| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Philippe Gilbert | Française des Jeux | 04:24:17 | |
| 2 | Sebastian Langeveld | Rabobank | + 00 | |
| 3 | Maarten Wynants | Quick Step | + 00 | |
| 4 | Antonio Colom | Astana | + 00 | |
| 5 | Aitor Galdos | Euskaltel-Euskadi | + 00 | |
| 6 | Marc de Maar | Rabobank | + 00 | |
| 7 | Gregory Rast | Astana | + 00 | |
| 8 | Frank Høj | Cofidis | + 00 | |
| 9 | Haimar Zubeldia | Euskaltel-Euskadi | + 00 | |
| 10 | Gustavo Dominguez Lemos | Xacobeo-Galicia | + 00 | |
| 11 | Markus Fothen | Gerolsteiner | + 00 | |
| 12 | Jon Bru | Euskaltel-Euskadi | + 00 | |
| 13 | Antonio Flecha Juan | Rabobank | + 00 | |
| 14 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 00 | |
| 15 | Martin Mares | PSK Whirlpool - Author | + 00 | |
| 16 | Bram Tankink | Rabobank | + 00 | |
| 17 | Aitor Perez Arrieta | Extremadura | + 00 | |
| 18 | Jesus Rosendo Prado | Andalucia - Cajasur | + 00 | |
| 19 | Nick Nuyens | Cofidis | + 00 | |
| 20 | Manuel Garate Juan | Quick Step | + 00 | |
| 21 | Addy Engels | Quick Step | + 00 | |
| 22 | Johnny Hoogerland | Van Vliet - EBH - Elshof | + 00 | |
| 23 | Ezequiel Mosquera | Xacobeo-Galicia | + 00 | |
| 24 | Eduard Vorganov | Xacobeo-Galicia | + 00 | |
| 25 | Rikke Dijkxhoorn | Van Vliet - EBH - Elshof | + 00 | |
| 26 | Manuel Ortega | Andalucia - Cajasur | + 00 | |
| 27 | Alberto Losada | Caisse d'Epargne | + 00 | |
| 28 | Iban Mayoz | Xacobeo-Galicia | + 00 | |
| 29 | Javier Moreno | Andalucia - Cajasur | + 00 | |
| 30 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 00 | |
| 31 | Tom Leezer | Rabobank | + 00 | |
| 32 | Matteo Carrara | Quick Step | + 00 | |
| 33 | Sébastien Joly | Française des Jeux | + 00 | |
| 34 | Pedro Merino Criado | + 00 | ||
| 35 | Jesus Del Nero Montes | Scott - American Beef | + 00 | |
| 36 | Rafael Valls | Scott - American Beef | + 00 | |
| 37 | Joan Llaneras Rosello | + 00 | ||
| 38 | Grischa Niermann | Rabobank | + 00 | |
| 39 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 40 | Delio Fernandez | Xacobeo-Galicia | + 00 | |
| 41 | Ignacio Sarabia | Extremadura | + 00 | |
| 42 | Christophe Mengin | Française des Jeux | + 00 | |
| 43 | Antonio Piedra | Andalucia - Cajasur | + 00 | |
| 44 | Julien Mazet | Astana | + 00 | |
| 45 | Alberto Fernandez Sainz | Xacobeo-Galicia | + 00 | |
| 46 | Vicente Toribio Jose | Burgos Monumental | + 00 | |
| 47 | Jose Ruiz Sanchez | Andalucia - Cajasur | + 00 | |
| 48 | Tom Stamsnijder | Gerolsteiner | + 00 | |
| 49 | Ronny Scholz | Gerolsteiner | + 00 | |
| 50 | Angel Mate Luis | Andalucia - Cajasur | + 00 | |
| 51 | Staf Scheirlinckx | Cofidis | + 00 | |
| 52 | Francisco Pérez | Caisse d'Epargne | + 00 | |
| 53 | Gorka Verdugo | Euskaltel-Euskadi | + 00 | |
| 54 | Andoni Lafuente | Euskaltel-Euskadi | + 00 | |
| 55 | Alessandro Proni | Quick Step | + 00 | |
| 56 | José Casas Claudio | Andalucia - Cajasur | + 00 | |
| 57 | Juan Olmo | Andalucia - Cajasur | + 00 | |
| 58 | Rein Taaramäe | Cofidis | + 00 | |
| 59 | Thierry Hupond | Skil - Shimano | + 00 | |
| 60 | Benoit Joachim | Astana | + 00 | |
| 61 | Jelle Vanendert | Française des Jeux | + 00 | |
| 62 | Benjamin Noval | Astana | + 00 | |
| 63 | Sandy Casar | Française des Jeux | + 00 | |
| 64 | Iñigo Landaluze | Euskaltel-Euskadi | + 00 | |
| 65 | Lars Vierbergen | Van Vliet - EBH - Elshof | + 00 | |
| 66 | Alberto Contador | Astana | + 00 | |
| 67 | Steve Morabito | Astana | + 00 | |
| 68 | Jaume Rovira | Extremadura | + 00 | |
| 69 | David López | Caisse d'Epargne | + 43 | + 43 |
| 70 | Sergio Herrero | Extremadura | + 43 | + 43 |
| 71 | Leonardo Scarselli | Quick Step | + 54 | + 54 |
| 72 | Hector Gonzalez | Scott - American Beef | + 01:11 | + 01:11 |
| 73 | Vladimir Karpets | Caisse d'Epargne | + 01:18 | + 01:18 |
| 74 | Xabier Zandio | Caisse d'Epargne | + 01:20 | + 01:20 |
| 75 | David Arroyo | Caisse d'Epargne | + 01:23 | + 01:23 |
| 76 | Joaquin Rojas José | Caisse d'Epargne | + 04:14 | + 04:14 |
| 77 | Josu Mondelo Diaz | Extremadura | + 09:46 | + 09:46 |
| 78 | Clément Lhotellerie | Skil - Shimano | + 09:46 | + 09:46 |
| 79 | Martin Mata Cabello | Burgos Monumental | + 09:46 | + 09:46 |
| 80 | Gorka Izagirre | NGC Medical - OTC Industria Porte | + 09:46 | + 09:46 |
| 81 | Pedro Gutierrez Alvarez | Burgos Monumental | + 09:46 | + 09:46 |
| 82 | Javier Iriarte | Burgos Monumental | + 09:46 | + 09:46 |
| 83 | Javier Estrada Juan | Andalucia - Cajasur | + 09:46 | + 09:46 |
| 84 | David Francisco Delgado | Burgos Monumental | + 09:46 | + 09:46 |
| 85 | Javier Ramirez Torres Jesus | Extremadura | + 09:46 | + 09:46 |
| 86 | Kevin van Impe | Quick Step | + 09:51 | + 09:51 |
| 87 | Jaime Garcia Latorre | Extremadura | + 12:16 | + 12:16 |
| 88 | Stanislav Kozubek | PSK Whirlpool - Author | + 12:18 | + 12:18 |
| 89 | Josu Agirre Asegniloaza | Euskaltel-Euskadi | + 12:18 | + 12:18 |
| 90 | Albert Timmer | Skil - Shimano | + 12:18 | + 12:18 |
| 91 | Tomas Buchacek | PSK Whirlpool - Author | + 12:18 | + 12:18 |