| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Paolo Bettini | Quick Step - Innergetic | 03:47:10 | |
| 2 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 00 | |
| 3 | David Bernabeu | Comunidad Valenciana | + 00 | |
| 4 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | + 25 | + 25 |
| 5 | Fränk Schleck | Team CSC | + 25 | + 25 |
| 6 | Jesus Del Nero Montes | 3 Molinos Resort | + 25 | + 25 |
| 7 | Franco Pellizotti | Liquigas | + 25 | + 25 |
| 8 | Ángel Gómez | Saunier Duval - Prodir | + 25 | + 25 |
| 9 | Rodrigo Garcia Rena | Kaiku | + 25 | + 25 |
| 10 | Josep Jufré | Davitamon - Lotto | + 25 | + 25 |
| 11 | Koos Moerenhout | Phonak Hearing Systems | + 25 | + 25 |
| 12 | Jon Bru | Kaiku | + 25 | + 25 |
| 13 | Iñaki Isasi | Euskaltel-Euskadi | + 25 | + 25 |
| 14 | Constantino Zaballa | Caisse d'Epargne - Illes Balears | + 25 | + 25 |
| 15 | Theo Eltink | Rabobank | + 25 | + 25 |
| 16 | David Arroyo | Caisse d'Epargne - Illes Balears | + 25 | + 25 |
| 17 | Aitor Hernández | Euskaltel-Euskadi | + 25 | + 25 |
| 18 | Bram de Groot | Rabobank | + 25 | + 25 |
| 19 | Pieter Weening | Rabobank | + 25 | + 25 |
| 20 | Jesús Hernández | Relax - GAM | + 25 | + 25 |
| 21 | Dario Cioni | Liquigas | + 25 | + 25 |
| 22 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 25 | + 25 |
| 23 | Luis Perez Romero | Andalucia - Paul Versan | + 25 | + 25 |
| 24 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 25 | + 25 |
| 25 | Francisco Cabello | Andalucia - Paul Versan | + 25 | + 25 |
| 26 | Oscar Garcia-casarrubios | Relax - GAM | + 25 | + 25 |
| 27 | Joseba Albizu Lizaso | Euskaltel-Euskadi | + 25 | + 25 |
| 28 | Jorge Azanza | Kaiku | + 25 | + 25 |
| 29 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 25 | + 25 |
| 30 | Gorka Verdugo | Euskaltel-Euskadi | + 25 | + 25 |
| 31 | Matthias Russ | Gerolsteiner | + 25 | + 25 |
| 32 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 25 | + 25 |
| 33 | Bernhard Kohl | T-Mobile Team | + 25 | + 25 |
| 34 | Juan Olmo | Andalucia - Paul Versan | + 25 | + 25 |
| 35 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 25 | + 25 |
| 36 | Vincenzo Nibali | Liquigas | + 25 | + 25 |
| 37 | Julian Sanchez | Comunidad Valenciana | + 25 | + 25 |
| 38 | Gerardo Fernandez | Vina Magna - Cropu | + 25 | + 25 |
| 39 | Mario Almagro Valero Jose | Relax - GAM | + 25 | + 25 |
| 40 | José Gomez | Saunier Duval - Prodir | + 25 | + 25 |
| 41 | Íñigo Cuesta | Team CSC | + 25 | + 25 |
| 42 | Koldo Gil | Saunier Duval - Prodir | + 25 | + 25 |
| 43 | Alexandr Kolobnev | Rabobank | + 02:49 | + 02:49 |
| 44 | Inigo Chaurreau | AG2R Prévoyance | + 03:22 | + 03:22 |
| 45 | Mikel Astarloza | AG2R Prévoyance | + 03:22 | + 03:22 |
| 46 | Samuel Dumoulin | AG2R Prévoyance | + 03:22 | + 03:22 |
| 47 | Yury Trofimov | Omnibike Dynamo Moscow | + 03:22 | + 03:22 |
| 48 | Steve Zamperi | Phonak Hearing Systems | + 03:22 | + 03:22 |
| 49 | David de La Fuente | Saunier Duval - Prodir | + 03:22 | + 03:22 |
| 50 | Vladimir Miholjevic | Liquigas | + 03:22 | + 03:22 |
| 51 | David Muñoz | Comunidad Valenciana | + 03:22 | + 03:22 |
| 52 | Grischa Niermann | Rabobank | + 03:22 | + 03:22 |
| 53 | Ruben Oarbeascoa Ispizua | Kaiku | + 03:22 | + 03:22 |
| 54 | Francisco Pérez | Caisse d'Epargne - Illes Balears | + 03:22 | + 03:22 |
| 55 | Sergio Pardilla | Vina Magna - Cropu | + 03:22 | + 03:22 |
| 56 | Markel Irizar | Euskaltel-Euskadi | + 03:22 | + 03:22 |
| 57 | Joseba Zubeldia | Euskaltel-Euskadi | + 03:22 | + 03:22 |
| 58 | Jaume Rovira | Andalucia - Paul Versan | + 03:22 | + 03:22 |
| 59 | Patrick Mccarty Jonathan | Phonak Hearing Systems | + 03:22 | + 03:22 |
| 60 | Beat Zberg | Gerolsteiner | + 03:22 | + 03:22 |
| 61 | Niels Scheuneman | Rabobank | + 03:22 | + 03:22 |
| 62 | Andy Schleck | Team CSC | + 03:22 | + 03:22 |
| 63 | Luis Fernandez Oliveira | Phonak Hearing Systems | + 03:22 | + 03:22 |
| 64 | Antonio Berasategui | Kaiku | + 03:22 | + 03:22 |
| 65 | Juan Gomis Lopez | Comunidad Valenciana | + 03:22 | + 03:22 |
| 66 | Javier Ruiz de Larrinaga | Kaiku | + 03:22 | + 03:22 |
| 67 | Ivan Gilmartin | Kaiku | + 03:22 | + 03:22 |
| 68 | Marcus Burghardt | T-Mobile Team | + 05:27 | + 05:27 |
| 69 | Wim van Huffel | Davitamon - Lotto | + 05:27 | + 05:27 |
| 70 | Thomas Dekker | Rabobank | + 06:52 | + 06:52 |
| 71 | Yuriy Krivtsov | AG2R Prévoyance | + 09:21 | + 09:21 |
| 72 | Gustavo Veloso | Kaiku | + 09:21 | + 09:21 |
| 73 | Filippo Pozzato | Quick Step - Innergetic | + 10:16 | + 10:16 |
| 74 | Bert Grabsch | Phonak Hearing Systems | + 10:16 | + 10:16 |
| 75 | Ivan Santaromita | Quick Step - Innergetic | + 10:16 | + 10:16 |
| 76 | Volodymir Gustov | Team CSC | + 10:16 | + 10:16 |
| 77 | José Cobo Juan | Saunier Duval - Prodir | + 10:16 | + 10:16 |
| 78 | Luengo Celaya Anton | Euskaltel-Euskadi | + 10:16 | + 10:16 |
| 79 | Serge Baguet | Quick Step - Innergetic | + 10:16 | + 10:16 |
| 80 | Wim Vansevenant | Davitamon - Lotto | + 10:16 | + 10:16 |
| 81 | Addy Engels | Quick Step - Innergetic | + 10:16 | + 10:16 |
| 82 | Ruben Lobato | Saunier Duval - Prodir | + 12:31 | + 12:31 |
| 83 | Ángel Martin Miguel | Phonak Hearing Systems | + 12:31 | + 12:31 |
| 84 | Steve Morabito | Phonak Hearing Systems | + 12:31 | + 12:31 |
| 85 | Manuel Vazquez | Andalucia - Paul Versan | + 12:31 | + 12:31 |
| 86 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 12:31 | + 12:31 |
| 87 | Thomas Fothen | Gerolsteiner | + 12:31 | + 12:31 |
| 88 | Volker Ordowski | Gerolsteiner | + 12:31 | + 12:31 |
| 89 | Santos Gonzalez | 3 Molinos Resort | + 12:31 | + 12:31 |
| 90 | Jan Hruska | 3 Molinos Resort | + 12:31 | + 12:31 |
| 91 | Antonio Tauler Llull | 3 Molinos Resort | + 12:31 | + 12:31 |
| 92 | Sergio Herrero | Vina Magna - Cropu | + 12:31 | + 12:31 |
| 93 | Andrea Peron | Team CSC | + 12:31 | + 12:31 |
| 94 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 12:31 | + 12:31 |
| 95 | Israel Nunez Baticon | Kaiku | + 12:31 | + 12:31 |
| 96 | Christian Vande Velde | Team CSC | + 12:31 | + 12:31 |
| 97 | Diego Gallego | Vina Magna - Cropu | + 12:31 | + 12:31 |
| 98 | Imanol Erviti | Caisse d'Epargne - Illes Balears | + 12:31 | + 12:31 |
| 99 | Manuel Lloret | Comunidad Valenciana | + 12:31 | + 12:31 |
| 100 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 12:31 | + 12:31 |
| 101 | Adrian Bonilla | Comunidad Valenciana | + 12:31 | + 12:31 |
| 102 | Hubert Schwab | Quick Step - Innergetic | + 12:31 | + 12:31 |
| 103 | Alexandre Moos | Phonak Hearing Systems | + 12:31 | + 12:31 |
| 104 | Isidro Cerrato Lopez | 3 Molinos Resort | + 12:31 | + 12:31 |
| 105 | Jorge García Marín | Relax - GAM | + 13:13 | + 13:13 |
| 106 | Jose Terciado Francisco | Relax - GAM | + 13:13 | + 13:13 |
| 107 | Javier Benitez | Grupo Nicolas Mateos | + 16:02 | + 16:02 |
| 108 | Nicola Loda | Liquigas | + 16:09 | + 16:09 |
| 109 | Kjell Carlström | Liquigas | + 16:09 | + 16:09 |
| 110 | Manuel Garate Juan | Quick Step - Innergetic | + 16:09 | + 16:09 |
| 111 | Joseba Agirrezabala | Grupo Nicolas Mateos | + 16:09 | + 16:09 |
| 112 | Ivan Seledkov | Omnibike Dynamo Moscow | + 16:09 | + 16:09 |
| 113 | Alberto Benitez Jose | Saunier Duval - Prodir | + 16:09 | + 16:09 |
| 114 | Martin Mata Cabello | Grupo Nicolas Mateos | + 16:09 | + 16:09 |
| 115 | Jose Herrada | Vina Magna - Cropu | + 16:09 | + 16:09 |
| 116 | Alberto Fernandez | Saunier Duval - Prodir | + 16:09 | + 16:09 |
| 117 | Arkaitz Durán | Saunier Duval - Prodir | + 16:09 | + 16:09 |
| 118 | Luis Arrieta José | AG2R Prévoyance | + 16:09 | + 16:09 |
| 119 | Iker Leonet Iza | Caisse d'Epargne - Illes Balears | + 16:09 | + 16:09 |
| 120 | Davide Bramati | Quick Step - Innergetic | + 16:16 | + 16:16 |
| 121 | Luca Paolini | Liquigas | + 18:50 | + 18:50 |
| 122 | Michael Albasini | Liquigas | + 18:50 | + 18:50 |
| 123 | Manuel Ortega | Andalucia - Paul Versan | + 21:30 | + 21:30 |
| 124 | Charles Dionne | Saunier Duval - Prodir | + 22:34 | + 22:34 |
| 125 | David Kopp | Gerolsteiner | + 24:01 | + 24:01 |
| 126 | Stefan Schumacher | Gerolsteiner | + 24:01 | + 24:01 |
| 127 | Hugo Pena Victor | Phonak Hearing Systems | + 24:01 | + 24:01 |
| 128 | Steffen Wesemann | T-Mobile Team | + 24:01 | + 24:01 |
| 129 | Andreas Klier | T-Mobile Team | + 24:01 | + 24:01 |
| 130 | Scott Davis | T-Mobile Team | + 24:01 | + 24:01 |
| 131 | Mario Aerts | Davitamon - Lotto | + 24:01 | + 24:01 |
| 132 | Johan Vansummeren | Davitamon - Lotto | + 24:01 | + 24:01 |
| 133 | Linus Gerdemann | T-Mobile Team | + 24:01 | + 24:01 |
| 134 | Peter Luttenberger | Team CSC | + 24:01 | + 24:01 |
| 135 | Marc Wauters | Rabobank | + 24:01 | + 24:01 |
| 136 | Pedro Horrillo | Rabobank | + 24:01 | + 24:01 |
| 137 | Joan Horrach | Caisse d'Epargne - Illes Balears | + 24:01 | + 24:01 |
| 138 | Daniele Nardello | T-Mobile Team | + 24:01 | + 24:01 |
| 139 | Markus Zberg | Gerolsteiner | + 24:01 | + 24:01 |
| 140 | Jose Box Quinto Mario | 3 Molinos Resort | + 24:01 | + 24:01 |
| 141 | Davide Vigano | Quick Step - Innergetic | + 24:01 | + 24:01 |
| 142 | Andrey Klyuev | Omnibike Dynamo Moscow | + 35:11 | + 35:11 |
| 143 | Viacheslav Vilkov | Omnibike Dynamo Moscow | + 37:13 | + 37:13 |