| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Leonardo Bertagnolli | Liquigas | 05:12:42 | |
| 2 | Manuel Garate Juan | Quick Step - Innergetic | + 00 | |
| 3 | Alejandro Valverde | Caisse d'Epargne | + 18 | + 18 |
| 4 | Alessandro Ballan | Lampre-Fondital | + 18 | + 18 |
| 5 | Carlos Barredo | Quick Step - Innergetic | + 18 | + 18 |
| 6 | Mikel Astarloza | Euskaltel-Euskadi | + 18 | + 18 |
| 7 | Carlos Sastre | Team CSC | + 18 | + 18 |
| 8 | Iñigo Landaluze | Euskaltel-Euskadi | + 28 | + 28 |
| 9 | Xavier Florencio | Bouygues Telecom | + 28 | + 28 |
| 10 | Giovanni Visconti | Quick Step - Innergetic | + 37 | + 37 |
| 11 | Davide Rebellin | Gerolsteiner | + 37 | + 37 |
| 12 | Matteo Carrara | Unibet.com | + 37 | + 37 |
| 13 | Robert Gesink | Rabobank | + 37 | + 37 |
| 14 | José Cobo Juan | Saunier Duval - Prodir | + 37 | + 37 |
| 15 | Christian Vande Velde | Team CSC | + 37 | + 37 |
| 16 | Manuel Beltrán | Liquigas | + 37 | + 37 |
| 17 | Luis Arrieta José | AG2R Prévoyance | + 37 | + 37 |
| 18 | Gorka Verdugo | Euskaltel-Euskadi | + 37 | + 37 |
| 19 | Miguel Galindo Jose | Relax - GAM | + 37 | + 37 |
| 20 | Jesús Hernández | Relax - GAM | + 37 | + 37 |
| 21 | Michael Albasini | Liquigas | + 37 | + 37 |
| 22 | José Gomez | Saunier Duval - Prodir | + 39 | + 39 |
| 23 | Haimar Zubeldia | Euskaltel-Euskadi | + 41 | + 41 |
| 24 | Jurgen van de Walle | Quick Step - Innergetic | + 43 | + 43 |
| 25 | Bram Tankink | Quick Step - Innergetic | + 01:36 | + 01:36 |
| 26 | Fränk Schleck | Team CSC | + 01:36 | + 01:36 |
| 27 | Rigoberto Uran | Unibet.com | + 01:36 | + 01:36 |
| 28 | Gustav Larsson | Unibet.com | + 03:41 | + 03:41 |
| 29 | Manuele Mori | Saunier Duval - Prodir | + 03:54 | + 03:54 |
| 30 | Patxi Vila | Lampre-Fondital | + 03:54 | + 03:54 |
| 31 | Andriy Grivko | Team Milram | + 04:51 | + 04:51 |
| 32 | Beat Zberg | Gerolsteiner | + 05:25 | + 05:25 |
| 33 | Joaquin Rojas José | Caisse d'Epargne | + 05:25 | + 05:25 |
| 34 | Dries Devenyns | Predictor - Lotto | + 05:25 | + 05:25 |
| 35 | Rinaldo Nocentini | AG2R Prévoyance | + 05:25 | + 05:25 |
| 36 | Allan Davis | Discovery Channel | + 05:25 | + 05:25 |
| 37 | Alessandro Spezialetti | Liquigas | + 05:25 | + 05:25 |
| 38 | Christophe Brandt | Predictor - Lotto | + 05:25 | + 05:25 |
| 39 | Mirko Celestino | Team Milram | + 05:25 | + 05:25 |
| 40 | Kjell Carlström | Liquigas | + 05:25 | + 05:25 |
| 41 | Aitor Perez Arrieta | Caisse d'Epargne | + 05:25 | + 05:25 |
| 42 | Anthony Charteau | Crédit Agricole | + 05:25 | + 05:25 |
| 43 | William Walker | Rabobank | + 05:25 | + 05:25 |
| 44 | Alexandre Botcharov | Crédit Agricole | + 05:25 | + 05:25 |
| 45 | Pietro Caucchioli | Crédit Agricole | + 05:25 | + 05:25 |
| 46 | Matej Jurco | Team Milram | + 05:25 | + 05:25 |
| 47 | Roman Troncoso | Karpin-Galicia | + 05:25 | + 05:25 |
| 48 | Wim van Huffel | Predictor - Lotto | + 05:25 | + 05:25 |
| 49 | Carl Naibo | AG2R Prévoyance | + 05:25 | + 05:25 |
| 50 | Paolo Bossoni | Lampre-Fondital | + 05:25 | + 05:25 |
| 51 | Sébastien Minard | Cofidis | + 05:25 | + 05:25 |
| 52 | Damiano Cunego | Lampre-Fondital | + 05:25 | + 05:25 |
| 53 | David Herrero | Karpin-Galicia | + 05:25 | + 05:25 |
| 54 | Antonio Flecha Juan | Rabobank | + 05:25 | + 05:25 |
| 55 | Joaquim Rodríguez | Caisse d'Epargne | + 05:25 | + 05:25 |
| 56 | Riccardo Riccò | Saunier Duval - Prodir | + 05:25 | + 05:25 |
| 57 | David Belda | Fuerteventura - Canarias | + 05:25 | + 05:25 |
| 58 | Volodymir Gustov | Team CSC | + 05:25 | + 05:25 |
| 59 | Theo Eltink | Rabobank | + 05:25 | + 05:25 |
| 60 | Koos Moerenhout | Rabobank | + 05:25 | + 05:25 |
| 61 | Janez Brajkovic | Discovery Channel | + 05:25 | + 05:25 |
| 62 | Laurens ten Dam | Unibet.com | + 05:25 | + 05:25 |
| 63 | René Mandri | AG2R Prévoyance | + 08:46 | + 08:46 |
| 64 | Matthias Russ | Gerolsteiner | + 10:34 | + 10:34 |
| 65 | Matthew Lloyd | Predictor - Lotto | + 10:34 | + 10:34 |
| 66 | David López | Caisse d'Epargne | + 10:34 | + 10:34 |
| 67 | Iker Leonet Iza | Fuerteventura - Canarias | + 10:34 | + 10:34 |
| 68 | Raul Garcia de Mateos | Relax - GAM | + 10:34 | + 10:34 |
| 69 | Daniel Moreno | Relax - GAM | + 10:34 | + 10:34 |
| 70 | Sylvain Chavanel | Cofidis | + 10:34 | + 10:34 |
| 71 | Cédric Vasseur | Quick Step - Innergetic | + 10:34 | + 10:34 |
| 72 | David García Dapena | Karpin-Galicia | + 10:34 | + 10:34 |
| 73 | Mikel Artetxe | Fuerteventura - Canarias | + 10:34 | + 10:34 |
| 74 | Adam Hansen | T-Mobile Team | + 10:34 | + 10:34 |
| 75 | Stijn Devolder | Discovery Channel | + 10:34 | + 10:34 |
| 76 | Mario Aerts | Predictor - Lotto | + 10:34 | + 10:34 |
| 77 | Santiago Pérez | Relax - GAM | + 10:34 | + 10:34 |
| 78 | Dmitriy Fofonov | Crédit Agricole | + 10:34 | + 10:34 |
| 79 | Paolo Tiralongo | Lampre-Fondital | + 12:26 | + 12:26 |
| 80 | Danilo Di Luca | Liquigas | + 12:26 | + 12:26 |
| 81 | Fabio Sacchi | Team Milram | + 12:26 | + 12:26 |
| 82 | Marco Velo | Team Milram | + 12:26 | + 12:26 |
| 83 | Maxime Monfort | Cofidis | + 12:26 | + 12:26 |
| 84 | Philippe Gilbert | Française des Jeux | + 12:26 | + 12:26 |
| 85 | Angel Vallejo Dominquez | Relax - GAM | + 12:26 | + 12:26 |
| 86 | Scott Davis | T-Mobile Team | + 12:26 | + 12:26 |
| 87 | Bingen Fernández Bustinza | Cofidis | + 12:26 | + 12:26 |
| 88 | Gustavo Dominguez Lemos | Karpin-Galicia | + 12:26 | + 12:26 |
| 89 | Giuseppe Guerini | T-Mobile Team | + 12:26 | + 12:26 |
| 90 | Michal Golas | Unibet.com | + 12:26 | + 12:26 |
| 91 | Marzio Bruseghin | Lampre-Fondital | + 12:26 | + 12:26 |
| 92 | Murilo Fischer | Liquigas | + 12:26 | + 12:26 |
| 93 | Aleksandr Kuschynski | Liquigas | + 12:26 | + 12:26 |
| 94 | Simon Gerrans | AG2R Prévoyance | + 12:26 | + 12:26 |
| 95 | Íñigo Cuesta | Team CSC | + 12:26 | + 12:26 |
| 96 | Marco Marzano | Lampre-Fondital | + 12:26 | + 12:26 |
| 97 | Jon Bru | Euskaltel-Euskadi | + 15:19 | + 15:19 |
| 98 | Mads Kaggestad | Crédit Agricole | + 15:19 | + 15:19 |
| 99 | Carlos Castaño | Karpin-Galicia | + 15:19 | + 15:19 |
| 100 | Bradley Mcgee | Française des Jeux | + 18:21 | + 18:21 |
| 101 | Roger Hammond | T-Mobile Team | + 18:21 | + 18:21 |
| 102 | Iker Camaño | Saunier Duval - Prodir | + 18:21 | + 18:21 |
| 103 | Ruben Lobato | Saunier Duval - Prodir | + 18:21 | + 18:21 |
| 104 | Christophe Laurent | Crédit Agricole | + 18:21 | + 18:21 |
| 105 | Samuel Sánchez | Euskaltel-Euskadi | + 18:21 | + 18:21 |
| 106 | Josep Jufré | Predictor - Lotto | + 18:21 | + 18:21 |
| 107 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 18:21 | + 18:21 |
| 108 | David de La Fuente | Saunier Duval - Prodir | + 18:21 | + 18:21 |
| 109 | Thomas Voeckler | Bouygues Telecom | + 18:21 | + 18:21 |
| 110 | Julien Loubet | AG2R Prévoyance | + 18:21 | + 18:21 |
| 111 | Gustavo Veloso | Karpin-Galicia | + 18:21 | + 18:21 |
| 112 | Gil Suray | Unibet.com | + 18:21 | + 18:21 |
| 113 | Eduard Vorganov | Karpin-Galicia | + 18:21 | + 18:21 |
| 114 | Rodrigo Garcia Rena | Fuerteventura - Canarias | + 18:21 | + 18:21 |
| 115 | Julian Sanchez | Relax - GAM | + 18:21 | + 18:21 |
| 116 | Staf Scheirlinckx | Cofidis | + 18:21 | + 18:21 |
| 117 | Rik Verbrugghe | Cofidis | + 18:21 | + 18:21 |