| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | León Sánchez Luis | Rabobank | 05:55:34 | |
| 2 | Simon Gerrans | Orica - GreenEDGE | + 07 | + 07 |
| 3 | Gianni Meersman | Lotto - Belisol Team | + 07 | + 07 |
| 4 | Christophe Le Mével | Garmin - Sharp | + 07 | + 07 |
| 5 | Bauke Mollema | Rabobank | + 07 | + 07 |
| 6 | Mauro Santambrogio | BMC Racing Team | + 07 | + 07 |
| 7 | Mads Christensen | Team Saxo Bank - Tinkoff Bank | + 07 | + 07 |
| 8 | Joaquim Rodríguez | Katusha Team | + 07 | + 07 |
| 9 | Xavier Florencio | Katusha Team | + 07 | + 07 |
| 10 | Diego Ulissi | Lampre-ISD | + 07 | + 07 |
| 11 | Igor Anton | Euskaltel-Euskadi | + 07 | + 07 |
| 12 | Andrew Talansky | Garmin - Sharp | + 07 | + 07 |
| 13 | Greg van Avermaet | BMC Racing Team | + 07 | + 07 |
| 14 | Haimar Zubeldia | RadioShack-Nissan | + 07 | + 07 |
| 15 | Rafal Majka | Team Saxo Bank - Tinkoff Bank | + 07 | + 07 |
| 16 | Nicolas Roche | AG2R La Mondiale | + 07 | + 07 |
| 17 | Daniele Ratto | Liquigas-Cannondale | + 07 | + 07 |
| 18 | Daniel Martin | Garmin - Sharp | + 07 | + 07 |
| 19 | Rafael Valls | Vacansoleil - DCM Pro Cycling Team | + 07 | + 07 |
| 20 | Sergio Henao | Sky ProCycling | + 07 | + 07 |
| 21 | Jesús Hernández | Team Saxo Bank - Tinkoff Bank | + 07 | + 07 |
| 22 | Rigoberto Uran | Sky ProCycling | + 07 | + 07 |
| 23 | Daniel Moreno | Katusha Team | + 07 | + 07 |
| 24 | Richie Porte | Sky ProCycling | + 07 | + 07 |
| 25 | Cameron Meyer | Orica - GreenEDGE | + 07 | + 07 |
| 26 | Alejandro Valverde | Movistar Team | + 07 | + 07 |
| 27 | Robert Gesink | Rabobank | + 07 | + 07 |
| 28 | Tiago Machado | RadioShack-Nissan | + 11 | + 11 |
| 29 | Jelle Vanendert | Lotto - Belisol Team | + 25 | + 25 |
| 30 | Cristiano Salerno | Liquigas-Cannondale | + 35 | + 35 |
| 31 | Mikel Astarloza | Euskaltel-Euskadi | + 03:42 | + 03:42 |
| 32 | Rémi Pauriol | FDJ - BigMat | + 03:42 | + 03:42 |
| 33 | Romain Bardet | AG2R La Mondiale | + 03:42 | + 03:42 |
| 34 | André Cardoso | Caja Rural | + 03:42 | + 03:42 |
| 35 | Alexandre Vinokourov | Astana Pro Team | + 03:42 | + 03:42 |
| 36 | Ivan Velasco | Euskaltel-Euskadi | + 03:42 | + 03:42 |
| 37 | Paul Martens | Rabobank | + 03:42 | + 03:42 |
| 38 | Cayetano Sarmiento Jose | Liquigas-Cannondale | + 03:42 | + 03:42 |
| 39 | Przemyslaw Niemiec | Lampre-ISD | + 03:42 | + 03:42 |
| 40 | Gorka Izagirre | Euskaltel-Euskadi | + 03:42 | + 03:42 |
| 41 | Simon Clarke | Orica - GreenEDGE | + 03:42 | + 03:42 |
| 42 | Alberto Losada | Katusha Team | + 03:42 | + 03:42 |
| 43 | Angel Vicioso | Katusha Team | + 03:42 | + 03:42 |
| 44 | Sergio Paulinho | Team Saxo Bank - Tinkoff Bank | + 03:42 | + 03:42 |
| 45 | Zdenek Stybar | Omega Pharma - Quick Step | + 03:42 | + 03:42 |
| 46 | Vicente Reynès | Lotto - Belisol Team | + 04:52 | + 04:52 |
| 47 | Romain Sicard | Euskaltel-Euskadi | + 04:52 | + 04:52 |
| 48 | Hernani Broco | Caja Rural | + 04:52 | + 04:52 |
| 49 | Yury Trofimov | Katusha Team | + 04:52 | + 04:52 |
| 50 | Xabier Zandio | Sky ProCycling | + 04:52 | + 04:52 |
| 51 | Rob Ruijgh | Vacansoleil - DCM Pro Cycling Team | + 04:52 | + 04:52 |
| 52 | Bart de Clercq | Lotto - Belisol Team | + 04:52 | + 04:52 |
| 53 | Tomasz Marczynski | Vacansoleil - DCM Pro Cycling Team | + 04:52 | + 04:52 |
| 54 | Dario Cataldo | Omega Pharma - Quick Step | + 04:52 | + 04:52 |
| 55 | Francesco Gavazzi | Astana Pro Team | + 04:52 | + 04:52 |
| 56 | Laurens ten Dam | Rabobank | + 04:52 | + 04:52 |
| 57 | Silva Pires Bruno | Team Saxo Bank - Tinkoff Bank | + 06:08 | + 06:08 |
| 58 | Winner Anacona | Lampre-ISD | + 08:10 | + 08:10 |
| 59 | Tiziano Dall'antonia | Liquigas-Cannondale | + 08:10 | + 08:10 |
| 60 | Marco Pinotti | BMC Racing Team | + 09:58 | + 09:58 |
| 61 | Amets Txurruka | Euskaltel-Euskadi | + 09:58 | + 09:58 |
| 62 | Arthur Vichot | FDJ - BigMat | + 09:58 | + 09:58 |
| 63 | Mikel Landa | Euskaltel-Euskadi | + 09:58 | + 09:58 |
| 64 | Amaël Moinard | BMC Racing Team | + 09:58 | + 09:58 |
| 65 | Paolo Tiralongo | Astana Pro Team | + 09:58 | + 09:58 |
| 66 | Javier Moreno | Movistar Team | + 11:16 | + 11:16 |
| 67 | Vladimir Karpets | Movistar Team | + 11:16 | + 11:16 |
| 68 | José Cobo Juan | Movistar Team | + 12:40 | + 12:40 |
| 69 | Björn Leukemans | Vacansoleil - DCM Pro Cycling Team | + 14:05 | + 14:05 |
| 70 | Christian Meier | Orica - GreenEDGE | + 14:05 | + 14:05 |
| 71 | Vicente Toribio Jose | Andalucia | + 14:05 | + 14:05 |
| 72 | Serge Pauwels | Omega Pharma - Quick Step | + 14:05 | + 14:05 |
| 73 | Volodymir Gustov | Team Saxo Bank - Tinkoff Bank | + 14:05 | + 14:05 |
| 74 | Michael Rogers | Sky ProCycling | + 14:05 | + 14:05 |
| 75 | Sergey Lagutin | Vacansoleil - DCM Pro Cycling Team | + 14:05 | + 14:05 |
| 76 | Bert-jan Lindeman | Vacansoleil - DCM Pro Cycling Team | + 14:05 | + 14:05 |
| 77 | Alexsandr Dyachenko | Astana Pro Team | + 14:05 | + 14:05 |
| 78 | Adrian Palomares | Andalucia | + 17:14 | + 17:14 |
| 79 | Pablo Lechuga | Andalucia | + 17:14 | + 17:14 |
| 80 | Javier Aramendia | Caja Rural | + 17:14 | + 17:14 |
| 81 | Andrey Zeits | Astana Pro Team | + 17:14 | + 17:14 |
| 82 | Marcos Garcia | Caja Rural | + 17:14 | + 17:14 |
| 83 | Nairo Quintana | Movistar Team | + 17:14 | + 17:14 |
| 84 | Jesus Rosendo Prado | Andalucia | + 17:14 | + 17:14 |
| 85 | Antonio Cabello Baena | Andalucia | + 17:28 | + 17:28 |
| 86 | Javier Chacon Quesada | Andalucia | + 17:28 | + 17:28 |