| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Alejandro Valverde | Movistar Team | 04:25:01 | |
| 2 | Tom-jelte Slagter | Garmin - Sharp | + 01:02 | + 01:02 |
| 3 | Sergey Chernetskiy | Team Katusha | + 01:02 | + 01:02 |
| 4 | André Cardoso | Garmin - Sharp | + 01:06 | + 01:06 |
| 5 | Yury Trofimov | Team Katusha | + 01:08 | + 01:08 |
| 6 | Ryder Hesjedal | Garmin - Sharp | + 01:40 | + 01:40 |
| 7 | Alexandr Kolobnev | Team Katusha | + 02:18 | + 02:18 |
| 8 | Benjamin King | Garmin - Sharp | + 02:28 | + 02:28 |
| 9 | David Arroyo | Caja Rural - Seguros RGA | + 02:39 | + 02:39 |
| 10 | Miguel Minguez | Euskadi | + 03:11 | + 03:11 |
| 11 | Caleb Fairly | Garmin - Sharp | + 03:11 | + 03:11 |
| 12 | David Belda | Burgos - BH | + 03:43 | + 03:43 |
| 13 | Sergey Shilov | Lokosphinx | + 03:45 | + 03:45 |
| 14 | John Gadret | Movistar Team | + 03:46 | + 03:46 |
| 15 | Fabian Wegmann | Garmin - Sharp | + 03:54 | + 03:54 |
| 16 | Jesus Del Pino | Burgos - BH | + 03:54 | + 03:54 |
| 17 | León Sánchez Luis | Caja Rural - Seguros RGA | + 04:24 | + 04:24 |
| 18 | Marcos Garcia | Caja Rural - Seguros RGA | + 04:24 | + 04:24 |
| 19 | Jesus Herrada | Movistar Team | + 06:36 | + 06:36 |
| 20 | Ion Izagirre | Movistar Team | + 06:36 | + 06:36 |
| 21 | Jose Herrada | Movistar Team | + 06:36 | + 06:36 |
| 22 | Nathan Haas | Garmin - Sharp | + 07:45 | + 07:45 |
| 23 | Carlos Barbero | Euskadi | + 07:45 | + 07:45 |
| 24 | Vicente Garcia de Mateos | Louletano | + 07:45 | + 07:45 |
| 25 | Daniel Silva | Radio Popular | + 07:45 | + 07:45 |
| 26 | Pavel Brutt | Team Katusha | + 08:30 | + 08:30 |
| 27 | Aleksey Rybalkin | Lokosphinx | + 10:38 | + 10:38 |
| 28 | Manuel Sola Arjona | Keith Mobel - Partizan | + 11:11 | + 11:11 |
| 29 | Andreas Keuser | Keith Mobel - Partizan | + 11:16 | + 11:16 |
| 30 | Janjan Navarra Junrey | LBC - MVPSF Cycling Pilipinas | + 11:16 | + 11:16 |
| 31 | Benat Txoperena | Euskadi | + 12:19 | + 12:19 |
| 32 | Raul Garcia de Mateos | Louletano | + 12:20 | + 12:20 |
| 33 | Jordi Simon | Team Ecuador | + 12:20 | + 12:20 |
| 34 | Micael Isidoro | Louletano | + 12:20 | + 12:20 |
| 35 | Sergey Vdovin | Lokosphinx | + 12:22 | + 12:22 |
| 36 | Arkimedes Arguelyes | Lokosphinx | + 12:29 | + 12:29 |
| 37 | Filipe Silva Sandro | Louletano | + 12:30 | + 12:30 |
| 38 | Mikel Iturria | Euskadi | + 12:44 | + 12:44 |
| 39 | Ibai Salas | Burgos - BH | + 12:51 | + 12:51 |
| 40 | Pello Bilbao | Caja Rural - Seguros RGA | + 12:51 | + 12:51 |
| 41 | Haritz Orbe | Euskadi | + 12:51 | + 12:51 |
| 42 | Javier Aramendia | Caja Rural - Seguros RGA | + 12:51 | + 12:51 |
| 43 | Igor Merino | Burgos - BH | + 12:51 | + 12:51 |
| 44 | Jaime Roson | Team Ecuador | + 12:51 | + 12:51 |
| 45 | Jon Larrinaga | Euskadi | + 13:02 | + 13:02 |
| 46 | Gorka Izagirre | Movistar Team | + 13:02 | + 13:02 |
| 47 | Victor Etxeberria | Euskadi | + 14:19 | + 14:19 |
| 48 | Dmitry Sokolov | Lokosphinx | + 16:46 | + 16:46 |
| 49 | Alexander Vdovin | Lokosphinx | + 18:23 | + 18:23 |
| 50 | Raul Alarcon | Louletano | + 18:23 | + 18:23 |
| 51 | Pablo Lechuga | Euskadi | + 18:24 | + 18:24 |
| 52 | Evgeny Shalunov | Lokosphinx | + 18:42 | + 18:42 |
| 53 | Martin Montenegro Adaro Jorge | Louletano | + 18:42 | + 18:42 |