| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | David Etxebarria | Liberty Seguros - Würth Team | 04:10:24 | |
| 2 | Damiano Cunego | Lampre-Caffita | + 00 | |
| 3 | Aitor Osa | Illes Balears - Caisse d'Epargne | + 00 | |
| 4 | Joaquim Rodríguez | Saunier Duval - Prodir | + 00 | |
| 5 | Rubén Plaza | Comunidad Valenciana | + 00 | |
| 6 | Pedro Arreitunandia | Team Barloworld - Valsir | + 00 | |
| 7 | Alberto Contador | Liberty Seguros - Würth Team | + 00 | |
| 8 | Jorge Ferrio Luque | Spiuk | + 14 | + 14 |
| 9 | Paolo Savoldelli | Discovery Channel | + 27 | + 27 |
| 10 | David Blanco | Comunidad Valenciana | + 29 | + 29 |
| 11 | David López | Euskaltel-Euskadi | + 39 | + 39 |
| 12 | Ricardo Serrano | Kaiku | + 39 | + 39 |
| 13 | Angel Vicioso | Liberty Seguros - Würth Team | + 50 | + 50 |
| 14 | Constantino Zaballa | Saunier Duval - Prodir | + 01:24 | + 01:24 |
| 15 | Patxi Vila | Lampre-Caffita | + 01:24 | + 01:24 |
| 16 | Félix Cárdenas | Team Barloworld - Valsir | + 01:24 | + 01:24 |
| 17 | Iker Camaño | Euskaltel-Euskadi | + 01:24 | + 01:24 |
| 18 | Iban Mayo | Euskaltel-Euskadi | + 01:24 | + 01:24 |
| 19 | Eladio Jiménez | Comunidad Valenciana | + 01:24 | + 01:24 |
| 20 | Roberto Heras | Liberty Seguros - Würth Team | + 01:24 | + 01:24 |
| 21 | Igor Astarloa | Team Barloworld - Valsir | + 01:24 | + 01:24 |
| 22 | Luis Rubiera José | Discovery Channel | + 01:24 | + 01:24 |
| 23 | Ion Del Rio | Andalucia - Paul Versan | + 02:44 | + 02:44 |
| 24 | Daniel Navarro | Liberty Seguros - Würth Team | + 03:41 | + 03:41 |
| 25 | Carlos Dominguez Juan | Saunier Duval - Prodir | + 05:51 | + 05:51 |
| 26 | Nacor Burgos | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 27 | Pavel Brutt | Lokomotiv | + 06:44 | + 06:44 |
| 28 | Luis Pasamontes | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 29 | Vladimir Efimkin | Team Barloworld - Valsir | + 06:44 | + 06:44 |
| 30 | Alberto Benitez Jose | Spiuk | + 06:44 | + 06:44 |
| 31 | Miguel Galindo Jose | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 32 | Ruben Oarbeascoa Ispizua | Kaiku | + 06:44 | + 06:44 |
| 33 | Raul Garcia de Mateos | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 34 | David Fernandez | Andalucia - Paul Versan | + 06:44 | + 06:44 |
| 35 | Alan Perez Lezaun | Orbea | + 06:44 | + 06:44 |
| 36 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 06:44 | + 06:44 |
| 37 | Manuel Beltrán | Discovery Channel | + 06:44 | + 06:44 |
| 38 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 39 | David Canada | Saunier Duval - Prodir | + 06:44 | + 06:44 |
| 40 | Gorazd Stangelj | Lampre-Caffita | + 06:44 | + 06:44 |
| 41 | Manuel Calvente | Team CSC | + 06:44 | + 06:44 |
| 42 | Aaron Villegas Trapaga | Orbea | + 06:44 | + 06:44 |
| 43 | Iban Mayoz | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 44 | Javier Ramirez Torres Jesus | Spiuk | + 06:44 | + 06:44 |
| 45 | Gorka Gonzalez | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 46 | Gustavo Dominguez Lemos | Orbea | + 06:44 | + 06:44 |
| 47 | Unai Osa | Illes Balears - Caisse d'Epargne | + 06:44 | + 06:44 |
| 48 | Asle Arvesen Kurt | Team CSC | + 06:44 | + 06:44 |
| 49 | José Azevedo | Discovery Channel | + 06:44 | + 06:44 |
| 50 | Efrain Gutierrez Sanchez | Andalucia - Paul Versan | + 06:44 | + 06:44 |
| 51 | Javier Pascual Llorente | Comunidad Valenciana | + 06:44 | + 06:44 |
| 52 | Volodymir Gustov | Fassa Bortolo | + 06:44 | + 06:44 |
| 53 | David Navas Chica | Illes Balears - Caisse d'Epargne | + 06:44 | + 06:44 |
| 54 | Pavel Padrnos | Discovery Channel | + 06:44 | + 06:44 |
| 55 | Josu Silloniz Aresti | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 56 | Benjamin Noval | Discovery Channel | + 06:44 | + 06:44 |
| 57 | Carlos Torrent | Catalunya - Angel Mir | + 06:44 | + 06:44 |
| 58 | Xavier Tondó | Catalunya - Angel Mir | + 06:44 | + 06:44 |
| 59 | Igor Anton | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 60 | Brian Vandborg | Team CSC | + 06:44 | + 06:44 |
| 61 | Jens Voigt | Team CSC | + 06:44 | + 06:44 |
| 62 | Antonio Tauler Llull | Illes Balears - Caisse d'Epargne | + 06:44 | + 06:44 |
| 63 | Carlos Castaño | Andalucia - Paul Versan | + 06:44 | + 06:44 |
| 64 | Francisco Cabello | Comunidad Valenciana | + 06:44 | + 06:44 |
| 65 | Marius Sabaliauskas | Lampre-Caffita | + 06:44 | + 06:44 |
| 66 | Xavier Florencio | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 67 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 68 | Luis Carrasco Gamiz José | Illes Balears - Caisse d'Epargne | + 06:44 | + 06:44 |
| 69 | Antonio Pastor Roldan Juan | Andalucia - Paul Versan | + 06:44 | + 06:44 |
| 70 | Roberto Laiseka | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 71 | Manuel Diaz Armas Dailos | Orbea | + 06:44 | + 06:44 |
| 72 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 06:44 | + 06:44 |
| 73 | Sergio Dominguez | Spiuk | + 06:44 | + 06:44 |
| 74 | Kanstantsin Sivtsov | Fassa Bortolo | + 06:44 | + 06:44 |
| 75 | Javier Benitez | Relax - Fuenlabarda | + 06:44 | + 06:44 |
| 76 | Ezequiel Mosquera | Kaiku | + 06:44 | + 06:44 |
| 77 | Julian Sanchez | Fassa Bortolo | + 06:44 | + 06:44 |
| 78 | Francisco Mancebo | Illes Balears - Caisse d'Epargne | + 06:44 | + 06:44 |
| 79 | Ruben Lobato | Saunier Duval - Prodir | + 06:44 | + 06:44 |
| 80 | Massimo Giunti | Fassa Bortolo | + 06:44 | + 06:44 |
| 81 | Sylwester Szmyd | Lampre-Caffita | + 06:44 | + 06:44 |
| 82 | Kim Kirchen | Fassa Bortolo | + 06:44 | + 06:44 |
| 83 | Giampaolo Cheula | Team Barloworld - Valsir | + 06:44 | + 06:44 |
| 84 | Serguei Klimov | Lokomotiv | + 11:33 | + 11:33 |
| 85 | Enrique Salgueiro | Spiuk | + 11:33 | + 11:33 |