| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Tom Boonen | Quick Step | 06:15:53 | |
| 2 | Filippo Pozzato | Team Katusha | + 47 | + 47 |
| 3 | Thor Hushovd | Cervelo TestTeam | + 01:17 | + 01:17 |
| 4 | Leif Hoste | Silence - Lotto | + 01:17 | + 01:17 |
| 5 | Johan Vansummeren | Silence - Lotto | + 01:22 | + 01:22 |
| 6 | Antonio Flecha Juan | Rabobank | + 02:14 | + 02:14 |
| 7 | Heinrich Haussler | Cervelo TestTeam | + 03:13 | + 03:13 |
| 8 | Sylvain Chavanel | Quick Step | + 03:15 | + 03:15 |
| 9 | Manuel Quinziato | Liquigas | + 05:00 | + 05:00 |
| 10 | Matti Breschel | Team Saxo Bank | + 05:29 | + 05:29 |
| 11 | Wouter Weylandt | Quick Step | + 05:29 | + 05:29 |
| 12 | Andreas Klier | Cervelo TestTeam | + 05:29 | + 05:29 |
| 13 | Frédéric Guesdon | Française des Jeux | + 05:29 | + 05:29 |
| 14 | Kevin van Impe | Quick Step | + 06:15 | + 06:15 |
| 15 | Roger Hammond | Cervelo TestTeam | + 06:15 | + 06:15 |
| 16 | Asle Arvesen Kurt | Team Saxo Bank | + 06:15 | + 06:15 |
| 17 | Niki Terpstra | Team Milram | + 06:15 | + 06:15 |
| 18 | Bert Scheirlinckx | Landbouwkrediet - Colnago | + 06:19 | + 06:19 |
| 19 | Jeremy Hunt | Cervelo TestTeam | + 06:32 | + 06:32 |
| 20 | Marcel Sieberg | Team Columbia - HTC | + 06:32 | + 06:32 |
| 21 | Mathew Hayman | Rabobank | + 06:32 | + 06:32 |
| 22 | Yauheni Hutarovich | Française des Jeux | + 06:32 | + 06:32 |
| 23 | Angelo Furlan | Lampre-NGC | + 06:32 | + 06:32 |
| 24 | Damien Gaudin | BBOX Bouygues Telecom | + 06:32 | + 06:32 |
| 25 | Bradley Wiggins | Garmin-Slipstream | + 06:32 | + 06:32 |
| 26 | Saïd Haddou | BBOX Bouygues Telecom | + 06:32 | + 06:32 |
| 27 | Maarten Wynants | Quick Step | + 06:32 | + 06:32 |
| 28 | Staf Scheirlinckx | Silence - Lotto | + 06:32 | + 06:32 |
| 29 | Sébastien Minard | Cofidis | + 06:32 | + 06:32 |
| 30 | Marcus Ljungqvist | Team Saxo Bank | + 06:32 | + 06:32 |
| 31 | Nicolas Jalabert | Agritubel | + 06:32 | + 06:32 |
| 32 | Matthew Goss | Team Saxo Bank | + 06:32 | + 06:32 |
| 33 | Gregory Rast | Astana | + 06:32 | + 06:32 |
| 34 | Filip Meirhaeghe | Landbouwkrediet - Colnago | + 06:32 | + 06:32 |
| 35 | Florent Brard | Cofidis | + 06:32 | + 06:32 |
| 36 | Servais Knaven | Team Milram | + 06:32 | + 06:32 |
| 37 | Nikolai Trusov | Team Katusha | + 06:32 | + 06:32 |
| 38 | Greg van Avermaet | Silence - Lotto | + 06:32 | + 06:32 |
| 39 | Joost Posthuma | Rabobank | + 06:32 | + 06:32 |
| 40 | Imanol Erviti | Caisse d'Epargne | + 06:32 | + 06:32 |
| 41 | Björn Leukemans | Vacansoleil | + 06:32 | + 06:32 |
| 42 | Pieter Vanspeybrouck | Topsport Vlaanderen - Mercator | + 06:32 | + 06:32 |
| 43 | Rony Martias | BBOX Bouygues Telecom | + 06:32 | + 06:32 |
| 44 | George Hincapie | Team Columbia - HTC | + 06:32 | + 06:32 |
| 45 | Lars Bak | Team Saxo Bank | + 06:32 | + 06:32 |
| 46 | Gabriel Rasch | Cervelo TestTeam | + 06:32 | + 06:32 |
| 47 | Bernhard Eisel | Team Columbia - HTC | + 06:43 | + 06:43 |
| 48 | Kasper Klostergaard | Team Saxo Bank | + 06:45 | + 06:45 |
| 49 | Fabian Cancellara | Team Saxo Bank | + 06:48 | + 06:48 |
| 50 | Yaroslav Popovych | Astana | + 09:09 | + 09:09 |
| 51 | Greg Henderson | Team Columbia - HTC | + 11:11 | + 11:11 |
| 52 | Aleksandr Kuschynski | Liquigas | + 11:11 | + 11:11 |
| 53 | Marco Bandiera | Lampre-NGC | + 11:11 | + 11:11 |
| 54 | Alexey Markov | Team Katusha | + 11:11 | + 11:11 |
| 55 | Stijn Devolder | Quick Step | + 11:11 | + 11:11 |
| 56 | Tom Veelers | Skil - Shimano | + 12:12 | + 12:12 |
| 57 | Mauro Da Dalto | Lampre-NGC | + 12:12 | + 12:12 |
| 58 | Rui Costa | Caisse d'Epargne | + 12:12 | + 12:12 |
| 59 | Matthieu Ladagnous | Française des Jeux | + 12:12 | + 12:12 |
| 60 | Renaud Dion | AG2R La Mondiale | + 12:12 | + 12:12 |
| 61 | Wesley Sulzberger | Française des Jeux | + 12:12 | + 12:12 |
| 62 | Edvald Boasson-hagen | Team Columbia - HTC | + 12:12 | + 12:12 |
| 63 | Maarten Tjallingii | Rabobank | + 12:12 | + 12:12 |
| 64 | Steven Cozza | Garmin-Slipstream | + 12:12 | + 12:12 |
| 65 | Marcus Burghardt | Team Columbia - HTC | + 12:12 | + 12:12 |
| 66 | Arnaud Coyot | Caisse d'Epargne | + 12:12 | + 12:12 |
| 67 | Aitor Galdos | Euskaltel-Euskadi | + 12:12 | + 12:12 |
| 68 | Alexandre Moos | BMC Racing Team | + 16:57 | + 16:57 |
| 69 | Aart Vierhouten | Vacansoleil | + 17:30 | + 17:30 |
| 70 | Björn Schröder | Team Milram | + 17:36 | + 17:36 |
| 71 | Pedro Horrillo | Rabobank | + 17:36 | + 17:36 |
| 72 | Lloyd Mondory | AG2R La Mondiale | + 17:36 | + 17:36 |
| 73 | Markus Eichler | Team Milram | + 17:36 | + 17:36 |
| 74 | Enrico Franzoi | Liquigas | + 17:36 | + 17:36 |
| 75 | Koen Barbe | Landbouwkrediet - Colnago | + 17:36 | + 17:36 |
| 76 | Christophe Laurent | Agritubel | + 17:36 | + 17:36 |
| 77 | Alexandre Blain | Cofidis | + 17:36 | + 17:36 |
| 78 | Stijn Neirynck | Topsport Vlaanderen - Mercator | + 17:36 | + 17:36 |
| 79 | Cyril Lemoine | Skil - Shimano | + 17:36 | + 17:36 |
| 80 | Martin Velits | Team Milram | + 17:36 | + 17:36 |
| 81 | Emilien Berges | Agritubel | + 17:36 | + 17:36 |
| 82 | Floris Goesinnen | Skil - Shimano | + 17:36 | + 17:36 |
| 83 | Markel Irizar | Euskaltel-Euskadi | + 17:36 | + 17:36 |
| 84 | Anders Lund | Team Saxo Bank | + 17:36 | + 17:36 |
| 85 | Yoann Offredo | Française des Jeux | + 17:36 | + 17:36 |
| 86 | Bert de Backer | Skil - Shimano | + 17:36 | + 17:36 |
| 87 | Arnaud Labbe | BBOX Bouygues Telecom | + 17:36 | + 17:36 |
| 88 | Brent Bookwalter | BMC Racing Team | + 17:36 | + 17:36 |
| 89 | Marcin Sapa | Lampre-NGC | + 17:36 | + 17:36 |
| 90 | Michael Barry | Team Columbia - HTC | + 17:36 | + 17:36 |
| 91 | Kevin de Weert | Quick Step | + 17:36 | + 17:36 |
| 92 | Daniel Oss | Liquigas | + 17:36 | + 17:36 |
| 93 | Michael Schär | Astana | + 17:36 | + 17:36 |
| 94 | Sebastian Langeveld | Rabobank | + 17:46 | + 17:46 |
| 95 | Chris Sutton | Garmin-Slipstream | + 17:46 | + 17:46 |
| 96 | Romain Villa | Cofidis | + 17:46 | + 17:46 |
| 97 | Daniele Righi | Lampre-NGC | + 17:46 | + 17:46 |
| 98 | Martijn Maaskant | Garmin-Slipstream | + 17:46 | + 17:46 |
| 99 | Mike Friedman | Garmin-Slipstream | + 17:48 | + 17:48 |