| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Antonio Colom | Astana | 04:06:13 | |
| 2 | León Sánchez Luis | Caisse d'Epargne | + 00 | |
| 3 | Alberto Contador | Discovery Channel | + 00 | |
| 4 | Vicente Reynès | Caisse d'Epargne | + 13 | + 13 |
| 5 | Vincenzo Nibali | Liquigas | + 13 | + 13 |
| 6 | Lorenzo Bernucci | T-Mobile Team | + 13 | + 13 |
| 7 | Vladimir Gusev | Discovery Channel | + 13 | + 13 |
| 8 | Jorge Ferrio Luque | Andalucia - Cajasur | + 13 | + 13 |
| 9 | Adrian Bonilla | Fuerteventura - Canarias | + 13 | + 13 |
| 10 | Iker Camaño | Saunier Duval - Prodir | + 13 | + 13 |
| 11 | Francisco Mancebo | Relax - GAM | + 13 | + 13 |
| 12 | Alberto Fernandez | Saunier Duval - Prodir | + 13 | + 13 |
| 13 | Ezequiel Mosquera | Karpin-Galicia | + 13 | + 13 |
| 14 | David de La Fuente | Saunier Duval - Prodir | + 13 | + 13 |
| 15 | Daniel Moreno | Relax - GAM | + 13 | + 13 |
| 16 | Ángel Gómez | Saunier Duval - Prodir | + 48 | + 48 |
| 17 | Murilo Fischer | Liquigas | + 01:13 | + 01:13 |
| 18 | Jesus Del Nero Montes | Saunier Duval - Prodir | + 01:13 | + 01:13 |
| 19 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 01:13 | + 01:13 |
| 20 | Javier Moreno | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 21 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 01:13 | + 01:13 |
| 22 | Vicente Ballester Martinez | Fuerteventura - Canarias | + 01:13 | + 01:13 |
| 23 | Serge Baguet | Quick Step - Innergetic | + 01:13 | + 01:13 |
| 24 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 01:13 | + 01:13 |
| 25 | Michael Schär | Astana | + 01:13 | + 01:13 |
| 26 | Thomas Frei | Astana | + 01:13 | + 01:13 |
| 27 | Jorge Azanza | Euskaltel-Euskadi | + 01:13 | + 01:13 |
| 28 | Erik Zabel | Team Milram | + 01:13 | + 01:13 |
| 29 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 30 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 01:13 | + 01:13 |
| 31 | Steve Morabito | Astana | + 01:13 | + 01:13 |
| 32 | Ivan Santaromita | Quick Step - Innergetic | + 01:13 | + 01:13 |
| 33 | Fernando Torres Martin | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 34 | Tim Klinger | Gerolsteiner | + 01:13 | + 01:13 |
| 35 | Aitor Hernández | Euskaltel-Euskadi | + 01:13 | + 01:13 |
| 36 | José Oroz Juan | Orbea - Laukiz F.T. | + 01:13 | + 01:13 |
| 37 | Diego Gallego | Vina Magna - Cropu | + 01:13 | + 01:13 |
| 38 | Gustavo Dominguez Lemos | Karpin-Galicia | + 01:13 | + 01:13 |
| 39 | Thomas Ziegler | T-Mobile Team | + 01:13 | + 01:13 |
| 40 | Jesus Rosendo Prado | Andalucia - Cajasur | + 01:13 | + 01:13 |
| 41 | Linus Gerdemann | T-Mobile Team | + 01:13 | + 01:13 |
| 42 | Javier Etxarri | Grupo Nicolas Mateos | + 01:13 | + 01:13 |
| 43 | Pedro Romero Ocampo | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 44 | Alberto Rodriguez | Vina Magna - Cropu | + 01:13 | + 01:13 |
| 45 | Stijn Devolder | Discovery Channel | + 01:13 | + 01:13 |
| 46 | Manuel Ortega | Andalucia - Cajasur | + 01:13 | + 01:13 |
| 47 | Maxim Iglinskiy | Astana | + 01:13 | + 01:13 |
| 48 | Patrick Calcagni | Liquigas | + 01:13 | + 01:13 |
| 49 | Luengo Celaya Anton | Euskaltel-Euskadi | + 01:13 | + 01:13 |
| 50 | Angel Vallejo Dominquez | Relax - GAM | + 01:13 | + 01:13 |
| 51 | Pieter Weening | Rabobank | + 01:13 | + 01:13 |
| 52 | Juan Olmo | Andalucia - Cajasur | + 01:13 | + 01:13 |
| 53 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 54 | David Bernabeu | Fuerteventura - Canarias | + 01:13 | + 01:13 |
| 55 | Koos Moerenhout | Rabobank | + 01:13 | + 01:13 |
| 56 | Michael Boogerd | Rabobank | + 01:13 | + 01:13 |
| 57 | Francisco Pérez | Caisse d'Epargne | + 01:13 | + 01:13 |
| 58 | Antonio Tauler Llull | + 01:13 | + 01:13 | |
| 59 | Manuel Garate Juan | Quick Step - Innergetic | + 01:13 | + 01:13 |
| 60 | Guido Trenti | Liquigas | + 01:13 | + 01:13 |
| 61 | Jose Ruiz Sanchez | Andalucia - Cajasur | + 01:13 | + 01:13 |
| 62 | Joan Llaneras Rosello | + 01:13 | + 01:13 | |
| 63 | Angel Vicioso | Relax - GAM | + 01:13 | + 01:13 |
| 64 | Rubens Bertogliati | Saunier Duval - Prodir | + 01:13 | + 01:13 |
| 65 | David Martin Peribanez | Vina Magna - Cropu | + 01:13 | + 01:13 |
| 66 | Andreas Klier | T-Mobile Team | + 01:13 | + 01:13 |
| 67 | Thomas Dekker | Rabobank | + 01:13 | + 01:13 |
| 68 | Oscar Garcia-casarrubios | Relax - GAM | + 01:13 | + 01:13 |
| 69 | Jesús Hernández | Relax - GAM | + 01:13 | + 01:13 |
| 70 | Antonio Flecha Juan | Rabobank | + 01:13 | + 01:13 |
| 71 | Remmert Wielinga | Saunier Duval - Prodir | + 01:13 | + 01:13 |
| 72 | Óscar Freire | Rabobank | + 01:13 | + 01:13 |
| 73 | David López | Caisse d'Epargne | + 01:13 | + 01:13 |
| 74 | Ignacio Sarabia | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 75 | José Cobo Juan | Saunier Duval - Prodir | + 01:13 | + 01:13 |
| 76 | Jose Herrada | Vina Magna - Cropu | + 01:13 | + 01:13 |
| 77 | Iban Mayo | Saunier Duval - Prodir | + 01:13 | + 01:13 |
| 78 | Giuseppe Guerini | T-Mobile Team | + 01:13 | + 01:13 |
| 79 | Josu Mondelo Diaz | Spiuk - Extremadura | + 01:13 | + 01:13 |
| 80 | Manuel Lloret | Fuerteventura - Canarias | + 03:51 | + 03:51 |
| 81 | Ralf Grabsch | Team Milram | + 04:12 | + 04:12 |
| 82 | Davide Vigano | Quick Step - Innergetic | + 04:12 | + 04:12 |
| 83 | Pavel Padrnos | Discovery Channel | + 05:10 | + 05:10 |
| 84 | Manuel Vazquez | Andalucia - Cajasur | + 05:47 | + 05:47 |
| 85 | Iban Mayoz | Euskaltel-Euskadi | + 05:47 | + 05:47 |
| 86 | Joan Horrach | Caisse d'Epargne | + 05:47 | + 05:47 |
| 87 | Thomas Fothen | Gerolsteiner | + 05:47 | + 05:47 |
| 88 | Ronny Scholz | Gerolsteiner | + 05:47 | + 05:47 |
| 89 | Matej Jurco | Team Milram | + 05:47 | + 05:47 |
| 90 | Oleg Chuzhda | Fuerteventura - Canarias | + 05:47 | + 05:47 |
| 91 | David Millar | Saunier Duval - Prodir | + 05:47 | + 05:47 |
| 92 | Markel Irizar | Euskaltel-Euskadi | + 05:47 | + 05:47 |
| 93 | Rodrigo Garcia Rena | Fuerteventura - Canarias | + 06:51 | + 06:51 |
| 94 | Patrik Sinkewitz | T-Mobile Team | + 06:51 | + 06:51 |
| 95 | Benoit Joachim | Astana | + 06:51 | + 06:51 |
| 96 | José Abril Merino Juan | Vina Magna - Cropu | + 06:51 | + 06:51 |
| 97 | Eduardo Gonzalo Ramirez | Agritubel | + 06:51 | + 06:51 |
| 98 | Lander Aperribay Aranda | Euskaltel-Euskadi | + 06:51 | + 06:51 |
| 99 | Jorge García Marín | Relax - GAM | + 06:51 | + 06:51 |
| 100 | Jose Terciado Francisco | Relax - GAM | + 06:51 | + 06:51 |
| 101 | José Martínez Francisco | Andalucia - Cajasur | + 06:51 | + 06:51 |
| 102 | Iker Mezo Askargorta | Orbea - Laukiz F.T. | + 06:51 | + 06:51 |
| 103 | Alessandro Spezialetti | Liquigas | + 06:57 | + 06:57 |
| 104 | Björn Schröder | Team Milram | + 06:57 | + 06:57 |
| 105 | José Casas Claudio | Andalucia - Cajasur | + 08:58 | + 08:58 |
| 106 | Beat Zberg | Gerolsteiner | + 10:09 | + 10:09 |
| 107 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 10:09 | + 10:09 |
| 108 | Jan Hruska | Relax - GAM | + 10:09 | + 10:09 |
| 109 | Egoitz Murgoitio Rekalde | Grupo Nicolas Mateos | + 10:09 | + 10:09 |
| 110 | Trent Lowe | Discovery Channel | + 10:09 | + 10:09 |
| 111 | Eric Baumann | T-Mobile Team | + 10:09 | + 10:09 |
| 112 | Sebastian Lang | Gerolsteiner | + 10:09 | + 10:09 |
| 113 | Volodymyr Bileka | Discovery Channel | + 10:09 | + 10:09 |
| 114 | Andrey Mizurov | Astana | + 10:09 | + 10:09 |
| 115 | Gianni Meersman | Discovery Channel | + 10:09 | + 10:09 |
| 116 | Tomas Vaitkus | Discovery Channel | + 10:09 | + 10:09 |
| 117 | Carlos Castaño | Karpin-Galicia | + 10:09 | + 10:09 |
| 118 | Julian Sanchez | Relax - GAM | + 10:09 | + 10:09 |
| 119 | Manuel Calvente | Agritubel | + 10:09 | + 10:09 |
| 120 | Mathieu Perget | Caisse d'Epargne | + 10:09 | + 10:09 |
| 121 | David García Dapena | Karpin-Galicia | + 10:09 | + 10:09 |
| 122 | Antonio Arroyo Ramirez Jose | Spiuk - Extremadura | + 10:09 | + 10:09 |
| 123 | Joseba Zubeldia | Euskaltel-Euskadi | + 10:09 | + 10:09 |
| 124 | Alan Perez Lezaun | Euskaltel-Euskadi | + 10:09 | + 10:09 |
| 125 | Luis Rubiera José | Discovery Channel | + 13:20 | + 13:20 |
| 126 | Steve Cummings | Discovery Channel | + 13:20 | + 13:20 |
| 127 | Sebastian Schwager | Team Milram | + 18:14 | + 18:14 |
| 128 | Johannes Fröhlinger | Gerolsteiner | + 18:14 | + 18:14 |
| 129 | David Muñoz | Fuerteventura - Canarias | + 18:14 | + 18:14 |
| 130 | Manuel Diaz Armas Dailos | Fuerteventura - Canarias | + 18:14 | + 18:14 |
| 131 | Sergei Ivanov | Astana | + 18:14 | + 18:14 |
| 132 | Jesus Tendero Marcos | Vina Magna - Cropu | + 18:14 | + 18:14 |
| 133 | Pedro Horrillo | Rabobank | + 18:14 | + 18:14 |
| 134 | Kai Reus | Rabobank | + 18:14 | + 18:14 |
| 135 | Sebastien Siedler | Team Milram | + 18:14 | + 18:14 |
| 136 | Andre Korff | T-Mobile Team | + 18:14 | + 18:14 |
| 137 | Marcus Burghardt | T-Mobile Team | + 18:14 | + 18:14 |
| 138 | David Martin | Orbea - Laukiz F.T. | + 18:14 | + 18:14 |
| 139 | Michael Albasini | Liquigas | + 18:14 | + 18:14 |
| 140 | Bert Grabsch | T-Mobile Team | + 18:14 | + 18:14 |
| 141 | William Walker | Rabobank | + 18:14 | + 18:14 |
| 142 | Dmitriy Muravyev | Astana | + 18:14 | + 18:14 |
| 143 | Julien Mazet | Astana | + 18:14 | + 18:14 |
| 144 | Marcel Sieberg | Team Milram | + 23:01 | + 23:01 |
| 145 | Christian Knees | Team Milram | + 23:01 | + 23:01 |
| 146 | Alessandro Proni | Quick Step - Innergetic | + 23:01 | + 23:01 |