| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alejandro Valverde | Movistar Team | 05:31:11 | |
| 2 | Bauke Mollema | Belkin Pro Cycling Team | + 14 | + 14 |
| 3 | Joaquim Rodríguez | Team Katusha | + 14 | + 14 |
| 4 | Mikel Nieve | Team Sky | + 14 | + 14 |
| 5 | Tony Gallopin | Lotto - Belisol | + 26 | + 26 |
| 6 | Jelle Vanendert | Lotto - Belisol | + 26 | + 26 |
| 7 | Haimar Zubeldia | Trek Factory Racing | + 26 | + 26 |
| 8 | Greg van Avermaet | BMC Racing Team | + 40 | + 40 |
| 9 | Giovanni Visconti | Movistar Team | + 40 | + 40 |
| 10 | Zdenek Stybar | Omega Pharma - Quick Step | + 43 | + 43 |
| 11 | Alexandr Kolobnev | Team Katusha | + 43 | + 43 |
| 12 | Arnold Jeannesson | FDJ.fr | + 43 | + 43 |
| 13 | José Serpa | Lampre-Merida | + 43 | + 43 |
| 14 | Tom-jelte Slagter | Garmin - Sharp | + 43 | + 43 |
| 15 | Anthony Roux | FDJ.fr | + 43 | + 43 |
| 16 | Tanel Kangert | Astana Pro Team | + 43 | + 43 |
| 18 | Romain Bardet | AG2R La Mondiale | + 43 | + 43 |
| 19 | Kristijan Durasek | Lampre-Merida | + 43 | + 43 |
| 20 | Nicolas Roche | Tinkoff - Saxo | + 43 | + 43 |
| 21 | Steven Kruijswijk | Belkin Pro Cycling Team | + 49 | + 49 |
| 22 | Alessandro de Marchi | Cannondale Pro Cycling | + 54 | + 54 |
| 23 | Pieter Serry | Omega Pharma - Quick Step | + 01:35 | + 01:35 |
| 24 | Jens Keukeleire | Orica - GreenEDGE | + 01:35 | + 01:35 |
| 25 | Daniel Martin | Garmin - Sharp | + 01:35 | + 01:35 |
| 26 | Maxim Iglinskiy | Astana Pro Team | + 01:35 | + 01:35 |
| 27 | Romain Sicard | Team Europcar | + 01:35 | + 01:35 |
| 28 | Jan Bakelants | Omega Pharma - Quick Step | + 01:35 | + 01:35 |
| 29 | André Cardoso | Garmin - Sharp | + 01:40 | + 01:40 |
| 30 | Nelson Oliveira | Lampre-Merida | + 02:05 | + 02:05 |
| 31 | Daan Olivier | Team Giant - Shimano | + 02:05 | + 02:05 |
| 32 | Michael Albasini | Orica - GreenEDGE | + 02:05 | + 02:05 |
| 33 | Eugenio Alafaci | Trek Factory Racing | + 02:44 | + 02:44 |
| 36 | Cyril Gautier | Team Europcar | + 02:59 | + 02:59 |
| 37 | Laurent Didier | Trek Factory Racing | + 02:59 | + 02:59 |
| 38 | Pello Bilbao | Caja Rural - Seguros RGA | + 02:59 | + 02:59 |
| 39 | Jesus Herrada | Movistar Team | + 02:59 | + 02:59 |
| 40 | Stijn Devolder | Trek Factory Racing | + 03:10 | + 03:10 |
| 41 | Ivan Rovny | Tinkoff - Saxo | + 03:10 | + 03:10 |
| 42 | Stef Clement | Belkin Pro Cycling Team | + 03:25 | + 03:25 |
| 43 | Adam Yates | Orica - GreenEDGE | + 03:57 | + 03:57 |
| 44 | Tim Wellens | Lotto - Belisol | + 04:03 | + 04:03 |
| 45 | Dennis Vanendert | Lotto - Belisol | + 04:03 | + 04:03 |
| 49 | Jose Herrada | Movistar Team | + 05:29 | + 05:29 |
| 50 | David López | Team Sky | + 05:29 | + 05:29 |
| 51 | Mikel Landa | Astana Pro Team | + 05:29 | + 05:29 |
| 52 | Alberto Losada | Team Katusha | + 05:29 | + 05:29 |
| 53 | Yury Trofimov | Team Katusha | + 05:29 | + 05:29 |
| 54 | Andriy Grivko | Astana Pro Team | + 05:29 | + 05:29 |
| 55 | Thomas Damuseau | Team Giant - Shimano | + 05:29 | + 05:29 |
| 56 | Mikaël Chérel | AG2R La Mondiale | + 05:29 | + 05:29 |
| 57 | Laurens ten Dam | Belkin Pro Cycling Team | + 05:29 | + 05:29 |
| 58 | Tejay van Garderen | BMC Racing Team | + 05:29 | + 05:29 |
| 59 | Michal Golas | Omega Pharma - Quick Step | + 06:11 | + 06:11 |
| 60 | Christian Knees | Team Sky | + 06:33 | + 06:33 |
| 61 | Rinaldo Nocentini | AG2R La Mondiale | + 08:00 | + 08:00 |
| 62 | Matteo Montaguti | AG2R La Mondiale | + 08:00 | + 08:00 |
| 63 | Fabio Sabatini | Cannondale Pro Cycling | + 11:36 | + 11:36 |
| 64 | Jesper Hansen | Tinkoff - Saxo | + 11:36 | + 11:36 |
| 65 | Nathan Earle | Team Sky | + 11:36 | + 11:36 |
| 66 | Jan Polanc | Lampre-Merida | + 11:36 | + 11:36 |
| 67 | Valerio Agnoli | Astana Pro Team | + 11:36 | + 11:36 |
| 68 | Boy van Poppel | Trek Factory Racing | + 11:36 | + 11:36 |
| 69 | Markel Irizar | Trek Factory Racing | + 11:36 | + 11:36 |
| 70 | Dylan van Baarle | Garmin - Sharp | + 11:36 | + 11:36 |
| 71 | Lluis Mas | Caja Rural - Seguros RGA | + 11:36 | + 11:36 |
| 72 | David Arroyo | Caja Rural - Seguros RGA | + 11:36 | + 11:36 |
| 73 | Amaël Moinard | BMC Racing Team | + 11:36 | + 11:36 |
| 74 | Antonio Piedra | Caja Rural - Seguros RGA | + 14:24 | + 14:24 |
| 75 | Aleksandr Kuschynski | Team Katusha | + 14:24 | + 14:24 |
| 76 | Amets Txurruka | Caja Rural - Seguros RGA | + 14:24 | + 14:24 |
| 78 | Axel Domont | AG2R La Mondiale | + 14:24 | + 14:24 |
| 79 | Reinardt Janse van Rensburg | Team Giant - Shimano | + 14:24 | + 14:24 |
| 80 | Carlos Verona | Omega Pharma - Quick Step | + 14:24 | + 14:24 |
| 82 | Chad Haga | Team Giant - Shimano | + 14:24 | + 14:24 |
| 83 | Kenny Elissonde | FDJ.fr | + 14:24 | + 14:24 |
| 84 | Jérémy Roy | FDJ.fr | + 14:24 | + 14:24 |
| 85 | Dmitriy Kozontchuk | Team Katusha | + 14:24 | + 14:24 |
| 86 | Yukiya Arashiro | Team Europcar | + 14:24 | + 14:24 |
| 87 | Jasper Stuyven | Trek Factory Racing | + 14:24 | + 14:24 |
| 88 | Lawson Craddock | Team Giant - Shimano | + 14:24 | + 14:24 |
| 89 | Hubert Dupont | AG2R La Mondiale | + 14:24 | + 14:24 |
| 90 | Alexey Lutsenko | Astana Pro Team | + 14:24 | + 14:24 |
| 91 | Tom Stamsnijder | Team Giant - Shimano | + 14:24 | + 14:24 |
| 92 | Simon Geschke | Team Giant - Shimano | + 14:51 | + 14:51 |
| 93 | Javier Aramendia | Caja Rural - Seguros RGA | + 16:02 | + 16:02 |
| 94 | Fernando Grijalba | Caja Rural - Seguros RGA | + 16:02 | + 16:02 |