| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alejandro Valverde | Illes Balears - Caisse d'Epargne | 03:59:05 | |
| 2 | Ricardo Serrano | Kaiku | + 00 | |
| 3 | Aitor Perez Arrieta | Spiuk | + 00 | |
| 4 | Adolfo Garcia Quesada | Comunidad Valenciana | + 00 | |
| 5 | Iker Camaño | Euskaltel-Euskadi | + 00 | |
| 6 | David Muñoz | Comunidad Valenciana | + 00 | |
| 7 | José Gomez | Saunier Duval - Prodir | + 00 | |
| 8 | Antonio Colom | Illes Balears - Caisse d'Epargne | + 05 | + 05 |
| 9 | Rolf Aldag | T-Mobile Team | + 41 | + 41 |
| 10 | Jon Bru | Kaiku | + 56 | + 56 |
| 11 | Ángel Gómez | Saunier Duval - Prodir | + 56 | + 56 |
| 12 | Antonio Tauler Llull | Illes Balears - Caisse d'Epargne | + 56 | + 56 |
| 13 | Luis Pasamontes | Relax - Fuenlabarda | + 56 | + 56 |
| 14 | Luis Martinez Jose | Comunidad Valenciana | + 56 | + 56 |
| 15 | David López | Euskaltel-Euskadi | + 56 | + 56 |
| 16 | Tadej Valjavec | Phonak Hearing Systems | + 56 | + 56 |
| 17 | Alberto Gonzalez Javier | Andalucia - Paul Versan | + 56 | + 56 |
| 18 | Ezequiel Mosquera | Kaiku | + 56 | + 56 |
| 19 | Marc Lotz | Quick Step | + 01:35 | + 01:35 |
| 20 | Theo Eltink | Rabobank | + 01:35 | + 01:35 |
| 21 | Grischa Niermann | Rabobank | + 01:35 | + 01:35 |
| 22 | Gustavo Dominguez Lemos | Orbea | + 01:35 | + 01:35 |
| 23 | David Canada | Saunier Duval - Prodir | + 01:35 | + 01:35 |
| 24 | Julen Zubero Aldekoa | Orbea | + 01:35 | + 01:35 |
| 25 | Patrik Sinkewitz | Quick Step | + 01:35 | + 01:35 |
| 26 | Christian Werner | T-Mobile Team | + 01:35 | + 01:35 |
| 27 | Antonio Olmo | Comunidad Valenciana | + 01:35 | + 01:35 |
| 28 | Xavier Tondó | Catalunya - Angel Mir | + 01:35 | + 01:35 |
| 29 | David Fernandez | Andalucia - Paul Versan | + 01:35 | + 01:35 |
| 30 | Ruben Oarbeascoa Ispizua | Kaiku | + 01:35 | + 01:35 |
| 31 | Erik Zabel | T-Mobile Team | + 04:19 | + 04:19 |
| 32 | Vicente Reynès | Illes Balears - Caisse d'Epargne | + 04:19 | + 04:19 |
| 33 | Antonio Pecharroman Jose | Quick Step | + 05:30 | + 05:30 |
| 34 | Rodrigo Garcia Rena | Kaiku | + 05:30 | + 05:30 |
| 35 | Aaron Villegas Trapaga | Orbea | + 05:30 | + 05:30 |
| 36 | Addy Engels | Quick Step | + 05:35 | + 05:35 |
| 37 | Gustavo Veloso | Kaiku | + 05:35 | + 05:35 |
| 38 | Gorka Arrizabalaga Agirre | Orbea | + 05:35 | + 05:35 |
| 39 | Luis Perez Romero | Relax - Fuenlabarda | + 07:20 | + 07:20 |
| 40 | Íñigo Cuesta | Saunier Duval - Prodir | + 07:36 | + 07:36 |
| 41 | Ruben Lobato | Saunier Duval - Prodir | + 07:36 | + 07:36 |
| 42 | Rory Sutherland | Rabobank | + 07:37 | + 07:37 |
| 43 | Torsten Hiekmann | T-Mobile Team | + 08:21 | + 08:21 |
| 44 | Jorge Azanza | Kaiku | + 08:29 | + 08:29 |
| 45 | Iker Flores | Euskaltel-Euskadi | + 08:29 | + 08:29 |
| 46 | Manuel Garate Juan | Saunier Duval - Prodir | + 09:01 | + 09:01 |
| 47 | Alexandr Kolobnev | Rabobank | + 09:01 | + 09:01 |
| 48 | Alan Perez Lezaun | Orbea | + 09:01 | + 09:01 |
| 49 | Efrain Gutierrez Sanchez | Andalucia - Paul Versan | + 09:01 | + 09:01 |
| 50 | Javier Benitez | Relax - Fuenlabarda | + 09:01 | + 09:01 |
| 51 | Xabier Zandio | Illes Balears - Caisse d'Epargne | + 09:01 | + 09:01 |
| 52 | Thorwald Veneberg | Rabobank | + 09:01 | + 09:01 |
| 53 | Sergio Dominguez | Spiuk | + 13:07 | + 13:07 |
| 54 | Iban Mayoz | Relax - Fuenlabarda | + 14:25 | + 14:25 |
| 55 | Aitor Osa | Illes Balears - Caisse d'Epargne | + 14:25 | + 14:25 |
| 56 | Rik Verbrugghe | Quick Step | + 14:25 | + 14:25 |
| 57 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 14:25 | + 14:25 |
| 58 | Paolo Bettini | Quick Step | + 14:25 | + 14:25 |
| 59 | Carlos Castaño | Andalucia - Paul Versan | + 14:25 | + 14:25 |
| 60 | David de La Fuente | Saunier Duval - Prodir | + 14:25 | + 14:25 |
| 61 | David Herrero | Euskaltel-Euskadi | + 14:25 | + 14:25 |
| 62 | Axetza Pena Iza | Euskaltel-Euskadi | + 14:25 | + 14:25 |
| 63 | Iván Gutiérrez | Illes Balears - Caisse d'Epargne | + 14:25 | + 14:25 |
| 64 | Jaume Rovira | Andalucia - Paul Versan | + 14:25 | + 14:25 |
| 65 | Maarten den Bakker | Rabobank | + 14:25 | + 14:25 |
| 66 | Andoni Aranaga Akzune | Kaiku | + 15:08 | + 15:08 |
| 67 | Nacor Burgos | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 68 | Moisés Dueñas | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 69 | Oscar Laguna | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 70 | Sascha Urweider | Phonak Hearing Systems | + 15:08 | + 15:08 |
| 71 | Miguel Mercado Juan | Quick Step | + 15:08 | + 15:08 |
| 72 | Javier Pascual Llorente | Comunidad Valenciana | + 15:08 | + 15:08 |
| 73 | Angel Vallejo Dominquez | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 74 | Javier Cherro Molina | Comunidad Valenciana | + 15:08 | + 15:08 |
| 75 | Rafael Macarron | Spiuk | + 15:08 | + 15:08 |
| 76 | Joan Llaneras Rosello | + 15:08 | + 15:08 | |
| 77 | Javier Ramirez Torres Jesus | Spiuk | + 15:08 | + 15:08 |
| 78 | Ignacio Gutierrez | Phonak Hearing Systems | + 15:08 | + 15:08 |
| 79 | Antonio Pastor Roldan Juan | Andalucia - Paul Versan | + 15:08 | + 15:08 |
| 80 | Unai Elorriaga Zubiaur | + 15:08 | + 15:08 | |
| 81 | Niki Aebersold | Phonak Hearing Systems | + 15:08 | + 15:08 |
| 82 | Miguel Alzamora Riera | + 15:08 | + 15:08 | |
| 83 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 15:08 | + 15:08 |
| 84 | Jesus Perez Priego | Spiuk | + 15:08 | + 15:08 |
| 85 | Cristian Moreni | Quick Step | + 15:08 | + 15:08 |
| 86 | Adrian Palomares | Kaiku | + 15:08 | + 15:08 |
| 87 | Xavier Florencio | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 88 | Israel Nunez Baticon | Kaiku | + 15:08 | + 15:08 |
| 89 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 15:08 | + 15:08 |
| 90 | Marc Wauters | Rabobank | + 15:08 | + 15:08 |
| 91 | Manuel Gomes Colinas Victor | Andalucia - Paul Versan | + 15:08 | + 15:08 |
| 92 | Oliver Zaugg | Saunier Duval - Prodir | + 15:08 | + 15:08 |
| 93 | Raul Garcia de Mateos | Relax - Fuenlabarda | + 15:08 | + 15:08 |
| 94 | Ronald Mutsaars | Rabobank | + 15:08 | + 15:08 |
| 95 | Steffen Wesemann | T-Mobile Team | + 15:08 | + 15:08 |
| 96 | Nicolas Fritsch | Saunier Duval - Prodir | + 15:08 | + 15:08 |
| 97 | Gorka Gonzalez | Euskaltel-Euskadi | + 15:08 | + 15:08 |
| 98 | Alexandre Moos | Phonak Hearing Systems | + 15:08 | + 15:08 |
| 99 | Mikel Artetxe | Euskaltel-Euskadi | + 15:08 | + 15:08 |
| 100 | Carlos Torrent | Catalunya - Angel Mir | + 15:08 | + 15:08 |
| 101 | Mikel Gaztanaga | Catalunya - Angel Mir | + 15:08 | + 15:08 |
| 102 | Antonio Garrido Jose | Quick Step | + 15:08 | + 15:08 |
| 103 | Jordi Berenguer Ferrer | Catalunya - Angel Mir | + 15:08 | + 15:08 |
| 104 | Alberto Rodriguez | Catalunya - Angel Mir | + 15:08 | + 15:08 |
| 105 | José Lara Francisco | T-Mobile Team | + 15:08 | + 15:08 |
| 106 | Ángel Casero | Comunidad Valenciana | + 15:08 | + 15:08 |
| 107 | Luengo Celaya Anton | Euskaltel-Euskadi | + 15:39 | + 15:39 |
| 108 | Gorka Amuriza Gumucio | Orbea | + 15:39 | + 15:39 |
| 109 | Mads Christensen | Quick Step | + 15:39 | + 15:39 |
| 110 | Xabat Ochotorena | Orbea | + 16:01 | + 16:01 |
| 111 | Jorge Sanchez Pimienta | Spiuk | + 16:12 | + 16:12 |
| 112 | Pedro Romero Ocampo | Spiuk | + 18:58 | + 18:58 |
| 113 | Jesus Del Nero Montes | Orbea | + 19:47 | + 19:47 |
| 114 | Unai Osa | Illes Balears - Caisse d'Epargne | + 21:40 | + 21:40 |
| 115 | Aitor Alonso Granados | + 21:40 | + 21:40 | |
| 116 | Fernando Torres Martin | Spiuk | + 21:40 | + 21:40 |