| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | David Kopp | Gerolsteiner | 03:50:11 | |
| 2 | Lorenzo Bernucci | T-Mobile Team | + 00 | |
| 3 | Iñaki Isasi | Euskaltel-Euskadi | + 00 | |
| 4 | Julian Sanchez | Comunidad Valenciana | + 00 | |
| 5 | Martin Elmiger | Phonak Hearing Systems | + 02 | + 02 |
| 6 | Jorge Azanza | Kaiku | + 02 | + 02 |
| 7 | Javier Benitez | Grupo Nicolas Mateos | + 02 | + 02 |
| 8 | Linus Gerdemann | T-Mobile Team | + 02 | + 02 |
| 9 | Markus Zberg | Gerolsteiner | + 02 | + 02 |
| 10 | Koos Moerenhout | Phonak Hearing Systems | + 02 | + 02 |
| 11 | Joseba Albizu Lizaso | Euskaltel-Euskadi | + 02 | + 02 |
| 12 | Constantino Zaballa | Caisse d'Epargne - Illes Balears | + 02 | + 02 |
| 13 | Luis Marichalar Pedro | Andalucia - Paul Versan | + 02 | + 02 |
| 14 | Ángel Edo | Andalucia - Paul Versan | + 02 | + 02 |
| 15 | Antonio Flecha Juan | Rabobank | + 02 | + 02 |
| 16 | Jon Bru | Kaiku | + 02 | + 02 |
| 17 | Steffen Wesemann | T-Mobile Team | + 02 | + 02 |
| 18 | Dario Cioni | Liquigas | + 02 | + 02 |
| 19 | Kim Kirchen | T-Mobile Team | + 02 | + 02 |
| 20 | Rodrigo Garcia Rena | Kaiku | + 02 | + 02 |
| 21 | Mario Aerts | Davitamon - Lotto | + 02 | + 02 |
| 22 | Ángel Gómez | Saunier Duval - Prodir | + 02 | + 02 |
| 23 | Josep Jufré | Davitamon - Lotto | + 02 | + 02 |
| 24 | Ignacio Gutierrez | Phonak Hearing Systems | + 02 | + 02 |
| 25 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 10 | + 10 |
| 26 | Israel Nunez Baticon | Kaiku | + 10 | + 10 |
| 27 | David Muñoz | Comunidad Valenciana | + 10 | + 10 |
| 28 | Luis Perez Romero | Andalucia - Paul Versan | + 10 | + 10 |
| 29 | Sergio Herrero | Vina Magna - Cropu | + 10 | + 10 |
| 30 | Jesus Del Nero Montes | 3 Molinos Resort | + 10 | + 10 |
| 31 | Andoni Aranaga Akzune | Euskaltel-Euskadi | + 10 | + 10 |
| 32 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 10 | + 10 |
| 33 | David Bernabeu | Comunidad Valenciana | + 10 | + 10 |
| 34 | Fränk Schleck | Team CSC | + 10 | + 10 |
| 35 | Carlos Castaño | Kaiku | + 10 | + 10 |
| 36 | Sergio Escobar Roure | Grupo Nicolas Mateos | + 10 | + 10 |
| 37 | Oscar Garcia-casarrubios | Relax - GAM | + 10 | + 10 |
| 38 | Enrique Gutiérrez José | Phonak Hearing Systems | + 10 | + 10 |
| 39 | Samuel Dumoulin | AG2R Prévoyance | + 10 | + 10 |
| 40 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 10 | + 10 |
| 41 | Leonardo Scarselli | Quick Step - Innergetic | + 10 | + 10 |
| 42 | Francisco Cabello | Andalucia - Paul Versan | + 10 | + 10 |
| 43 | Jesús Hernández | Relax - GAM | + 10 | + 10 |
| 44 | Gerardo Fernandez | Vina Magna - Cropu | + 10 | + 10 |
| 45 | Grischa Niermann | Rabobank | + 10 | + 10 |
| 46 | Gorka Verdugo | Euskaltel-Euskadi | + 10 | + 10 |
| 47 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 10 | + 10 |
| 48 | Volker Ordowski | Gerolsteiner | + 10 | + 10 |
| 49 | Bram de Groot | Rabobank | + 10 | + 10 |
| 50 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 10 | + 10 |
| 51 | Santos Gonzalez | 3 Molinos Resort | + 10 | + 10 |
| 52 | Servais Knaven | Quick Step - Innergetic | + 10 | + 10 |
| 53 | Alexandr Kolobnev | Rabobank | + 10 | + 10 |
| 54 | Jan Hruska | 3 Molinos Resort | + 10 | + 10 |
| 55 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 10 | + 10 |
| 56 | Patrick Mccarty Jonathan | Phonak Hearing Systems | + 10 | + 10 |
| 57 | Luis Fernandez Oliveira | Phonak Hearing Systems | + 10 | + 10 |
| 58 | Manuel Garate Juan | Quick Step - Innergetic | + 10 | + 10 |
| 59 | Stefan Schumacher | Gerolsteiner | + 10 | + 10 |
| 60 | Beat Zberg | Gerolsteiner | + 10 | + 10 |
| 61 | Volodymir Gustov | Team CSC | + 10 | + 10 |
| 62 | Addy Engels | Quick Step - Innergetic | + 10 | + 10 |
| 63 | Antonio Tauler Llull | 3 Molinos Resort | + 10 | + 10 |
| 64 | Mario Almagro Valero Jose | Relax - GAM | + 10 | + 10 |
| 65 | Steve Zamperi | Phonak Hearing Systems | + 10 | + 10 |
| 66 | Iker Leonet Iza | Caisse d'Epargne - Illes Balears | + 10 | + 10 |
| 67 | Francisco Pérez | Caisse d'Epargne - Illes Balears | + 10 | + 10 |
| 68 | Íñigo Cuesta | Team CSC | + 10 | + 10 |
| 69 | Javier Moreno | Grupo Nicolas Mateos | + 10 | + 10 |
| 70 | Inigo Chaurreau | AG2R Prévoyance | + 10 | + 10 |
| 71 | Alexandre Moos | Phonak Hearing Systems | + 10 | + 10 |
| 72 | Juan Gomis Lopez | Comunidad Valenciana | + 10 | + 10 |
| 73 | Joseba Zubeldia | Euskaltel-Euskadi | + 10 | + 10 |
| 74 | Markel Irizar | Euskaltel-Euskadi | + 10 | + 10 |
| 75 | Adrian Palomares | Kaiku | + 21 | + 21 |
| 76 | Sergei Ivanov | T-Mobile Team | + 21 | + 21 |
| 77 | Gilberto Simoni | Saunier Duval - Prodir | + 21 | + 21 |
| 78 | Johan Vansummeren | Davitamon - Lotto | + 21 | + 21 |
| 79 | Michael Boogerd | Rabobank | + 21 | + 21 |
| 80 | Joost Posthuma | Rabobank | + 21 | + 21 |
| 81 | Luis Arrieta José | AG2R Prévoyance | + 21 | + 21 |
| 82 | Thomas Ziegler | T-Mobile Team | + 21 | + 21 |
| 83 | Marcus Burghardt | T-Mobile Team | + 21 | + 21 |
| 84 | Thomas Dekker | Rabobank | + 21 | + 21 |
| 85 | Gregory Rast | Phonak Hearing Systems | + 21 | + 21 |
| 86 | Adrian Bonilla | Comunidad Valenciana | + 21 | + 21 |
| 87 | Alberto Losada | Kaiku | + 52 | + 52 |
| 88 | José Gomez | Saunier Duval - Prodir | + 02:32 | + 02:32 |
| 89 | Jose Terciado Francisco | Relax - GAM | + 02:32 | + 02:32 |
| 90 | Vladimir Miholjevic | Liquigas | + 04:30 | + 04:30 |
| 91 | Theo Eltink | Rabobank | + 04:30 | + 04:30 |
| 92 | Gustavo Veloso | Kaiku | + 04:30 | + 04:30 |
| 93 | Mikel Astarloza | AG2R Prévoyance | + 04:30 | + 04:30 |
| 94 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 04:30 | + 04:30 |
| 95 | Sergio Pardilla | Vina Magna - Cropu | + 04:30 | + 04:30 |
| 96 | Koldo Fernandez | Euskaltel-Euskadi | + 04:30 | + 04:30 |
| 97 | Javier Mejias | Saunier Duval - Prodir | + 04:30 | + 04:30 |
| 98 | Vicente Peiro Marqueno | Comunidad Valenciana | + 04:30 | + 04:30 |
| 99 | Filippo Pozzato | Quick Step - Innergetic | + 04:52 | + 04:52 |
| 100 | Francesco Chicchi | Quick Step - Innergetic | + 04:52 | + 04:52 |
| 101 | Iker Flores | Euskaltel-Euskadi | + 06:16 | + 06:16 |
| 102 | Mathew Hayman | Rabobank | + 08:17 | + 08:17 |
| 103 | Pedro Horrillo | Rabobank | + 08:17 | + 08:17 |
| 104 | Pablo Lastras | Caisse d'Epargne - Illes Balears | + 08:17 | + 08:17 |
| 105 | Joan Horrach | Caisse d'Epargne - Illes Balears | + 08:17 | + 08:17 |
| 106 | Jesus Buendia Romero | 3 Molinos Resort | + 08:17 | + 08:17 |
| 107 | David Arroyo | Caisse d'Epargne - Illes Balears | + 08:17 | + 08:17 |
| 108 | José Cobo Juan | Saunier Duval - Prodir | + 08:17 | + 08:17 |
| 109 | Imanol Erviti | Caisse d'Epargne - Illes Balears | + 11:24 | + 11:24 |
| 110 | Lloyd Mondory | AG2R Prévoyance | + 13:46 | + 13:46 |
| 111 | Ruben Lobato | Saunier Duval - Prodir | + 13:46 | + 13:46 |
| 112 | Ivan Seledkov | Omnibike Dynamo Moscow | + 13:46 | + 13:46 |
| 113 | Manuel Ortega | Andalucia - Paul Versan | + 13:49 | + 13:49 |
| 114 | Javier Ruiz de Larrinaga | Kaiku | + 13:56 | + 13:56 |
| 115 | Antonio Garrido Jose | Quick Step - Innergetic | + 13:56 | + 13:56 |
| 116 | Manuel Lloret | Comunidad Valenciana | + 13:56 | + 13:56 |
| 117 | Luis Martinez Jose | Comunidad Valenciana | + 13:56 | + 13:56 |
| 118 | Koldo Gil | Saunier Duval - Prodir | + 13:56 | + 13:56 |
| 119 | Juan Olmo | Andalucia - Paul Versan | + 13:56 | + 13:56 |
| 120 | Yuriy Krivtsov | AG2R Prévoyance | + 16:01 | + 16:01 |
| 121 | Vladislav Borisov | Omnibike Dynamo Moscow | + 16:01 | + 16:01 |
| 122 | Diego Gallego | Vina Magna - Cropu | + 17:47 | + 17:47 |
| 123 | Carlos Torrent | Vina Magna - Cropu | + 17:47 | + 17:47 |
| 124 | Mario de Sarraga Orviz | Relax - GAM | + 17:47 | + 17:47 |
| 125 | Jose Herrada | Vina Magna - Cropu | + 17:47 | + 17:47 |
| 126 | Manuel Vazquez | Andalucia - Paul Versan | + 17:47 | + 17:47 |
| 127 | Pablo Urtasun | Kaiku | + 29:06 | + 29:06 |
| 128 | Charles Dionne | Saunier Duval - Prodir | + 34:06 | + 34:06 |
| 129 | Denis Vorontsov | Omnibike Dynamo Moscow | + 34:06 | + 34:06 |
| 130 | Ivan Terenine | Omnibike Dynamo Moscow | + 34:06 | + 34:06 |