| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Tom Boonen | Quick Step | 05:58:42 | |
| 2 | Fabian Cancellara | Team CSC - Saxo Bank | + 01 | + 01 |
| 3 | Alessandro Ballan | Lampre | + 01 | + 01 |
| 4 | Martijn Maaskant | Garmin-Chipotle p/b H30 | + 03:39 | + 03:39 |
| 5 | Stuart O'grady | Team CSC - Saxo Bank | + 03:57 | + 03:57 |
| 6 | Leif Hoste | Silence - Lotto | + 03:57 | + 03:57 |
| 7 | Stijn Devolder | Quick Step | + 03:59 | + 03:59 |
| 8 | Johan Vansummeren | Silence - Lotto | + 04:35 | + 04:35 |
| 9 | George Hincapie | Team Columbia | + 05:12 | + 05:12 |
| 10 | Fabio Baldato | Lampre | + 05:12 | + 05:12 |
| 11 | Frédéric Guesdon | Française des Jeux | + 05:12 | + 05:12 |
| 12 | Antonio Flecha Juan | Rabobank | + 05:12 | + 05:12 |
| 13 | Manuel Quinziato | Liquigas | + 05:12 | + 05:12 |
| 14 | Wim de Vocht | Silence - Lotto | + 05:12 | + 05:12 |
| 15 | Staf Scheirlinckx | Cofidis | + 05:12 | + 05:12 |
| 16 | Marcus Ljungqvist | Team CSC - Saxo Bank | + 05:12 | + 05:12 |
| 17 | Bernhard Eisel | Team Columbia | + 05:20 | + 05:20 |
| 18 | Sven Krauss | Gerolsteiner | + 07:18 | + 07:18 |
| 19 | Steven de Jongh | Quick Step | + 07:18 | + 07:18 |
| 20 | Matti Breschel | Team CSC - Saxo Bank | + 07:18 | + 07:18 |
| 21 | Nick Nuyens | Cofidis | + 07:18 | + 07:18 |
| 22 | Murilo Fischer | Liquigas | + 07:18 | + 07:18 |
| 23 | Roger Hammond | Team Columbia | + 07:18 | + 07:18 |
| 24 | Wouter Weylandt | Quick Step | + 07:18 | + 07:18 |
| 25 | Christophe Mengin | Française des Jeux | + 07:18 | + 07:18 |
| 26 | Ralf Grabsch | Team Milram | + 07:20 | + 07:20 |
| 27 | Greg van Avermaet | Silence - Lotto | + 07:20 | + 07:20 |
| 28 | Steffen Wesemann | Cycle Collstrop | + 07:27 | + 07:27 |
| 29 | Tom Veelers | Skil - Shimano | + 07:34 | + 07:34 |
| 30 | Markus Eichler | Team Milram | + 07:39 | + 07:39 |
| 31 | Baden Cooke | Barloworld | + 11:08 | + 11:08 |
| 32 | Martin Elmiger | AG2R La Mondiale | + 11:26 | + 11:26 |
| 33 | Allan Johansen | Team Designa Køkken | + 11:26 | + 11:26 |
| 34 | Servais Knaven | Team Columbia | + 11:34 | + 11:34 |
| 35 | Aurelien Clerc | Bouygues Telecom | + 11:44 | + 11:44 |
| 36 | Jimmy Casper | Agritubel | + 11:44 | + 11:44 |
| 37 | Asle Arvesen Kurt | Team CSC - Saxo Bank | + 11:44 | + 11:44 |
| 38 | Jimmy Engoulvent | Crédit Agricole | + 11:44 | + 11:44 |
| 39 | Nico Eeckhout | Topsport Vlaanderen | + 11:46 | + 11:46 |
| 40 | Stijn Vandenbergh | AG2R La Mondiale | + 11:46 | + 11:46 |
| 41 | David Boucher | Landbouwkrediet - Tönissteiner | + 11:46 | + 11:46 |
| 42 | Kevin Neirynck | Landbouwkrediet - Tönissteiner | + 11:46 | + 11:46 |
| 43 | Sébastien Hinault | Crédit Agricole | + 11:55 | + 11:55 |
| 44 | Matthé Pronk | Cycle Collstrop | + 12:11 | + 12:11 |
| 45 | Jan Kuyckx | Landbouwkrediet - Tönissteiner | + 13:56 | + 13:56 |
| 46 | Paolo Fornaciari | Lampre | + 13:56 | + 13:56 |
| 47 | Filip Meirhaeghe | Landbouwkrediet - Tönissteiner | + 15:42 | + 15:42 |
| 48 | Kurt Hovelynck | Topsport Vlaanderen | + 15:42 | + 15:42 |
| 49 | Filippo Pozzato | Liquigas | + 15:42 | + 15:42 |
| 50 | László Bodrogi | Crédit Agricole | + 15:42 | + 15:42 |
| 51 | Matteo Tosatto | Quick Step | + 15:42 | + 15:42 |
| 52 | Alexandre Pichot | Bouygues Telecom | + 15:42 | + 15:42 |
| 53 | Frederik Willems | Liquigas | + 15:42 | + 15:42 |
| 54 | Pedro Horrillo | Rabobank | + 16:48 | + 16:48 |
| 55 | Joaquin Rojas José | Caisse d'Epargne | + 16:48 | + 16:48 |
| 56 | Robert Wagner | Skil - Shimano | + 16:48 | + 16:48 |
| 57 | Tyler Farrar | Garmin-Chipotle p/b H30 | + 16:48 | + 16:48 |
| 58 | Heinrich Haussler | Gerolsteiner | + 16:48 | + 16:48 |
| 59 | Kristof Goddaert | Topsport Vlaanderen | + 16:48 | + 16:48 |
| 60 | Vicente García José | Caisse d'Epargne | + 16:48 | + 16:48 |
| 61 | Steven Caethoven | Agritubel | + 16:48 | + 16:48 |
| 62 | Christian Knees | Team Milram | + 16:48 | + 16:48 |
| 63 | Erki Pütsep | Bouygues Telecom | + 16:48 | + 16:48 |
| 64 | Luciano Pagliarini | Scott - American Beef | + 16:48 | + 16:48 |
| 65 | Peter Wrolich | Gerolsteiner | + 16:48 | + 16:48 |
| 66 | Gabriel Rasch | Crédit Agricole | + 16:48 | + 16:48 |
| 67 | Chris Sutton | Garmin-Chipotle p/b H30 | + 16:48 | + 16:48 |
| 68 | Nicolas Portal | Caisse d'Epargne | + 16:48 | + 16:48 |
| 69 | Imanol Erviti | Caisse d'Epargne | + 16:48 | + 16:48 |
| 70 | Wilfried Cretskens | Quick Step | + 16:48 | + 16:48 |
| 71 | Markel Irizar | Euskaltel-Euskadi | + 16:48 | + 16:48 |
| 72 | Martin Müller | Team Milram | + 16:48 | + 16:48 |
| 73 | Frank Høj | Cofidis | + 16:48 | + 16:48 |
| 74 | Mathieu Drujon | Caisse d'Epargne | + 16:48 | + 16:48 |
| 75 | Sebastian Lang | Gerolsteiner | + 16:48 | + 16:48 |
| 76 | Aleksandr Kuschynski | Liquigas | + 16:48 | + 16:48 |
| 77 | Franck Renier | Bouygues Telecom | + 16:48 | + 16:48 |
| 78 | Cedric Coutouly | Agritubel | + 16:48 | + 16:48 |
| 79 | Koen Barbe | Topsport Vlaanderen | + 16:48 | + 16:48 |
| 80 | Paolo Longo Borghini | Barloworld | + 16:55 | + 16:55 |
| 81 | Pieter Vanspeybrouck | Topsport Vlaanderen | + 16:55 | + 16:55 |
| 82 | Geoffroy Lequatre | Agritubel | + 16:55 | + 16:55 |
| 83 | Matthieu Ladagnous | Française des Jeux | + 16:57 | + 16:57 |
| 84 | Massimiliano Mori | Lampre | + 16:57 | + 16:57 |
| 85 | Danilo Napolitano | Lampre | + 16:57 | + 16:57 |
| 86 | Mickaël Delage | Française des Jeux | + 16:57 | + 16:57 |
| 87 | Yoann Offredo | Française des Jeux | + 16:57 | + 16:57 |
| 88 | Ian Stannard | Landbouwkrediet - Tönissteiner | + 16:57 | + 16:57 |
| 89 | Fabio Sabatini | Team Milram | + 16:57 | + 16:57 |
| 90 | Marco Marcato | Cycle Collstrop | + 16:57 | + 16:57 |
| 91 | José Oroz Juan | Euskaltel-Euskadi | + 16:57 | + 16:57 |
| 92 | Mathieu Heijboer | Cofidis | + 16:57 | + 16:57 |
| 93 | Wim Vansevenant | Silence - Lotto | + 16:57 | + 16:57 |
| 94 | Marco Bandiera | Lampre | + 16:57 | + 16:57 |
| 95 | Floris Goesinnen | Skil - Shimano | + 16:57 | + 16:57 |
| 96 | Yannick Talabardon | Crédit Agricole | + 16:57 | + 16:57 |
| 97 | Hervé Duclos-lassalle | Cofidis | + 17:03 | + 17:03 |
| 98 | Rick Flens | Rabobank | + 17:03 | + 17:03 |
| 99 | Jan Boven | Rabobank | + 17:03 | + 17:03 |
| 100 | Renaud Dion | AG2R La Mondiale | + 17:03 | + 17:03 |
| 101 | Raul Alarcon | Scott - American Beef | + 17:07 | + 17:07 |
| 102 | Joost Posthuma | Rabobank | + 17:07 | + 17:07 |
| 103 | Niki Terpstra | Team Milram | + 17:07 | + 17:07 |
| 104 | Tom Leezer | Rabobank | + 17:07 | + 17:07 |
| 105 | Sébastien Minard | Cofidis | + 17:07 | + 17:07 |
| 106 | Arnaud Gérard | Française des Jeux | + 17:07 | + 17:07 |
| 107 | Vincent Jérôme | Bouygues Telecom | + 17:07 | + 17:07 |
| 108 | Roy Sentjens | Silence - Lotto | + 17:07 | + 17:07 |
| 109 | Mikhail Ignatiev | Tinkoff Credit Systems | + 18:53 | + 18:53 |
| 110 | Emilien Berges | Agritubel | + 19:21 | + 19:21 |
| 111 | Mikel Gaztanaga | Agritubel | + 19:21 | + 19:21 |
| 112 | Christophe Laurent | Garmin-Chipotle p/b H30 | + 19:21 | + 19:21 |
| 113 | Mathew Hayman | Rabobank | + 29:35 | + 29:35 |