 | + 19:20 |
| 73 | Heinrich Haussler | Gerolsteiner | + 19:20 | + 19:20 |
| 74 | Matthew White | Discovery Channel | + 19:20 | + 19:20 |
| 75 | William Bonnet | Crédit Agricole | + 19:20 | + 19:20 |
| 76 | Luciano Pagliarini | Saunier Duval - Prodir | + 19:20 | + 19:20 |
| 77 | Koen de Kort | Astana - Würth Team | + 19:20 | + 19:20 |
| 78 | Peter Wrolich | Gerolsteiner | + 19:20 | + 19:20 |
| 79 | Aaron Kemps | Astana - Würth Team | + 19:20 | + 19:20 |
| 80 | Koldo Fernandez | Euskaltel-Euskadi | + 19:20 | + 19:20 |
| 81 | Piet Rooijakkers | Skil - Shimano | + 19:20 | + 19:20 |
| 82 | Hervé Duclos-lassalle | Cofidis | + 19:20 | + 19:20 |
| 83 | Sjef de Wilde | Landbouwkrediet - Colnago | + 19:20 | + 19:20 |
| 84 | Christophe Agnolutto | Agritubel | + 19:20 | + 19:20 |
| 85 | Florent Brard | Caisse d'Epargne - Illes Balears | + 19:20 | + 19:20 |
| 86 | Ludovic Auger | Française des Jeux | + 19:20 | + 19:20 |
| 87 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 19:20 | + 19:20 |
| 88 | Rony Martias | Bouygues Telecom | + 19:20 | + 19:20 |
| 89 | Mathieu Claude | Bouygues Telecom | + 19:20 | + 19:20 |
| 90 | Maarten Tjallingii | Skil - Shimano | + 19:20 | + 19:20 |
| 91 | Markel Irizar | Euskaltel-Euskadi | + 19:20 | + 19:20 |
| 92 | Kevin Neirynck | Landbouwkrediet - Colnago | + 19:20 | + 19:20 |
| 93 | Mauro Da Dalto | Liquigas | + 19:20 | + 19:20 |
| 94 | Stéphane Bergès | Agritubel | + 19:20 | + 19:20 |
| 95 | Franck Renier | Bouygues Telecom | + 19:20 | + 19:20 |
| 96 | Tristan Valentin | Cofidis | + 19:20 | + 19:20 |
| 97 | Bastiaan Giling | T-Mobile Team | + 19:20 | + 19:20 |
| 98 | Laurent Mangel | AG2R Prévoyance | + 19:20 | + 19:20 |
| 99 | Paul Martens | Skil - Shimano | + 19:20 | + 19:20 |
| 100 | Andre Korff | T-Mobile Team | + 19:20 | + 19:20 |
| 101 | Gilles Canouet | Agritubel | + 19:20 | + 19:20 |
| 102 | Joseba Zubeldia | Euskaltel-Euskadi | + 19:32 | + 19:32 |
| 103 | Mikhaylo Khalilov | Team LPR | + 19:32 | + 19:32 |
| 104 | Dimitri Konyshev | Team LPR | + 19:36 | + 19:36 |
| 105 | Rik Reinerink | Skil - Shimano | + 19:38 | + 19:38 |
| 106 | Jurgen van Loocke | Landbouwkrediet - Colnago | + 19:38 | + 19:38 |
| 107 | Daniele Righi | Lampre-Fondital | + 19:38 | + 19:38 |
| 108 | Stefano Zanini | Liquigas | + 19:38 | + 19:38 |
| 109 | Matthé Pronk | Unibet.com | + 30:56 | + 30:56 |
| 110 | Ángel Gómez | Saunier Duval - Prodir | + 30:56 | + 30:56 |
| 111 | Erwin Thijs | Unibet.com | + 34:34 | + 34:34 |
| 112 | Aurelien Clerc | Phonak Hearing Systems | + 34:34 | + 34:34 |