| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Antonio Colom | Illes Balears - Caisse d'Epargne | 03:52:00 | |
| 2 | Antonio Pecharroman Jose | Quick Step | + 02 | + 02 |
| 3 | David de La Fuente | Saunier Duval - Prodir | + 02 | + 02 |
| 4 | Alejandro Valverde | Illes Balears - Caisse d'Epargne | + 09 | + 09 |
| 5 | Aitor Perez Arrieta | Spiuk | + 09 | + 09 |
| 6 | Ángel Edo | Saunier Duval - Prodir | + 09 | + 09 |
| 7 | Ricardo Serrano | Kaiku | + 09 | + 09 |
| 8 | Marc Lotz | Quick Step | + 09 | + 09 |
| 9 | Javier Cherro Molina | Comunidad Valenciana | + 09 | + 09 |
| 10 | Mathew Hayman | Rabobank | + 09 | + 09 |
| 11 | Josep Jufré | Relax - Fuenlabarda | + 09 | + 09 |
| 12 | Andreas Klier | Discovery Channel | + 09 | + 09 |
| 13 | David Muñoz | Comunidad Valenciana | + 09 | + 09 |
| 14 | Jaume Rovira | Andalucia - Paul Versan | + 09 | + 09 |
| 15 | Mario Almagro Valero Jose | Relax - Fuenlabarda | + 09 | + 09 |
| 16 | Raul Garcia de Mateos | Relax - Fuenlabarda | + 09 | + 09 |
| 17 | Ángel Gómez | Saunier Duval - Prodir | + 09 | + 09 |
| 18 | Grischa Niermann | Rabobank | + 09 | + 09 |
| 19 | Addy Engels | Quick Step | + 09 | + 09 |
| 20 | Ruben Oarbeascoa Ispizua | Kaiku | + 09 | + 09 |
| 21 | David Fernandez | Andalucia - Paul Versan | + 09 | + 09 |
| 22 | Aaron Villegas Trapaga | Orbea | + 09 | + 09 |
| 23 | David Canada | Saunier Duval - Prodir | + 09 | + 09 |
| 24 | Manuel Garate Juan | Saunier Duval - Prodir | + 09 | + 09 |
| 25 | Luis Pasamontes | Relax - Fuenlabarda | + 09 | + 09 |
| 26 | Xavier Tondó | Catalunya - Angel Mir | + 09 | + 09 |
| 27 | Thorwald Veneberg | Rabobank | + 09 | + 09 |
| 28 | Tadej Valjavec | Phonak Hearing Systems | + 09 | + 09 |
| 29 | Moisés Dueñas | Relax - Fuenlabarda | + 09 | + 09 |
| 30 | Adrian Palomares | Kaiku | + 09 | + 09 |
| 31 | Adolfo Garcia Quesada | Comunidad Valenciana | + 09 | + 09 |
| 32 | Antonio Olmo | Comunidad Valenciana | + 09 | + 09 |
| 33 | Antonio Tauler Llull | Illes Balears - Caisse d'Epargne | + 09 | + 09 |
| 34 | Igor Anton | Euskaltel-Euskadi | + 09 | + 09 |
| 35 | Luis Martinez Jose | Comunidad Valenciana | + 09 | + 09 |
| 36 | Maarten den Bakker | Rabobank | + 09 | + 09 |
| 37 | David Bernabeu | Comunidad Valenciana | + 09 | + 09 |
| 38 | David López | Euskaltel-Euskadi | + 09 | + 09 |
| 39 | Sergio Domínguez Muñoz | + 09 | + 09 | |
| 40 | Patrik Sinkewitz | Quick Step | + 09 | + 09 |
| 41 | José Gomez | Saunier Duval - Prodir | + 23 | + 23 |
| 42 | Joseba Agirrezabala | + 28 | + 28 | |
| 43 | Óscar Freire | Rabobank | + 28 | + 28 |
| 44 | Ezequiel Mosquera | Kaiku | + 01:12 | + 01:12 |
| 45 | Steven de Jongh | Rabobank | + 01:24 | + 01:24 |
| 46 | Erik Zabel | T-Mobile Team | + 01:24 | + 01:24 |
| 47 | Efrain Gutierrez Sanchez | Andalucia - Paul Versan | + 01:24 | + 01:24 |
| 48 | Alberto Benitez Jose | Spiuk | + 01:24 | + 01:24 |
| 49 | Israel Nunez Baticon | Kaiku | + 01:24 | + 01:24 |
| 50 | Rolf Aldag | T-Mobile Team | + 01:24 | + 01:24 |
| 51 | Gustavo Veloso | Kaiku | + 01:24 | + 01:24 |
| 52 | Xavier Florencio | Relax - Fuenlabarda | + 01:24 | + 01:24 |
| 53 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 01:27 | + 01:27 |
| 54 | Oliver Zaugg | Saunier Duval - Prodir | + 01:27 | + 01:27 |
| 55 | Ruben Lobato | Saunier Duval - Prodir | + 01:27 | + 01:27 |
| 56 | Marc Wauters | Rabobank | + 01:27 | + 01:27 |
| 57 | Karsten Kroon | Rabobank | + 01:27 | + 01:27 |
| 58 | Javier Ramirez Torres Jesus | Spiuk | + 01:27 | + 01:27 |
| 59 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 01:27 | + 01:27 |
| 60 | Xabat Ochotorena | Orbea | + 02:30 | + 02:30 |
| 61 | David Herrero | Euskaltel-Euskadi | + 03:19 | + 03:19 |
| 62 | Carlos Castaño | Andalucia - Paul Versan | + 03:19 | + 03:19 |
| 63 | Sergio Escobar Roure | Illes Balears - Caisse d'Epargne | + 03:19 | + 03:19 |
| 64 | Julen Zubero Aldekoa | Orbea | + 03:19 | + 03:19 |
| 65 | Manuel Diaz Armas Dailos | Orbea | + 03:19 | + 03:19 |
| 66 | Torsten Hiekmann | T-Mobile Team | + 05:56 | + 05:56 |
| 67 | Rory Sutherland | Rabobank | + 05:56 | + 05:56 |
| 68 | Carlos Torrent | Catalunya - Angel Mir | + 08:32 | + 08:32 |
| 69 | Pablo Lastras | Illes Balears - Caisse d'Epargne | + 08:36 | + 08:36 |
| 70 | Nacor Burgos | Relax - Fuenlabarda | + 08:36 | + 08:36 |
| 71 | Xabier Zandio | Illes Balears - Caisse d'Epargne | + 08:36 | + 08:36 |
| 72 | Joaquim Rodríguez | Saunier Duval - Prodir | + 08:36 | + 08:36 |
| 73 | Angel Vallejo Dominquez | Relax - Fuenlabarda | + 08:36 | + 08:36 |
| 74 | Daniel Moreno | Relax - Fuenlabarda | + 08:36 | + 08:36 |
| 75 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 08:36 | + 08:36 |
| 76 | Eloy Teruel | + 08:36 | + 08:36 | |
| 77 | Niki Aebersold | Phonak Hearing Systems | + 08:36 | + 08:36 |
| 78 | Jon Bru | Kaiku | + 08:36 | + 08:36 |
| 79 | Bernhard Kohl | T-Mobile Team | + 08:36 | + 08:36 |
| 80 | Iker Mezo Askargorta | Orbea | + 08:36 | + 08:36 |
| 81 | Pablo Urtasun | Kaiku | + 08:36 | + 08:36 |
| 82 | Alexandre Moos | Phonak Hearing Systems | + 08:36 | + 08:36 |
| 83 | Andoni Aranaga Akzune | Kaiku | + 08:36 | + 08:36 |
| 84 | Alberto Lopez | Euskaltel-Euskadi | + 08:36 | + 08:36 |
| 85 | Javier Ruiz de Larrinaga | Kaiku | + 08:36 | + 08:36 |
| 86 | Unai Osa | Illes Balears - Caisse d'Epargne | + 08:36 | + 08:36 |
| 87 | Alan Perez Lezaun | Orbea | + 11:10 | + 11:10 |
| 88 | Luis Perez Romero | Relax - Fuenlabarda | + 12:41 | + 12:41 |
| 89 | Gorka Arrizabalaga Agirre | Orbea | + 16:10 | + 16:10 |
| 90 | Alberto Rodriguez | Catalunya - Angel Mir | + 16:10 | + 16:10 |
| 91 | Unai Elorriaga Zubiaur | + 16:10 | + 16:10 |