| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Damiano Cunego | Lampre | 04:20:21 | |
| 2 | Alejandro Valverde | Caisse d'Epargne | + 00 | |
| 3 | Kjell Carlström | Liquigas | + 00 | |
| 4 | Mikel Astarloza | Euskaltel-Euskadi | + 00 | |
| 5 | Alexandr Kolobnev | Team CSC - Saxo Bank | + 12 | + 12 |
| 6 | Paolo Tiralongo | Lampre | + 12 | + 12 |
| 7 | Jaume Rovira | Extremadura | + 12 | + 12 |
| 8 | Josep Jufré | Scott - American Beef | + 12 | + 12 |
| 9 | Benat Intxausti | + 12 | + 12 | |
| 10 | Egoi Martinez | Euskaltel-Euskadi | + 12 | + 12 |
| 11 | Anker Sørensen Chris | Team CSC - Saxo Bank | + 12 | + 12 |
| 12 | Mikel Nieve | Orbea - Oreka SDA | + 12 | + 12 |
| 13 | Julian Sanchez | Contentpolis - Murcia | + 12 | + 12 |
| 14 | Joaquim Rodríguez | Caisse d'Epargne | + 12 | + 12 |
| 15 | Ezequiel Mosquera | Xacobeo-Galicia | + 12 | + 12 |
| 16 | David Arroyo | Caisse d'Epargne | + 12 | + 12 |
| 17 | Fränk Schleck | Team CSC - Saxo Bank | + 12 | + 12 |
| 18 | Carlos Sastre | Team CSC - Saxo Bank | + 23 | + 23 |
| 19 | Amets Txurruka | Euskaltel-Euskadi | + 44 | + 44 |
| 20 | Dario Cataldo | Liquigas | + 44 | + 44 |
| 21 | Manuel Beltrán | Liquigas | + 44 | + 44 |
| 22 | Javier Etxarri | Contentpolis - Murcia | + 44 | + 44 |
| 23 | Andy Schleck | Team CSC - Saxo Bank | + 44 | + 44 |
| 24 | Jonathan Castroviejo | Orbea - Oreka SDA | + 44 | + 44 |
| 25 | Volodymir Gustov | Team CSC - Saxo Bank | + 44 | + 44 |
| 26 | Sergio Pardilla | Burgos Monumental | + 44 | + 44 |
| 27 | Alberto Fernandez | Scott - American Beef | + 44 | + 44 |
| 28 | José Gomez | Scott - American Beef | + 44 | + 44 |
| 29 | Roman Klimov | Katusha CT | + 01:37 | + 01:37 |
| 30 | Matej Mugerli | Liquigas | + 01:44 | + 01:44 |
| 31 | Roberto Alvarez Martin Luis | Burgos Monumental | + 01:44 | + 01:44 |
| 32 | Philip Deignan | AG2R La Mondiale | + 01:44 | + 01:44 |
| 33 | Daniel Sesma Sorbet | Orbea - Oreka SDA | + 01:44 | + 01:44 |
| 34 | Eduard Vorganov | Xacobeo-Galicia | + 01:44 | + 01:44 |
| 35 | Hubert Dupont | AG2R La Mondiale | + 01:44 | + 01:44 |
| 36 | Julien Loubet | AG2R La Mondiale | + 01:44 | + 01:44 |
| 37 | Sergio Domínguez Muñoz | Contentpolis - Murcia | + 01:44 | + 01:44 |
| 38 | Iban Mayoz | Xacobeo-Galicia | + 01:44 | + 01:44 |
| 39 | Iker Camaño | Scott - American Beef | + 01:44 | + 01:44 |
| 40 | Miguel Minguez | Orbea - Oreka SDA | + 01:44 | + 01:44 |
| 41 | Javier Ramirez Torres Jesus | Extremadura | + 01:44 | + 01:44 |
| 42 | Juan Olmo | Andalucia - Cajasur | + 01:44 | + 01:44 |
| 43 | Patxi Vila | Lampre | + 01:47 | + 01:47 |
| 44 | Jose Terciado Francisco | Extremadura | + 01:47 | + 01:47 |
| 45 | Avelino Antuna Coro Andres | Burgos Monumental | + 01:47 | + 01:47 |
| 46 | Gustav Larsson | Team CSC - Saxo Bank | + 01:47 | + 01:47 |
| 47 | Alberto Losada | Caisse d'Epargne | + 01:47 | + 01:47 |
| 48 | Íñigo Cuesta | Team CSC - Saxo Bank | + 01:47 | + 01:47 |
| 49 | Andrey Solomennikov | Katusha CT | + 01:54 | + 01:54 |
| 50 | David de La Fuente | Scott - American Beef | + 01:54 | + 01:54 |
| 51 | Matteo Bono | Lampre | + 01:54 | + 01:54 |
| 52 | Leonardo Piepoli | Scott - American Beef | + 01:54 | + 01:54 |
| 53 | Ruben Lobato | Scott - American Beef | + 01:54 | + 01:54 |
| 54 | Javier Moreno | Andalucia - Cajasur | + 01:59 | + 01:59 |
| 55 | Dmitriy Kosyakov | Katusha CT | + 02:12 | + 02:12 |
| 56 | Xabat Ochotorena | Extremadura | + 02:25 | + 02:25 |
| 57 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 03:44 | + 03:44 |
| 58 | Iván Melero | Orbea - Oreka SDA | + 03:44 | + 03:44 |
| 59 | Blaise Sonnery | AG2R La Mondiale | + 04:50 | + 04:50 |
| 60 | David López | Caisse d'Epargne | + 05:35 | + 05:35 |
| 61 | Dionisio Galparsoro | Euskaltel-Euskadi | + 05:59 | + 05:59 |
| 62 | Pedro Gutierrez Alvarez | Burgos Monumental | + 07:02 | + 07:02 |
| 63 | Raul Santamarta Valvuena | Burgos Monumental | + 07:12 | + 07:12 |
| 64 | Rafael Serrano Fernandez | Contentpolis - Murcia | + 07:12 | + 07:12 |
| 65 | Jesus Rosendo Prado | Andalucia - Cajasur | + 07:12 | + 07:12 |
| 66 | Eladio Sánchez | Orbea - Oreka SDA | + 07:12 | + 07:12 |
| 67 | Angel Mate Luis | Andalucia - Cajasur | + 07:12 | + 07:12 |
| 68 | Enrique Mata Cabello | Burgos Monumental | + 07:12 | + 07:12 |
| 69 | Antonio Piedra | Andalucia - Cajasur | + 07:12 | + 07:12 |
| 70 | Marlon Perez | Caisse d'Epargne | + 08:59 | + 08:59 |
| 71 | Aitor Galdos | Euskaltel-Euskadi | + 08:59 | + 08:59 |
| 72 | Igor Romero Etxebarria | Orbea - Oreka SDA | + 08:59 | + 08:59 |
| 73 | Aitor Olano Orbegozo | Orbea - Oreka SDA | + 08:59 | + 08:59 |
| 74 | Eritz Ruiz | Orbea - Oreka SDA | + 08:59 | + 08:59 |
| 75 | Javier Iriarte | Burgos Monumental | + 08:59 | + 08:59 |
| 76 | Daniel Moreno | Caisse d'Epargne | + 08:59 | + 08:59 |
| 77 | Mikhail Antonov | Katusha CT | + 08:59 | + 08:59 |
| 78 | Olegs Melehs | Dynatek - Latvia | + 08:59 | + 08:59 |
| 79 | Daniil Komkov | Katusha CT | + 08:59 | + 08:59 |
| 80 | Alexander Porsev | Katusha CT | + 08:59 | + 08:59 |
| 81 | Alexey Kunshin | Katusha CT | + 08:59 | + 08:59 |
| 82 | Jurgen van Goolen | Team CSC - Saxo Bank | + 08:59 | + 08:59 |
| 83 | Javier Estrada Juan | Andalucia - Cajasur | + 08:59 | + 08:59 |
| 84 | Valerio Agnoli | Liquigas | + 08:59 | + 08:59 |
| 85 | Rigoberto Uran | Caisse d'Epargne | + 08:59 | + 08:59 |
| 86 | Alberto Fernandez Sainz | Xacobeo-Galicia | + 08:59 | + 08:59 |
| 87 | Jorge Azanza | Euskaltel-Euskadi | + 08:59 | + 08:59 |
| 88 | Israel Pérez | Extremadura | + 08:59 | + 08:59 |
| 89 | Marco Marzano | Lampre | + 08:59 | + 08:59 |
| 90 | Serafín Martinez | Xacobeo-Galicia | + 12:28 | + 12:28 |
| 91 | Francisco Mourón Juan | Xacobeo-Galicia | + 12:28 | + 12:28 |
| 92 | Jorge Sanchez Pimienta | Contentpolis - Murcia | + 12:28 | + 12:28 |
| 93 | Nicolas Rousseau | AG2R La Mondiale | + 12:28 | + 12:28 |
| 94 | David Francisco Delgado | Burgos Monumental | + 12:28 | + 12:28 |