| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Javier Rodriguez | Comunidad Valenciana | 05:04:23 | |
| 2 | Alejandro Valverde | Illes Balears - Caisse d'Epargne | + 09 | + 09 |
| 3 | Angel Vicioso | Liberty Seguros - Würth Team | + 09 | + 09 |
| 4 | Egoi Martinez | Euskaltel-Euskadi | + 09 | + 09 |
| 5 | Ricardo Serrano | Kaiku | + 09 | + 09 |
| 6 | David Blanco | Comunidad Valenciana | + 09 | + 09 |
| 7 | Matthias Kessler | T-Mobile Team | + 09 | + 09 |
| 8 | Dionisio Galparsoro | Kaiku | + 09 | + 09 |
| 9 | Pedro Arreitunandia | Team Barloworld - Valsir | + 09 | + 09 |
| 10 | Leonardo Bertagnolli | Cofidis | + 09 | + 09 |
| 11 | Joaquim Rodríguez | Saunier Duval - Prodir | + 09 | + 09 |
| 12 | Jorge Ferrio Luque | Spiuk | + 09 | + 09 |
| 13 | Eladio Jiménez | Comunidad Valenciana | + 12 | + 12 |
| 14 | Haimar Zubeldia | Euskaltel-Euskadi | + 12 | + 12 |
| 15 | David Etxebarria | Liberty Seguros - Würth Team | + 26 | + 26 |
| 16 | Aitor Osa | Illes Balears - Caisse d'Epargne | + 54 | + 54 |
| 17 | Jon Bru | Kaiku | + 03:07 | + 03:07 |
| 18 | Samuel Sánchez | Euskaltel-Euskadi | + 03:07 | + 03:07 |
| 19 | David Muñoz | Comunidad Valenciana | + 03:07 | + 03:07 |
| 20 | Nacor Burgos | Relax - Fuenlabarda | + 03:07 | + 03:07 |
| 21 | Luis Pasamontes | Relax - Fuenlabarda | + 03:07 | + 03:07 |
| 22 | Tiaan Kannemeyer | Team Barloworld - Valsir | + 03:07 | + 03:07 |
| 23 | Alberto Martinez José | Agritubel | + 03:07 | + 03:07 |
| 24 | Aitor Perez Arrieta | Spiuk | + 03:07 | + 03:07 |
| 25 | Ruben Lobato | Saunier Duval - Prodir | + 03:07 | + 03:07 |
| 26 | José Lara Francisco | T-Mobile Team | + 03:07 | + 03:07 |
| 27 | Francisco Mancebo | Illes Balears - Caisse d'Epargne | + 03:07 | + 03:07 |
| 28 | Dmitriy Fofonov | Cofidis | + 03:07 | + 03:07 |
| 29 | Matthias Russ | Gerolsteiner | + 03:07 | + 03:07 |
| 30 | Manuel Lloret | Comunidad Valenciana | + 03:34 | + 03:34 |
| 31 | Serhiy Honchar | Domina Vacanze | + 03:47 | + 03:47 |
| 32 | Andrea Moletta | Gerolsteiner | + 03:47 | + 03:47 |
| 33 | Javier Ramirez | Liberty Seguros - Würth Team | + 03:47 | + 03:47 |
| 34 | Antonio Serrano Marcos | Liberty Seguros - Würth Team | + 03:47 | + 03:47 |
| 35 | Vladimir Karpets | Illes Balears - Caisse d'Epargne | + 03:47 | + 03:47 |
| 36 | Ruggero Borghi | Domina Vacanze | + 03:47 | + 03:47 |
| 37 | Matteo Carrara | Team Barloworld - Valsir | + 08:01 | + 08:01 |
| 38 | Unai Osa | Illes Balears - Caisse d'Epargne | + 08:48 | + 08:48 |
| 39 | Manuel Garate Juan | Saunier Duval - Prodir | + 08:48 | + 08:48 |
| 40 | Andoni Aranaga Akzune | Kaiku | + 08:48 | + 08:48 |
| 41 | Carlos Dominguez Juan | Saunier Duval - Prodir | + 08:48 | + 08:48 |
| 42 | Daniel Navarro | Liberty Seguros - Würth Team | + 08:48 | + 08:48 |
| 43 | Iban Mayo | Euskaltel-Euskadi | + 08:48 | + 08:48 |
| 44 | Jose Ruiz Sanchez | Andalucia - Paul Versan | + 08:48 | + 08:48 |
| 45 | Roberto Heras | Liberty Seguros - Würth Team | + 08:48 | + 08:48 |
| 46 | Daniel Moreno | Relax - Fuenlabarda | + 08:48 | + 08:48 |
| 47 | Carlos Castaño | Andalucia - Paul Versan | + 08:48 | + 08:48 |
| 48 | Marcel Strauss | Gerolsteiner | + 08:48 | + 08:48 |
| 49 | Íñigo Cuesta | Saunier Duval - Prodir | + 08:48 | + 08:48 |
| 50 | Alan Perez Lezaun | Orbea | + 11:59 | + 11:59 |
| 51 | Gustavo Dominguez Lemos | Orbea | + 11:59 | + 11:59 |
| 52 | Matthew White | Cofidis | + 11:59 | + 11:59 |
| 53 | Jorge Azanza | Kaiku | + 11:59 | + 11:59 |
| 54 | Joan Horrach | Illes Balears - Caisse d'Epargne | + 11:59 | + 11:59 |
| 55 | Ángel Edo | Saunier Duval - Prodir | + 11:59 | + 11:59 |
| 56 | Félix Cárdenas | Team Barloworld - Valsir | + 11:59 | + 11:59 |
| 57 | Christian Werner | T-Mobile Team | + 11:59 | + 11:59 |
| 58 | Marco Fertonani | Domina Vacanze | + 11:59 | + 11:59 |
| 59 | Adrian Bonilla | Comunidad Valenciana | + 11:59 | + 11:59 |
| 60 | Alberto Benitez Jose | Spiuk | + 11:59 | + 11:59 |
| 61 | David Latasa Lasa | Comunidad Valenciana | + 11:59 | + 11:59 |
| 62 | Alberto Contador | Liberty Seguros - Würth Team | + 11:59 | + 11:59 |
| 63 | Xabier Zandio | Illes Balears - Caisse d'Epargne | + 11:59 | + 11:59 |
| 64 | Angel Vallejo Dominquez | Relax - Fuenlabarda | + 11:59 | + 11:59 |
| 65 | Antonio Berasategui | Kaiku | + 11:59 | + 11:59 |
| 66 | Xavier Florencio | Relax - Fuenlabarda | + 11:59 | + 11:59 |
| 67 | Gorka Gonzalez | Euskaltel-Euskadi | + 17:39 | + 17:39 |
| 68 | Ruben Oarbeascoa Ispizua | Kaiku | + 17:39 | + 17:39 |
| 69 | Xavier Tondó | Catalunya - Angel Mir | + 17:39 | + 17:39 |
| 70 | Igor Astarloa | Team Barloworld - Valsir | + 17:39 | + 17:39 |
| 71 | Igor Anton | Euskaltel-Euskadi | + 17:39 | + 17:39 |
| 72 | Gorka Amuriza Gumucio | Orbea | + 17:39 | + 17:39 |
| 73 | Antonio Pastor Roldan Juan | Andalucia - Paul Versan | + 18:47 | + 18:47 |
| 74 | Alessandro Vanotti | Domina Vacanze | + 18:49 | + 18:49 |
| 75 | Iban Mayoz | Relax - Fuenlabarda | + 20:46 | + 20:46 |
| 76 | Efrain Gutierrez Sanchez | Andalucia - Paul Versan | + 21:22 | + 21:22 |
| 77 | Christophe Edaleine | Cofidis | + 21:22 | + 21:22 |
| 78 | Mario Almagro Valero Jose | Relax - Fuenlabarda | + 21:22 | + 21:22 |
| 79 | Manuel Gomes Colinas Victor | Andalucia - Paul Versan | + 21:22 | + 21:22 |
| 80 | Israel Pérez | Spiuk | + 21:22 | + 21:22 |