| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Joaquim Rodríguez | Caisse d'Epargne | 03:55:59 | |
| 2 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 3 | Matteo Bono | Lampre-Fondital | + 08 | + 08 |
| 4 | David López | Caisse d'Epargne | + 08 | + 08 |
| 5 | Francisco Mancebo | Relax - GAM | + 08 | + 08 |
| 6 | Constantino Zaballa | Caisse d'Epargne | + 08 | + 08 |
| 7 | Bobby Julich | Team CSC | + 08 | + 08 |
| 8 | Igor Anton | Euskaltel-Euskadi | + 08 | + 08 |
| 9 | David de La Fuente | Saunier Duval - Prodir | + 08 | + 08 |
| 10 | Angel Vicioso | Relax - GAM | + 08 | + 08 |
| 11 | Fränk Schleck | Team CSC | + 08 | + 08 |
| 12 | Iker Camaño | Saunier Duval - Prodir | + 08 | + 08 |
| 13 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 42 | + 42 |
| 14 | Pablo Lastras | Caisse d'Epargne | + 42 | + 42 |
| 15 | Aitor Galdos | Euskaltel-Euskadi | + 01:18 | + 01:18 |
| 16 | Manuel Ortega | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 17 | Nicki Sørensen | Team CSC | + 01:22 | + 01:22 |
| 18 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 01:22 | + 01:22 |
| 19 | Manuel Gomes Colinas Victor | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 20 | Aitor Hernández | Euskaltel-Euskadi | + 01:22 | + 01:22 |
| 21 | Javier Moreno | Spiuk - Extremadura | + 01:22 | + 01:22 |
| 22 | Jorge Ferrio Luque | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 23 | Mikel Astarloza | Euskaltel-Euskadi | + 01:22 | + 01:22 |
| 24 | Ivan Gilmartin | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 25 | Unai Etxebarria Arana | Euskaltel-Euskadi | + 01:22 | + 01:22 |
| 26 | Alberto Rodriguez | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 27 | Alexandr Kolobnev | Team CSC | + 01:22 | + 01:22 |
| 28 | Alberto Benitez Jose | Saunier Duval - Prodir | + 01:22 | + 01:22 |
| 29 | Julian Sanchez | Relax - GAM | + 01:22 | + 01:22 |
| 30 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 01:22 | + 01:22 |
| 31 | David Martin Peribanez | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 32 | Jose Herrada | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 33 | Antonio Olmo | Andalucia - Cajasur | + 01:22 | + 01:22 |
| 34 | Manuel Diaz Armas Dailos | Fuerteventura - Canarias | + 01:22 | + 01:22 |
| 35 | Iván Melero | Orbea - Laukiz F.T. | + 01:22 | + 01:22 |
| 36 | Joseba Zumeta Etxabe | Orbea - Laukiz F.T. | + 01:22 | + 01:22 |
| 37 | Miguel Galindo Jose | Relax - GAM | + 01:22 | + 01:22 |
| 38 | Israel Pérez | Spiuk - Extremadura | + 01:22 | + 01:22 |
| 39 | Benat Intxausti | Grupo Nicolas Mateos | + 01:22 | + 01:22 |
| 40 | Diego Gallego | Vina Magna - Cropu | + 01:22 | + 01:22 |
| 41 | José Oroz Juan | Orbea - Laukiz F.T. | + 01:22 | + 01:22 |
| 42 | Anker Sørensen Chris | Team CSC | + 01:22 | + 01:22 |
| 43 | Volodymir Gustov | Team CSC | + 01:22 | + 01:22 |
| 44 | Íñigo Cuesta | Team CSC | + 01:27 | + 01:27 |
| 45 | Carlos Sastre | Team CSC | + 01:27 | + 01:27 |
| 46 | Ruben Lobato | Saunier Duval - Prodir | + 01:27 | + 01:27 |
| 47 | Paolo Tiralongo | Lampre-Fondital | + 01:27 | + 01:27 |
| 48 | José Cobo Juan | Saunier Duval - Prodir | + 01:27 | + 01:27 |
| 49 | Josu Agirre Asegniloaza | Orbea - Laukiz F.T. | + 01:32 | + 01:32 |
| 50 | Gorka Amuriza Gumucio | Grupo Nicolas Mateos | + 01:42 | + 01:42 |
| 51 | Julen Zubero Aldekoa | Orbea - Laukiz F.T. | + 01:42 | + 01:42 |
| 52 | Jon Bru | Euskaltel-Euskadi | + 01:42 | + 01:42 |
| 53 | Oscar Garcia-casarrubios | Relax - GAM | + 02:16 | + 02:16 |
| 54 | Diego Milan | Grupo Nicolas Mateos | + 02:45 | + 02:45 |
| 55 | Denis Kudashev | Relax - GAM | + 02:57 | + 02:57 |
| 56 | Javier Aramendia | Orbea - Laukiz F.T. | + 02:57 | + 02:57 |
| 57 | Egoitz Murgoitio Rekalde | Grupo Nicolas Mateos | + 03:20 | + 03:20 |
| 58 | Matej Jurco | Team Milram | + 03:45 | + 03:45 |
| 59 | Mirko Celestino | Team Milram | + 03:48 | + 03:48 |
| 60 | Santos Gonzalez | Karpin-Galicia | + 03:51 | + 03:51 |
| 61 | Josu Mondelo Diaz | Spiuk - Extremadura | + 03:51 | + 03:51 |
| 62 | Javier Etxarri | Grupo Nicolas Mateos | + 03:51 | + 03:51 |
| 63 | Vicente Ballester Martinez | Fuerteventura - Canarias | + 03:51 | + 03:51 |
| 64 | Javier Ramirez | Fuerteventura - Canarias | + 03:51 | + 03:51 |
| 65 | Juan Olmo | Andalucia - Cajasur | + 03:51 | + 03:51 |
| 66 | Luis Pérez Rodríguez | Andalucia - Cajasur | + 03:51 | + 03:51 |
| 67 | Axetza Pena Iza | Euskaltel-Euskadi | + 03:51 | + 03:51 |
| 68 | Ivan Velasco | Euskaltel-Euskadi | + 03:51 | + 03:51 |
| 69 | Vicente Peiro Marqueno | Grupo Nicolas Mateos | + 03:51 | + 03:51 |
| 70 | Lars Bak | Team CSC | + 03:51 | + 03:51 |
| 71 | Francisco Pérez | Caisse d'Epargne | + 03:51 | + 03:51 |
| 72 | Asier Fernandez Mateos | Orbea - Laukiz F.T. | + 04:36 | + 04:36 |
| 73 | Pedro Romero Ocampo | Spiuk - Extremadura | + 04:40 | + 04:40 |
| 74 | Lander Aperribay Aranda | Euskaltel-Euskadi | + 04:40 | + 04:40 |
| 75 | Patxi Vila | Lampre-Fondital | + 05:46 | + 05:46 |
| 76 | David Arroyo | Caisse d'Epargne | + 05:46 | + 05:46 |
| 77 | Marzio Bruseghin | Lampre-Fondital | + 05:46 | + 05:46 |
| 78 | Rubén Plaza | Caisse d'Epargne | + 05:46 | + 05:46 |
| 79 | Ignacio Sarabia | Spiuk - Extremadura | + 10:32 | + 10:32 |
| 80 | José Abril Merino Juan | Vina Magna - Cropu | + 10:32 | + 10:32 |
| 81 | Antonio Cosme Fraile | Vina Magna - Cropu | + 11:35 | + 11:35 |