| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Stuart O'grady | Team CSC | 06:09:07 | |
| 2 | Antonio Flecha Juan | Rabobank | + 52 | + 52 |
| 3 | Steffen Wesemann | Team Wiesenhof - Felt | + 52 | + 52 |
| 4 | Björn Leukemans | Predictor - Lotto | + 53 | + 53 |
| 5 | Roberto Petito | Liquigas | + 55 | + 55 |
| 6 | Tom Boonen | Quick Step - Innergetic | + 55 | + 55 |
| 7 | Roger Hammond | T-Mobile Team | + 55 | + 55 |
| 8 | Enrico Franzoi | Lampre-Fondital | + 56 | + 56 |
| 9 | Kevin van Impe | Quick Step - Innergetic | + 01:24 | + 01:24 |
| 10 | Fabio Baldato | Lampre-Fondital | + 02:27 | + 02:27 |
| 11 | Lars Michaelsen | Team CSC | + 02:27 | + 02:27 |
| 12 | David Kopp | Gerolsteiner | + 02:28 | + 02:28 |
| 13 | Leif Hoste | Predictor - Lotto | + 02:28 | + 02:28 |
| 14 | Matti Breschel | Team CSC | + 02:28 | + 02:28 |
| 15 | Ralf Grabsch | Team Milram | + 02:28 | + 02:28 |
| 16 | Staf Scheirlinckx | Cofidis | + 02:28 | + 02:28 |
| 17 | Vladimir Gusev | Discovery Channel | + 02:28 | + 02:28 |
| 18 | Stijn Devolder | Discovery Channel | + 02:28 | + 02:28 |
| 19 | Fabian Cancellara | Team CSC | + 02:38 | + 02:38 |
| 20 | Marcus Burghardt | T-Mobile Team | + 03:43 | + 03:43 |
| 21 | Sebastien Rosseler | Quick Step - Innergetic | + 03:45 | + 03:45 |
| 22 | Stéphane Poulhiès | AG2R Prévoyance | + 05:04 | + 05:04 |
| 23 | Peter van Petegem | Quick Step - Innergetic | + 05:04 | + 05:04 |
| 24 | Martin Elmiger | AG2R Prévoyance | + 05:05 | + 05:05 |
| 25 | Frédéric Guesdon | Française des Jeux | + 05:05 | + 05:05 |
| 26 | Joaquin Rojas José | Caisse d'Epargne | + 05:05 | + 05:05 |
| 27 | Gennady Mikhailov | Astana | + 05:05 | + 05:05 |
| 28 | Bert Grabsch | T-Mobile Team | + 05:05 | + 05:05 |
| 29 | Greg van Avermaet | Predictor - Lotto | + 05:06 | + 05:06 |
| 30 | Olaf Pollack | Team Wiesenhof - Felt | + 05:07 | + 05:07 |
| 31 | Floris Goesinnen | Skil - Shimano | + 05:12 | + 05:12 |
| 32 | Nico Eeckhout | Chocolade Jacques - Topsport Vlaand | + 08:28 | + 08:28 |
| 33 | Filip Meirhaeghe | Landbouwkrediet - Tönissteiner | + 08:28 | + 08:28 |
| 34 | Nicolas Rousseau | AG2R Prévoyance | + 08:29 | + 08:29 |
| 35 | Filippo Pozzato | Liquigas | + 08:29 | + 08:29 |
| 36 | Volodymyr Bileka | Discovery Channel | + 08:31 | + 08:31 |
| 37 | Aivaras Baranauskas | Agritubel | + 09:27 | + 09:27 |
| 38 | Steven de Jongh | Quick Step - Innergetic | + 09:38 | + 09:38 |
| 39 | William Bonnet | Crédit Agricole | + 09:38 | + 09:38 |
| 40 | Marcel Sieberg | Team Milram | + 09:38 | + 09:38 |
| 41 | Rony Martias | Bouygues Telecom | + 09:38 | + 09:38 |
| 42 | Sven Krauss | Gerolsteiner | + 09:38 | + 09:38 |
| 43 | Thor Hushovd | Crédit Agricole | + 09:38 | + 09:38 |
| 44 | Florent Brard | Caisse d'Epargne | + 09:38 | + 09:38 |
| 45 | Bram de Groot | Rabobank | + 09:38 | + 09:38 |
| 46 | Marcus Ljungqvist | Team CSC | + 09:38 | + 09:38 |
| 47 | Magnus Bäckstedt | Liquigas | + 09:39 | + 09:39 |
| 48 | Andy Flickinger | Bouygues Telecom | + 09:39 | + 09:39 |
| 49 | Peter Wrolich | Gerolsteiner | + 09:39 | + 09:39 |
| 50 | Jörg Ludewig | Team Wiesenhof - Felt | + 09:39 | + 09:39 |
| 51 | Koen de Kort | Astana | + 09:39 | + 09:39 |
| 52 | Philippe Gilbert | Française des Jeux | + 09:39 | + 09:39 |
| 53 | Tom Steels | Predictor - Lotto | + 09:39 | + 09:39 |
| 54 | Ángel Gómez | Saunier Duval - Prodir | + 09:39 | + 09:39 |
| 55 | Christophe Mengin | Française des Jeux | + 09:40 | + 09:40 |
| 56 | Robert Wagner | Team Wiesenhof - Felt | + 09:40 | + 09:40 |
| 57 | Paolo Fornaciari | Lampre-Fondital | + 09:41 | + 09:41 |
| 58 | Wim Vansevenant | Predictor - Lotto | + 09:43 | + 09:43 |
| 59 | Lorenzo Bernucci | T-Mobile Team | + 09:43 | + 09:43 |
| 60 | Roy Sentjens | Predictor - Lotto | + 09:45 | + 09:45 |
| 61 | Alessandro Ballan | Lampre-Fondital | + 09:52 | + 09:52 |
| 62 | Yohann Gène | Bouygues Telecom | + 12:21 | + 12:21 |
| 63 | Iban Iriondo Uranga | Euskaltel-Euskadi | + 12:21 | + 12:21 |
| 64 | Kasper Klostergaard | Team CSC | + 12:21 | + 12:21 |
| 65 | Bernhard Eisel | T-Mobile Team | + 12:21 | + 12:21 |
| 66 | Max van Heeswijk | Rabobank | + 12:21 | + 12:21 |
| 67 | Gregory Rast | Astana | + 12:21 | + 12:21 |
| 68 | Bastiaan Giling | Team Wiesenhof - Felt | + 12:21 | + 12:21 |
| 69 | Raul Alarcon | Saunier Duval - Prodir | + 12:22 | + 12:22 |
| 70 | Servais Knaven | T-Mobile Team | + 16:22 | + 16:22 |
| 71 | Fabio Sabatini | Team Milram | + 16:22 | + 16:22 |
| 72 | Maarten Tjallingii | Skil - Shimano | + 16:22 | + 16:22 |
| 73 | Wouter Weylandt | Quick Step - Innergetic | + 16:23 | + 16:23 |
| 74 | Niki Terpstra | Team Milram | + 16:41 | + 16:41 |
| 75 | Raivis Belohvosciks | Saunier Duval - Prodir | + 16:41 | + 16:41 |
| 76 | Steven Caethoven | Chocolade Jacques - Topsport Vlaand | + 16:43 | + 16:43 |
| 77 | Christophe Laurent | Crédit Agricole | + 16:43 | + 16:43 |
| 78 | Maarten den Bakker | Skil - Shimano | + 16:43 | + 16:43 |
| 79 | Markel Irizar | Euskaltel-Euskadi | + 16:44 | + 16:44 |
| 80 | Alessandro Cortinovis | Team Milram | + 16:44 | + 16:44 |
| 81 | Koldo Fernandez | Euskaltel-Euskadi | + 16:48 | + 16:48 |
| 82 | Mathieu Heijboer | Cofidis | + 16:49 | + 16:49 |
| 83 | Andreas Klier | T-Mobile Team | + 16:56 | + 16:56 |
| 84 | Tristan Valentin | Cofidis | + 17:53 | + 17:53 |
| 85 | Pedro Horrillo | Rabobank | + 18:25 | + 18:25 |
| 86 | Carlo Westphal | Gerolsteiner | + 19:17 | + 19:17 |
| 87 | Wouter van Mechelen | Landbouwkrediet - Tönissteiner | + 20:37 | + 20:37 |
| 88 | Tom Stamsnijder | Gerolsteiner | + 20:57 | + 20:57 |
| 89 | Erki Pütsep | Bouygues Telecom | + 20:58 | + 20:58 |
| 90 | Alessandro Vanotti | Liquigas | + 27:43 | + 27:43 |
| 91 | Jan Kuyckx | Landbouwkrediet - Tönissteiner | + 28:33 | + 28:33 |
| 92 | Johan Vansummeren | Predictor - Lotto | + 31:34 | + 31:34 |
| 93 | Alexandre Usov | AG2R Prévoyance | + 34:33 | + 34:33 |
| 94 | Imanol Erviti | Caisse d'Epargne | + 34:33 | + 34:33 |
| 95 | Clément Lhotellerie | Skil - Shimano | + 34:33 | + 34:33 |
| 96 | Evert Verbist | Chocolade Jacques - Topsport Vlaand | + 34:34 | + 34:34 |