| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Carlos Sastre | Team CSC | 04:00:57 | |
| 2 | Damiano Cunego | Lampre-Fondital | + 00 | |
| 3 | Joaquim Rodríguez | Caisse d'Epargne - Illes Balears | + 00 | |
| 4 | Alberto Contador | Astana - Würth Team | + 00 | |
| 5 | David Arroyo | Caisse d'Epargne - Illes Balears | + 12 | + 12 |
| 6 | Ruggero Marzoli | + 23 | + 23 | |
| 7 | Jaume Rovira | Andalucia - Paul Versan | + 23 | + 23 |
| 8 | Francisco Pérez | Caisse d'Epargne - Illes Balears | + 23 | + 23 |
| 9 | David Etxebarria | Astana - Würth Team | + 23 | + 23 |
| 10 | José Gomez | Saunier Duval - Prodir | + 26 | + 26 |
| 11 | David López | Euskaltel-Euskadi | + 27 | + 27 |
| 12 | Javier Rodriguez | Comunidad Valenciana | + 29 | + 29 |
| 13 | David Muñoz | Comunidad Valenciana | + 29 | + 29 |
| 14 | Benat Albizuri Aransono | Euskaltel-Euskadi | + 29 | + 29 |
| 15 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 29 | + 29 |
| 16 | Manuele Mori | Saunier Duval - Prodir | + 29 | + 29 |
| 17 | Nicki Sørensen | Team CSC | + 29 | + 29 |
| 18 | Adrian Palomares | Kaiku | + 29 | + 29 |
| 19 | Gorka Verdugo | Euskaltel-Euskadi | + 29 | + 29 |
| 20 | Unai Osa | Astana - Würth Team | + 29 | + 29 |
| 21 | Luis Carrasco Gamiz José | Caisse d'Epargne - Illes Balears | + 29 | + 29 |
| 22 | Alberto Rodriguez | Massi | + 29 | + 29 |
| 23 | Josu Mondelo Diaz | Spiuk - Extremadura | + 29 | + 29 |
| 24 | Iker Camaño | Euskaltel-Euskadi | + 29 | + 29 |
| 25 | Evgeni Petrov | Lampre-Fondital | + 29 | + 29 |
| 26 | Daniel Moreno | Relax - GAM | + 29 | + 29 |
| 27 | Igor Anton | Euskaltel-Euskadi | + 29 | + 29 |
| 28 | Arkaitz Durán | Saunier Duval - Prodir | + 29 | + 29 |
| 29 | Joan Horrach | Caisse d'Epargne - Illes Balears | + 29 | + 29 |
| 30 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 29 | + 29 |
| 31 | Peter Luttenberger | Team CSC | + 29 | + 29 |
| 32 | Daniel Navarro | Astana - Würth Team | + 29 | + 29 |
| 33 | Ezequiel Mosquera | Comunidad Valenciana | + 29 | + 29 |
| 34 | Xabier Zandio | Caisse d'Epargne - Illes Balears | + 29 | + 29 |
| 35 | Marco Fertonani | Caisse d'Epargne - Illes Balears | + 48 | + 48 |
| 36 | Vicente Peiro Marqueno | Comunidad Valenciana | + 48 | + 48 |
| 37 | Ivan Velasco | Orbea | + 01:08 | + 01:08 |
| 38 | Manuel Vazquez | Andalucia - Paul Versan | + 01:08 | + 01:08 |
| 39 | Manuel Lloret | Comunidad Valenciana | + 01:08 | + 01:08 |
| 40 | Manuel Diaz Armas Dailos | Orbea | + 01:08 | + 01:08 |
| 41 | David Latasa Lasa | Comunidad Valenciana | + 01:08 | + 01:08 |
| 42 | Jesús Hernández | Relax - GAM | + 01:08 | + 01:08 |
| 43 | Jorge García Marín | Relax - GAM | + 01:31 | + 01:31 |
| 44 | Aaron Villegas Trapaga | Orbea | + 01:31 | + 01:31 |
| 45 | Mario Sanchez Fernandez | Andalucia - Paul Versan | + 01:31 | + 01:31 |
| 46 | Gorka Amuriza Gumucio | Orbea | + 01:31 | + 01:31 |
| 47 | Carlos Lopez Marin Juan | Grupo Nicolas Mateos | + 01:31 | + 01:31 |
| 48 | Raul Garcia de Mateos | Relax - GAM | + 01:31 | + 01:31 |
| 49 | Pedro Romero Ocampo | Spiuk - Extremadura | + 01:31 | + 01:31 |
| 50 | Jordi Berenguer Ferrer | Massi | + 01:33 | + 01:33 |
| 51 | Angel Rodriguez Garcia | Spiuk - Extremadura | + 01:33 | + 01:33 |
| 52 | Patxi Vila | Lampre-Fondital | + 01:33 | + 01:33 |
| 53 | Iván Melero | Orbea | + 01:56 | + 01:56 |
| 54 | Enrique Salgueiro | Spiuk - Extremadura | + 02:02 | + 02:02 |
| 55 | Ricardo Serrano | Kaiku | + 02:31 | + 02:31 |
| 56 | Oleg Chuzhda | Comunidad Valenciana | + 02:51 | + 02:51 |
| 57 | Luis Maldonado Cano | Massi | + 02:51 | + 02:51 |
| 58 | Rafael Casero Moreno | 3 Molinos Resort | + 02:51 | + 02:51 |
| 59 | Luis Marichalar Pedro | Andalucia - Paul Versan | + 02:51 | + 02:51 |
| 60 | Joseba Zumeta Etxabe | Orbea | + 02:51 | + 02:51 |
| 61 | Martin Mata Cabello | Grupo Nicolas Mateos | + 02:51 | + 02:51 |
| 62 | Manuel Ortega | Andalucia - Paul Versan | + 02:51 | + 02:51 |
| 63 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 02:51 | + 02:51 |
| 64 | Javier Moreno | Grupo Nicolas Mateos | + 02:51 | + 02:51 |
| 65 | Miguel Galindo Jose | Relax - GAM | + 02:51 | + 02:51 |
| 66 | José Casas Claudio | Comunidad Valenciana | + 02:51 | + 02:51 |
| 67 | Antonio Redondo Jose | Astana - Würth Team | + 02:51 | + 02:51 |
| 68 | Jorge Ferrio Luque | 3 Molinos Resort | + 02:51 | + 02:51 |
| 69 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 02:51 | + 02:51 |
| 70 | Isidro Cerrato Lopez | 3 Molinos Resort | + 02:51 | + 02:51 |
| 71 | Jens Voigt | Team CSC | + 03:47 | + 03:47 |
| 72 | Michael Blaudzun | Team CSC | + 03:47 | + 03:47 |
| 73 | Fränk Schleck | Team CSC | + 03:47 | + 03:47 |
| 74 | Antonio Arroyo Ramirez Jose | Spiuk - Extremadura | + 04:47 | + 04:47 |
| 75 | Isidro Nozal Vega | Astana - Würth Team | + 05:18 | + 05:18 |
| 76 | Ruben Lobato | Saunier Duval - Prodir | + 06:13 | + 06:13 |
| 77 | Alberto Fernandez | Saunier Duval - Prodir | + 06:13 | + 06:13 |
| 78 | Haimar Zubeldia | Euskaltel-Euskadi | + 06:13 | + 06:13 |
| 79 | Roberto Laiseka | Euskaltel-Euskadi | + 06:17 | + 06:17 |
| 80 | Óscar Pereiro | Caisse d'Epargne - Illes Balears | + 06:17 | + 06:17 |
| 81 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 06:17 | + 06:17 |
| 82 | Diego Milan | Grupo Nicolas Mateos | + 06:17 | + 06:17 |
| 83 | Gustavo Veloso | Kaiku | + 06:17 | + 06:17 |
| 84 | Mikel Pradera | Caisse d'Epargne - Illes Balears | + 06:17 | + 06:17 |
| 85 | Carlos Fernandez Mora Juan | Grupo Nicolas Mateos | + 06:17 | + 06:17 |
| 86 | Iker Leonet Iza | Caisse d'Epargne - Illes Balears | + 06:17 | + 06:17 |
| 87 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 06:17 | + 06:17 |
| 88 | Luengo Celaya Anton | Euskaltel-Euskadi | + 06:17 | + 06:17 |
| 89 | Rafael Macarron | Spiuk - Extremadura | + 06:17 | + 06:17 |
| 90 | Marco Marzano | Lampre-Fondital | + 06:17 | + 06:17 |
| 91 | Victor Hernandez Beltran | + 06:17 | + 06:17 | |
| 92 | Xavier Tondó | Relax - GAM | + 06:17 | + 06:17 |
| 93 | Alexis Rodriguez | 3 Molinos Resort | + 06:17 | + 06:17 |
| 94 | Sergio Paulinho | Astana - Würth Team | + 06:17 | + 06:17 |
| 95 | Alberto Benitez Jose | Saunier Duval - Prodir | + 06:17 | + 06:17 |
| 96 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 06:17 | + 06:17 |
| 97 | Josu Agirre Asegniloaza | Orbea | + 06:17 | + 06:17 |
| 98 | Pedro Martinez Romera | 3 Molinos Resort | + 06:17 | + 06:17 |
| 99 | Francisco Cabello | Andalucia - Paul Versan | + 06:17 | + 06:17 |
| 100 | Fernando Cepeda Wilson | Massi | + 06:17 | + 06:17 |
| 101 | Antonio Pecharroman Jose | Comunidad Valenciana | + 06:17 | + 06:17 |
| 102 | Javier Ruiz de Larrinaga | Kaiku | + 06:17 | + 06:17 |
| 103 | Antonio Olmo | Comunidad Valenciana | + 06:17 | + 06:17 |
| 104 | José Cobo Juan | Saunier Duval - Prodir | + 06:17 | + 06:17 |
| 105 | Ruben Lorca Jimenez | 3 Molinos Resort | + 11:50 | + 11:50 |
| 106 | Denis Kudashev | Relax - GAM | + 11:50 | + 11:50 |