| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Unai Etxebarria Arana | Euskaltel-Euskadi | 03:57:45 | |
| 2 | Francisco Ventoso | Saunier Duval - Prodir | + 00 | |
| 3 | Murilo Fischer | Liquigas | + 00 | |
| 4 | David Kopp | Gerolsteiner | + 00 | |
| 5 | Vicente Reynès | Caisse d'Epargne | + 00 | |
| 6 | Koldo Fernandez | Euskaltel-Euskadi | + 00 | |
| 7 | Gregory Rast | Astana | + 00 | |
| 8 | Thomas Ziegler | T-Mobile Team | + 00 | |
| 9 | Kevin Hulsmans | Quick Step - Innergetic | + 00 | |
| 10 | Óscar Freire | Rabobank | + 00 | |
| 11 | Vladimir Gusev | Discovery Channel | + 00 | |
| 12 | Gennady Mikhailov | Astana | + 00 | |
| 13 | Lorenzo Bernucci | T-Mobile Team | + 00 | |
| 14 | Stefan Schumacher | Gerolsteiner | + 00 | |
| 15 | Patrick Calcagni | Liquigas | + 00 | |
| 16 | Daniel Moreno | Relax - GAM | + 00 | |
| 17 | Diego Gallego | Vina Magna - Cropu | + 00 | |
| 18 | Martin Müller | Team Milram | + 00 | |
| 19 | Aleksandr Kuschynski | Liquigas | + 00 | |
| 20 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 21 | Alberto Fernandez | Saunier Duval - Prodir | + 00 | |
| 22 | Ezequiel Mosquera | Karpin-Galicia | + 00 | |
| 23 | León Sánchez Luis | Caisse d'Epargne | + 00 | |
| 24 | Alberto Rodriguez | Vina Magna - Cropu | + 00 | |
| 25 | Volodymyr Bileka | Discovery Channel | + 00 | |
| 26 | Jorge Ferrio Luque | Andalucia - Cajasur | + 00 | |
| 27 | Gustavo Dominguez Lemos | Karpin-Galicia | + 00 | |
| 28 | Danilo Di Luca | Liquigas | + 00 | |
| 29 | Antonio Colom | Astana | + 00 | |
| 30 | Pieter Weening | Rabobank | + 00 | |
| 31 | Adrian Bonilla | Fuerteventura - Canarias | + 00 | |
| 32 | Iker Camaño | Saunier Duval - Prodir | + 00 | |
| 33 | Fernando Torres Martin | Spiuk - Extremadura | + 00 | |
| 34 | Manuel Garate Juan | Quick Step - Innergetic | + 00 | |
| 35 | Joan Llaneras Rosello | + 00 | ||
| 36 | Vicente Ballester Martinez | Fuerteventura - Canarias | + 00 | |
| 37 | Ivan Santaromita | Quick Step - Innergetic | + 09 | + 09 |
| 38 | Marc de Maar | Rabobank | + 13 | + 13 |
| 39 | Daniel Navarro | Astana | + 22 | + 22 |
| 40 | Alberto Contador | Discovery Channel | + 22 | + 22 |
| 41 | Trent Lowe | Discovery Channel | + 22 | + 22 |
| 42 | Kevin Seeldraeyers | Quick Step - Innergetic | + 22 | + 22 |
| 43 | Gianni Meersman | Discovery Channel | + 22 | + 22 |
| 44 | Francisco Pérez | Caisse d'Epargne | + 22 | + 22 |
| 45 | Jesús Hernández | Relax - GAM | + 22 | + 22 |
| 46 | David López | Caisse d'Epargne | + 22 | + 22 |
| 47 | Joost Posthuma | Rabobank | + 22 | + 22 |
| 48 | Rodrigo Garcia Rena | Fuerteventura - Canarias | + 22 | + 22 |
| 49 | Luis Rubiera José | Discovery Channel | + 22 | + 22 |
| 50 | Tim Klinger | Gerolsteiner | + 31 | + 31 |
| 51 | Carlo Westphal | Gerolsteiner | + 31 | + 31 |
| 52 | Luengo Celaya Anton | Euskaltel-Euskadi | + 41 | + 41 |
| 53 | Josu Mondelo Diaz | Spiuk - Extremadura | + 41 | + 41 |
| 54 | Gerben Löwik | Rabobank | + 44 | + 44 |
| 55 | Antonio Flecha Juan | Rabobank | + 44 | + 44 |
| 56 | Thomas Dekker | Rabobank | + 44 | + 44 |
| 57 | Stijn Devolder | Discovery Channel | + 50 | + 50 |
| 58 | Gorka Amuriza Gumucio | Grupo Nicolas Mateos | + 52 | + 52 |
| 59 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 54 | + 54 |
| 60 | Joaquin Rojas José | Caisse d'Epargne | + 54 | + 54 |
| 61 | Thomas Frei | Astana | + 57 | + 57 |
| 62 | Juan Olmo | Andalucia - Cajasur | + 57 | + 57 |
| 63 | Tom Stamsnijder | Gerolsteiner | + 57 | + 57 |
| 64 | David Belda | Fuerteventura - Canarias | + 57 | + 57 |
| 65 | Luis Pérez Rodríguez | Andalucia - Cajasur | + 57 | + 57 |
| 66 | Matthias Russ | Gerolsteiner | + 57 | + 57 |
| 67 | Jose Herrada | Vina Magna - Cropu | + 57 | + 57 |
| 68 | David de La Fuente | Saunier Duval - Prodir | + 57 | + 57 |
| 69 | Santiago Pérez | Relax - GAM | + 57 | + 57 |
| 70 | Javier Etxarri | Grupo Nicolas Mateos | + 57 | + 57 |
| 71 | Aaron Villegas Trapaga | Orbea - Laukiz F.T. | + 57 | + 57 |
| 72 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 57 | + 57 |
| 73 | Antonio Redondo Jose | Astana | + 57 | + 57 |
| 74 | Pavel Padrnos | Discovery Channel | + 57 | + 57 |
| 75 | Alberto Martinez José | Agritubel | + 57 | + 57 |
| 76 | Enrique Salgueiro | Karpin-Galicia | + 57 | + 57 |
| 77 | Enrico Poitschke | Team Milram | + 57 | + 57 |
| 78 | Johannes Fröhlinger | Gerolsteiner | + 57 | + 57 |
| 79 | Antonio Olmo | Andalucia - Cajasur | + 57 | + 57 |
| 80 | Koos Moerenhout | Rabobank | + 57 | + 57 |
| 81 | David Bernabeu | Fuerteventura - Canarias | + 57 | + 57 |
| 82 | Igor Abakoumov | Astana | + 57 | + 57 |
| 83 | Filippo Pozzato | Liquigas | + 57 | + 57 |
| 84 | Davide Vigano | Quick Step - Innergetic | + 57 | + 57 |
| 85 | Gaizka Lasa Larraya | Karpin-Galicia | + 57 | + 57 |
| 86 | Julen Zubero Aldekoa | Orbea - Laukiz F.T. | + 57 | + 57 |
| 87 | Isidro Nozal Vega | Karpin-Galicia | + 57 | + 57 |
| 88 | Ángel Gómez | Saunier Duval - Prodir | + 57 | + 57 |
| 89 | Steve Cummings | Discovery Channel | + 57 | + 57 |
| 90 | Iban Iriondo Uranga | Euskaltel-Euskadi | + 01:15 | + 01:15 |
| 91 | Giuseppe Guerini | T-Mobile Team | + 01:20 | + 01:20 |
| 92 | Christian Knees | Team Milram | + 01:23 | + 01:23 |
| 93 | Iván Melero | Orbea - Laukiz F.T. | + 01:35 | + 01:35 |
| 94 | Joseba Zubeldia | Euskaltel-Euskadi | + 03:13 | + 03:13 |
| 95 | Manuel Calvente | Agritubel | + 04:58 | + 04:58 |
| 96 | Francisco Mancebo | Relax - GAM | + 04:58 | + 04:58 |
| 97 | Michael Albasini | Liquigas | + 04:58 | + 04:58 |
| 98 | Tomas Vaitkus | Discovery Channel | + 04:58 | + 04:58 |
| 99 | Patrik Sinkewitz | T-Mobile Team | + 05:02 | + 05:02 |
| 100 | Unai Uribarri | Euskaltel-Euskadi | + 05:47 | + 05:47 |
| 101 | Moisés Dueñas | Agritubel | + 05:47 | + 05:47 |
| 102 | Sebastian Lang | Gerolsteiner | + 08:23 | + 08:23 |
| 103 | Maxim Iglinskiy | Astana | + 08:23 | + 08:23 |
| 104 | Jose Ruiz Sanchez | Andalucia - Cajasur | + 09:47 | + 09:47 |
| 105 | Pablo Lastras | Caisse d'Epargne | + 11:35 | + 11:35 |
| 106 | Joan Horrach | Caisse d'Epargne | + 11:35 | + 11:35 |
| 107 | David Abal Diego | Karpin-Galicia | + 12:03 | + 12:03 |
| 108 | Gonzalo Rabuñal | Karpin-Galicia | + 12:03 | + 12:03 |
| 109 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 12:03 | + 12:03 |
| 110 | José Casas Claudio | Andalucia - Cajasur | + 12:03 | + 12:03 |
| 111 | Björn Schröder | Team Milram | + 12:03 | + 12:03 |
| 112 | Eloy Teruel | Grupo Nicolas Mateos | + 12:03 | + 12:03 |
| 113 | Matej Jurco | Team Milram | + 12:03 | + 12:03 |
| 114 | Servais Knaven | T-Mobile Team | + 12:03 | + 12:03 |
| 115 | Sergei Ivanov | Astana | + 12:03 | + 12:03 |
| 116 | Sebastien Siedler | Team Milram | + 12:03 | + 12:03 |
| 117 | Axetza Pena Iza | Euskaltel-Euskadi | + 12:03 | + 12:03 |
| 118 | Inigo Lazkano Iriondo | Orbea - Laukiz F.T. | + 12:03 | + 12:03 |
| 119 | Benoit Joachim | Astana | + 12:03 | + 12:03 |
| 120 | Miguel Ochoa Gonzalez | Grupo Nicolas Mateos | + 12:03 | + 12:03 |
| 121 | Carlos Torrent | Vina Magna - Cropu | + 12:03 | + 12:03 |
| 122 | Guillermo Ferrer Garcia | + 12:03 | + 12:03 | |
| 123 | Jesus Tendero Marcos | Vina Magna - Cropu | + 12:03 | + 12:03 |
| 124 | Antonio Lopez Gil Jose | Andalucia - Cajasur | + 12:10 | + 12:10 |
| 125 | Iker Mezo Askargorta | Orbea - Laukiz F.T. | + 12:10 | + 12:10 |
| 126 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 12:10 | + 12:10 |
| 127 | José Oroz Juan | Orbea - Laukiz F.T. | + 12:10 | + 12:10 |
| 128 | Guido Trenti | Liquigas | + 12:10 | + 12:10 |
| 129 | Bernhard Eisel | T-Mobile Team | + 12:10 | + 12:10 |
| 130 | Scott Davis | T-Mobile Team | + 12:10 | + 12:10 |
| 131 | William Walker | Rabobank | + 12:10 | + 12:10 |
| 132 | Angel Vallejo Dominquez | Relax - GAM | + 12:10 | + 12:10 |
| 133 | Manuel Diaz Armas Dailos | Fuerteventura - Canarias | + 12:10 | + 12:10 |
| 134 | Jesus Del Nero Montes | Saunier Duval - Prodir | + 12:10 | + 12:10 |
| 135 | Javier Moreno | Spiuk - Extremadura | + 12:10 | + 12:10 |
| 136 | Oscar Garcia-casarrubios | Relax - GAM | + 12:16 | + 12:16 |
| 137 | Jorge García Marín | Relax - GAM | + 12:16 | + 12:16 |
| 138 | Roberto Alvarez Martin Luis | Vina Magna - Cropu | + 12:16 | + 12:16 |
| 139 | Carlos Carinena Luque Juan | Andalucia - Cajasur | + 12:16 | + 12:16 |
| 140 | David Martin Peribanez | Vina Magna - Cropu | + 12:19 | + 12:19 |
| 141 | Julian Sanchez | Relax - GAM | + 12:19 | + 12:19 |
| 142 | Antonio Piedra | Fuerteventura - Canarias | + 12:22 | + 12:22 |
| 143 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 18:56 | + 18:56 |
| 144 | Manuel Vazquez | Andalucia - Cajasur | + 18:56 | + 18:56 |
| 145 | Manuel Ortega | Andalucia - Cajasur | + 18:56 | + 18:56 |
| 146 | José Martínez Francisco | Andalucia - Cajasur | + 18:56 | + 18:56 |
| 147 | Jesus Rosendo Prado | Andalucia - Cajasur | + 18:56 | + 18:56 |
| 148 | Igor Romero Etxebarria | Orbea - Laukiz F.T. | + 23:29 | + 23:29 |
| 149 | Javier Aramendia | Orbea - Laukiz F.T. | + 23:29 | + 23:29 |
| 150 | Egoitz Murgoitio Rekalde | Grupo Nicolas Mateos | + 23:29 | + 23:29 |
| 151 | Ivan Gilmartin | Vina Magna - Cropu | + 23:29 | + 23:29 |
| 152 | Carlos Castaño | Karpin-Galicia | + 23:29 | + 23:29 |
| 153 | Raul Alarcon | Saunier Duval - Prodir | + 23:29 | + 23:29 |
| 154 | José Lara Francisco | Andalucia - Cajasur | + 25:45 | + 25:45 |
| 155 | Luis Perez Romero | Andalucia - Cajasur | + 25:45 | + 25:45 |
| 156 | Antonio Banos Ballester Jose | Grupo Nicolas Mateos | + 25:45 | + 25:45 |
| 157 | Diego Milan | Grupo Nicolas Mateos | + 25:45 | + 25:45 |
| 158 | Alan Perez Lezaun | Euskaltel-Euskadi | + 25:45 | + 25:45 |
| 159 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 25:45 | + 25:45 |