| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Samuel Sánchez | Euskaltel-Euskadi | 04:04:19 | |
| 2 | Igor Anton | Euskaltel-Euskadi | + 05 | + 05 |
| 3 | Fränk Schleck | Team Saxo Bank | + 05 | + 05 |
| 4 | David Bernabeu | Barbot - Siper | + 05 | + 05 |
| 5 | Javier Moreno | Andalucía - Cajasur | + 05 | + 05 |
| 6 | Mauro Finetto | Liquigas-Doimo | + 05 | + 05 |
| 7 | Rigoberto Uran | Caisse d'Epargne | + 05 | + 05 |
| 8 | Sergey Chernetskiy | + 05 | + 05 | |
| 9 | Egoi Martinez | Euskaltel-Euskadi | + 05 | + 05 |
| 10 | Jose Herrada | Caja Rural | + 05 | + 05 |
| 11 | Raul Santamarta Valvuena | Burgos 2016 - Castilla y Leon | + 05 | + 05 |
| 12 | David Gutierrez G. | Footon-Servetto | + 05 | + 05 |
| 13 | Arnold Jeannesson | Caisse d'Epargne | + 05 | + 05 |
| 14 | Evgeni Petrov | Team Katusha | + 08 | + 08 |
| 15 | Fabricio Ferrari | Caja Rural | + 08 | + 08 |
| 16 | David Arroyo | Caisse d'Epargne | + 08 | + 08 |
| 17 | Jose Mendes | LA - Rota dos Moveis | + 08 | + 08 |
| 18 | Gregory Brenes | Burgos 2016 - Castilla y Leon | + 08 | + 08 |
| 19 | Axetza Pena Iza | Caja Rural | + 08 | + 08 |
| 20 | Benat Intxausti | Euskaltel-Euskadi | + 08 | + 08 |
| 21 | David López | Caisse d'Epargne | + 08 | + 08 |
| 22 | Mauricio Soler | Caisse d'Epargne | + 08 | + 08 |
| 23 | Pedro Merino Criado | Footon-Servetto | + 08 | + 08 |
| 24 | Ezequiel Mosquera | Xacobeo-Galicia | + 08 | + 08 |
| 25 | Eros Capecchi | Footon-Servetto | + 13 | + 13 |
| 26 | Ivan Santaromita | Liquigas-Doimo | + 27 | + 27 |
| 27 | Nicki Sørensen | Team Saxo Bank | + 01:11 | + 01:11 |
| 28 | Sergey Shilov | + 01:11 | + 01:11 | |
| 29 | David García Dapena | Xacobeo-Galicia | + 01:11 | + 01:11 |
| 30 | Eduard Vorganov | Team Katusha | + 01:11 | + 01:11 |
| 31 | Avelino Antuna Coro Andres | Burgos 2016 - Castilla y Leon | + 01:11 | + 01:11 |
| 32 | André Cardoso | Palmeiras Resort - Prio | + 01:11 | + 01:11 |
| 33 | Andoni Blazquez Berasarte | Orbea | + 01:11 | + 01:11 |
| 34 | Cesar Fonte | Barbot - Siper | + 01:11 | + 01:11 |
| 35 | Marco Corti | Footon-Servetto | + 01:11 | + 01:11 |
| 36 | Mikel Landa | Orbea | + 01:11 | + 01:11 |
| 37 | Richie Porte | Team Saxo Bank | + 01:11 | + 01:11 |
| 38 | Alberto Morras Fernandez | Madeinox - Boavista | + 01:11 | + 01:11 |
| 39 | Gustavo Veloso | Xacobeo-Galicia | + 01:11 | + 01:11 |
| 40 | Ricardo Mestre | Palmeiras Resort - Prio | + 01:11 | + 01:11 |
| 41 | David Livramento | Palmeiras Resort - Prio | + 01:11 | + 01:11 |
| 42 | Silva Pires Bruno | Barbot - Siper | + 01:11 | + 01:11 |
| 43 | José Gomez | Andalucía - Cajasur | + 01:11 | + 01:11 |
| 44 | Alberto Losada | Caisse d'Epargne | + 01:11 | + 01:11 |
| 45 | Marcos Garcia | Xacobeo-Galicia | + 01:11 | + 01:11 |
| 46 | Alexandre Botcharov | Team Katusha | + 01:11 | + 01:11 |
| 47 | Sergio Sousa | Madeinox - Boavista | + 01:11 | + 01:11 |
| 48 | José Oroz Juan | Euskaltel-Euskadi | + 01:11 | + 01:11 |
| 49 | Iván Melero | Burgos 2016 - Castilla y Leon | + 01:11 | + 01:11 |
| 50 | Rubén Plaza | Caisse d'Epargne | + 01:11 | + 01:11 |
| 51 | Jens Voigt | Team Saxo Bank | + 01:11 | + 01:11 |
| 52 | Laurent Didier | Team Saxo Bank | + 01:11 | + 01:11 |
| 53 | Victor Rodrigues | Caja Rural | + 01:11 | + 01:11 |
| 54 | Sergio Ribeiro | Barbot - Siper | + 01:11 | + 01:11 |
| 55 | Francesco Bellotti | Liquigas-Doimo | + 01:11 | + 01:11 |
| 56 | Ricardo Vilela | Madeinox - Boavista | + 01:11 | + 01:11 |
| 57 | Xabier Zabalo Imaz | Orbea | + 02:18 | + 02:18 |
| 58 | Garikoitz Bravo | Caja Rural | + 02:18 | + 02:18 |
| 59 | Delio Fernandez | Xacobeo-Galicia | + 02:18 | + 02:18 |
| 60 | Iban Mayoz | Footon-Servetto | + 02:21 | + 02:21 |
| 61 | Ricardo Garcia | Orbea | + 02:26 | + 02:26 |
| 62 | Ion Izagirre | Orbea | + 02:26 | + 02:26 |
| 63 | Luis Silva | Palmeiras Resort - Prio | + 02:26 | + 02:26 |
| 64 | Michal Kwiatkowski | Caja Rural | + 02:26 | + 02:26 |
| 65 | Arturo Mora Ortiz | Caja Rural | + 02:26 | + 02:26 |
| 66 | Celio Sousa | Madeinox - Boavista | + 02:26 | + 02:26 |
| 67 | Luis Pinheiro | Madeinox - Boavista | + 02:26 | + 02:26 |
| 68 | Egoitz Garcia | Caja Rural | + 02:26 | + 02:26 |
| 69 | Higinio Fernandez | Caja Rural | + 02:26 | + 02:26 |
| 70 | Gonzalo Rabuñal | Xacobeo-Galicia | + 02:26 | + 02:26 |
| 71 | Diego Gallego | Burgos 2016 - Castilla y Leon | + 02:26 | + 02:26 |
| 72 | Vergilio Santos | LA - Rota dos Moveis | + 02:26 | + 02:26 |
| 73 | Ruben Reig Conejero | Caja Rural | + 02:26 | + 02:26 |
| 74 | Edgar Pinto | LA - Rota dos Moveis | + 02:26 | + 02:26 |
| 75 | Luca Mazzanti | Team Katusha | + 02:26 | + 02:26 |
| 76 | Filipe Cardoso | LA - Rota dos Moveis | + 04:42 | + 04:42 |
| 77 | Ivan Velasco | Euskaltel-Euskadi | + 04:50 | + 04:50 |
| 78 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 04:50 | + 04:50 |
| 79 | Rui Sousa | Barbot - Siper | + 04:50 | + 04:50 |
| 80 | Swift Metcalfe Tomas | Palmeiras Resort - Prio | + 04:50 | + 04:50 |
| 81 | Benat Urain Epelde | Orbea | + 04:50 | + 04:50 |
| 82 | Mario Costa | Barbot - Siper | + 04:50 | + 04:50 |
| 83 | Andrey Amador | Caisse d'Epargne | + 04:50 | + 04:50 |
| 84 | Jorge Azanza | Euskaltel-Euskadi | + 04:50 | + 04:50 |
| 85 | Manuel Anton Francisco | Burgos 2016 - Castilla y Leon | + 04:50 | + 04:50 |
| 86 | Angel Candil Delgado Miguel | LA - Rota dos Moveis | + 04:50 | + 04:50 |
| 87 | Valery Kaykov | + 04:50 | + 04:50 | |
| 88 | Pascual Orengo Lopez | Burgos 2016 - Castilla y Leon | + 04:50 | + 04:50 |
| 89 | David Francisco Delgado | Burgos 2016 - Castilla y Leon | + 04:50 | + 04:50 |
| 90 | Javier Ramirez | Andalucía - Cajasur | + 04:50 | + 04:50 |
| 91 | Serafín Martinez | Xacobeo-Galicia | + 04:50 | + 04:50 |
| 92 | Daniel Mestre | Palmeiras Resort - Prio | + 04:50 | + 04:50 |
| 93 | Serguei Klimov | Team Katusha | + 04:50 | + 04:50 |
| 94 | Manuel Vazquez | Andalucía - Cajasur | + 04:50 | + 04:50 |
| 95 | Alessandro Vanotti | Liquigas-Doimo | + 06:56 | + 06:56 |
| 96 | Mikel Ilundain Tirapu | Orbea | + 06:56 | + 06:56 |
| 97 | Oliver Zaugg | Liquigas-Doimo | + 06:56 | + 06:56 |
| 98 | André Steensen | Team Saxo Bank | + 06:56 | + 06:56 |
| 99 | Lluis Mas | Burgos 2016 - Castilla y Leon | + 06:56 | + 06:56 |
| 100 | Aaen Jørgensen Jonas | Team Saxo Bank | + 06:56 | + 06:56 |
| 101 | Brian Vandborg | Liquigas-Doimo | + 06:56 | + 06:56 |
| 102 | Adrian Saez | Orbea | + 06:56 | + 06:56 |
| 103 | Artur Ershov | + 06:56 | + 06:56 |