| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Antonio Colom | Team Katusha | 03:54:49 | |
| 2 | Edvald Boasson-hagen | Team Columbia - HTC | + 56 | + 56 |
| 3 | Jérôme Pineau | Quick Step | + 56 | + 56 |
| 4 | Sylvain Chavanel | Quick Step | + 56 | + 56 |
| 5 | Maxime Monfort | Team Columbia - HTC | + 56 | + 56 |
| 6 | Morris Possoni | Team Columbia - HTC | + 01:00 | + 01:00 |
| 7 | Mikel Nieve | Euskaltel-Euskadi | + 01:01 | + 01:01 |
| 8 | Manuel Vazquez | Contentpolis - Ampo | + 01:05 | + 01:05 |
| 9 | Paul Martens | Rabobank | + 01:05 | + 01:05 |
| 10 | Markus Fothen | Team Milram | + 01:05 | + 01:05 |
| 11 | Tony Martin | Team Columbia - HTC | + 01:06 | + 01:06 |
| 12 | Francisco Pérez | Caisse d'Epargne | + 01:06 | + 01:06 |
| 13 | Roman Kreuziger | Liquigas | + 01:28 | + 01:28 |
| 14 | Ivan Santaromita | Liquigas | + 01:32 | + 01:32 |
| 15 | Manuel Garate Juan | Rabobank | + 02:00 | + 02:00 |
| 16 | Iñigo Landaluze | Euskaltel-Euskadi | + 02:00 | + 02:00 |
| 17 | Laurens ten Dam | Rabobank | + 02:00 | + 02:00 |
| 18 | Dario Cataldo | Quick Step | + 02:25 | + 02:25 |
| 19 | Joaquin Rojas José | Caisse d'Epargne | + 02:25 | + 02:25 |
| 20 | Pablo Lastras | Caisse d'Epargne | + 02:35 | + 02:35 |
| 21 | Davide Malacarne | Quick Step | + 02:35 | + 02:35 |
| 22 | Bert Grabsch | Team Columbia - HTC | + 02:35 | + 02:35 |
| 23 | Christian Pfannberger | Team Katusha | + 02:35 | + 02:35 |
| 24 | Aitor Perez Arrieta | Contentpolis - Ampo | + 02:35 | + 02:35 |
| 25 | Gorazd Stangelj | Liquigas | + 02:35 | + 02:35 |
| 26 | Andrey Amador | Caisse d'Epargne | + 02:35 | + 02:35 |
| 27 | Rafael Valls | Burgos Monumental - Castilla y Leon | + 02:35 | + 02:35 |
| 28 | Javier Moreno | Andalucía - Cajasur | + 02:35 | + 02:35 |
| 29 | David López | Caisse d'Epargne | + 02:35 | + 02:35 |
| 30 | Javier Etxarri | Contentpolis - Ampo | + 02:35 | + 02:35 |
| 31 | Koos Moerenhout | Rabobank | + 02:35 | + 02:35 |
| 32 | Aitor Hernández | Euskaltel-Euskadi | + 02:35 | + 02:35 |
| 33 | Eduard Vorganov | Xacobeo-Galicia | + 02:35 | + 02:35 |
| 34 | Johannes Fröhlinger | Team Milram | + 02:35 | + 02:35 |
| 35 | Marcos Garcia | Xacobeo-Galicia | + 02:38 | + 02:38 |
| 36 | Jonathan Tiernan-locke | Plowman Craven - Madison | + 03:21 | + 03:21 |
| 37 | Arjen de Baat | Van Vliet - EBH - Elshof | + 03:21 | + 03:21 |
| 38 | Samuel Dumoulin | Cofidis | + 03:21 | + 03:21 |
| 39 | Marco Pinotti | Team Columbia - HTC | + 04:57 | + 04:57 |
| 40 | Kanstantsin Sivtsov | Team Columbia - HTC | + 04:57 | + 04:57 |
| 41 | Björn Thurau | Elk Haus | + 04:57 | + 04:57 |
| 42 | Andreas Schillinger | Team Nutrixxion - Sparkasse | + 04:57 | + 04:57 |
| 43 | Gerhard Trampusch | Elk Haus | + 04:57 | + 04:57 |
| 44 | Esteban Plaza Mira | Andalucía - Cajasur | + 04:57 | + 04:57 |
| 45 | Javier Ramirez | Andalucía - Cajasur | + 04:57 | + 04:57 |
| 46 | Pedro Fernandez | Xacobeo-Galicia | + 04:57 | + 04:57 |
| 47 | Gustavo Dominguez Lemos | Xacobeo-Galicia | + 04:57 | + 04:57 |
| 48 | Eritz Ruiz | Orbea | + 04:57 | + 04:57 |
| 49 | Sergio Domínguez Muñoz | Contentpolis - Ampo | + 04:57 | + 04:57 |
| 50 | Dries Devenyns | Quick Step | + 04:57 | + 04:57 |
| 51 | Jorge Azanza | Euskaltel-Euskadi | + 04:57 | + 04:57 |
| 52 | Javier Aramendia | Euskaltel-Euskadi | + 04:57 | + 04:57 |
| 53 | Josu Agirre Asegniloaza | Euskaltel-Euskadi | + 04:57 | + 04:57 |
| 54 | Bingen Fernández Bustinza | Cofidis | + 04:57 | + 04:57 |
| 55 | José Oroz Juan | Euskaltel-Euskadi | + 04:57 | + 04:57 |
| 56 | Romain Sicard | Orbea | + 04:57 | + 04:57 |
| 57 | Matteo Tosatto | Quick Step | + 07:01 | + 07:01 |
| 58 | Frederik Willems | Liquigas | + 07:01 | + 07:01 |
| 59 | Manuel Calvente | Andalucía - Cajasur | + 07:04 | + 07:04 |
| 60 | Joan Horrach | Team Katusha | + 09:11 | + 09:11 |
| 61 | David Arroyo | Caisse d'Epargne | + 09:11 | + 09:11 |
| 62 | Martin Müller | Team Milram | + 09:11 | + 09:11 |
| 63 | Matthias Russ | Team Milram | + 09:11 | + 09:11 |
| 64 | Jesus Rosendo Prado | Andalucía - Cajasur | + 09:11 | + 09:11 |
| 65 | Enrico Franzoi | Liquigas | + 09:11 | + 09:11 |
| 66 | Serguei Klimov | Team Katusha | + 09:11 | + 09:11 |
| 67 | Vladimir Karpets | Team Katusha | + 09:11 | + 09:11 |
| 68 | Joaquim Rodríguez | Caisse d'Epargne | + 09:11 | + 09:11 |
| 69 | Joseba Larralde Alzugarai | Orbea | + 09:11 | + 09:11 |
| 70 | Diego Gallego | Burgos Monumental - Castilla y Leon | + 09:11 | + 09:11 |
| 71 | Hubert Schwab | Quick Step | + 09:11 | + 09:11 |
| 72 | Dmitriy Kozontchuk | Rabobank | + 09:11 | + 09:11 |
| 73 | Javier Estrada Juan | Andalucía - Cajasur | + 09:11 | + 09:11 |
| 74 | Alexandre Botcharov | Team Katusha | + 09:11 | + 09:11 |
| 75 | Adrian Palomares | Contentpolis - Ampo | + 09:11 | + 09:11 |
| 76 | Arnold Jeannesson | Caisse d'Epargne | + 09:11 | + 09:11 |
| 77 | Dirk Müller | Team Nutrixxion - Sparkasse | + 09:19 | + 09:19 |
| 78 | Alejandro Paleo | Xacobeo-Galicia | + 09:45 | + 09:45 |
| 79 | Iban Mayoz | Xacobeo-Galicia | + 09:57 | + 09:57 |
| 80 | Francisco Mourón Juan | Xacobeo-Galicia | + 09:57 | + 09:57 |
| 81 | Mauro Facci | Quick Step | + 10:44 | + 10:44 |
| 82 | Julian Sanchez | Contentpolis - Ampo | + 10:49 | + 10:49 |
| 83 | Dennis Pohl | Team Kuota - Indeland | + 12:10 | + 12:10 |
| 84 | Bram Schmitz | Van Vliet - EBH - Elshof | + 12:10 | + 12:10 |
| 85 | Rikke Dijkxhoorn | Van Vliet - EBH - Elshof | + 12:12 | + 12:12 |
| 86 | Jos van Emden | Rabobank | + 12:12 | + 12:12 |
| 87 | Nick Nuyens | Rabobank | + 12:14 | + 12:14 |
| 88 | Manuel Quinziato | Liquigas | + 12:14 | + 12:14 |
| 89 | Peter Velits | Team Milram | + 12:14 | + 12:14 |
| 90 | Sylwester Szmyd | Liquigas | + 12:14 | + 12:14 |
| 91 | Alberto Losada | Caisse d'Epargne | + 12:14 | + 12:14 |
| 92 | Gorka Verdugo | Euskaltel-Euskadi | + 12:14 | + 12:14 |
| 93 | Jose Ruiz Sanchez | Andalucía - Cajasur | + 12:14 | + 12:14 |
| 94 | Vladimir Isaichev | Xacobeo-Galicia | + 12:26 | + 12:26 |
| 95 | Kurt Hovelynck | Quick Step | + 12:26 | + 12:26 |
| 96 | Harald Starzengruber | Elk Haus | + 12:26 | + 12:26 |
| 97 | Jonathan Castroviejo | Orbea | + 13:20 | + 13:20 |
| 98 | Ronan van Zandbeek | Van Vliet - EBH - Elshof | + 15:17 | + 15:17 |
| 99 | Evan Oliphant | Plowman Craven - Madison | + 15:17 | + 15:17 |
| 100 | Stephen Adams | Plowman Craven - Madison | + 15:17 | + 15:17 |
| 101 | Tom Stamsnijder | Rabobank | + 15:17 | + 15:17 |
| 102 | Sjoerd Kouwenhoven | Van Vliet - EBH - Elshof | + 15:17 | + 15:17 |
| 103 | Eneko Echeverz Carte | Orbea | + 15:17 | + 15:17 |
| 104 | Sergio de Lis | Euskaltel-Euskadi | + 15:17 | + 15:17 |
| 105 | Stijn Devolder | Quick Step | + 15:17 | + 15:17 |
| 106 | Stephane Augé | Cofidis | + 15:20 | + 15:20 |
| 107 | Jean-michel Schlüter | Team Nutrixxion - Sparkasse | + 15:20 | + 15:20 |
| 108 | Lars Vierbergen | Van Vliet - EBH - Elshof | + 15:20 | + 15:20 |
| 109 | Daniel Sesma Sorbet | Orbea | + 15:20 | + 15:20 |
| 110 | Antonio Piedra | Andalucía - Cajasur | + 18:19 | + 18:19 |
| 111 | Antonio Redondo Jose | Andalucía - Cajasur | + 18:19 | + 18:19 |
| 112 | Rafael Serrano Fernandez | Contentpolis - Ampo | + 18:19 | + 18:19 |
| 113 | Avelino Antuna Coro Andres | Burgos Monumental - Castilla y Leon | + 18:19 | + 18:19 |
| 114 | Angel Madrazo | Caisse d'Epargne | + 18:21 | + 18:21 |
| 115 | José Casas Claudio | Contentpolis - Ampo | + 21:26 | + 21:26 |
| 116 | Gorka Izagirre | Contentpolis - Ampo | + 21:26 | + 21:26 |
| 117 | Bas Stamsnijder | Van Vliet - EBH - Elshof | + 23:42 | + 23:42 |
| 118 | Robbie Mcewen | Team Katusha | + 28:28 | + 28:28 |
| 119 | Andoni Blazquez Berasarte | Orbea | + 28:28 | + 28:28 |