| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Fabian Wegmann | Gerolsteiner | +null | |
| 2 | Michael Albasini | Liquigas | +null | |
| 3 | Joaquim Rodríguez | Caisse d'Epargne | +null | |
| 4 | David Herrero | Xacobeo-Galicia | +null | |
| 5 | Riccardo Riccò | Scott - American Beef | +null | |
| 6 | Manuel Vazquez | Contentpolis - Murcia | +null | |
| 7 | Leonardo Duque | Cofidis | +null | |
| 8 | David de La Fuente | Scott - American Beef | +null | |
| 9 | Aitor Galdos | Euskaltel-Euskadi | +null | |
| 10 | Andrea Moletta | Gerolsteiner | +null | |
| 11 | Bobby Julich | Team CSC - Saxo Bank | +null | |
| 12 | David García Dapena | Xacobeo-Galicia | +null | |
| 13 | Alberto Fernandez | Scott - American Beef | +null | |
| 14 | Mikel Nieve | Orbea - Oreka SDA | +null | |
| 15 | Vladimir Efimkin | AG2R La Mondiale | +null | |
| 16 | Matej Mugerli | Liquigas | +null | |
| 17 | Ruben Lobato | Scott - American Beef | +null | |
| 18 | Jose Terciado Francisco | Extremadura | +null | |
| 19 | Javier Moreno | Andalucia - Cajasur | +null | |
| 20 | Anker Sørensen Chris | Team CSC - Saxo Bank | +null | |
| 21 | Jose Herrada | Contentpolis - Murcia | + 20 | + 20 |
| 22 | Eloy Teruel | Contentpolis - Murcia | + 21 | + 21 |
| 23 | Rinaldo Nocentini | AG2R La Mondiale | + 21 | + 21 |
| 24 | Oliver Zaugg | Gerolsteiner | + 28 | + 28 |
| 25 | Dario Cataldo | Liquigas | + 28 | + 28 |
| 26 | Carlos Sastre | Team CSC - Saxo Bank | + 28 | + 28 |
| 27 | Nicki Sørensen | Team CSC - Saxo Bank | + 28 | + 28 |
| 28 | Hubert Dupont | AG2R La Mondiale | + 28 | + 28 |
| 29 | Stéphane Goubert | AG2R La Mondiale | + 28 | + 28 |
| 30 | Alejandro Valverde | Caisse d'Epargne | + 28 | + 28 |
| 31 | Fränk Schleck | Team CSC - Saxo Bank | + 28 | + 28 |
| 32 | Igor Astarloa | Team Milram | + 32 | + 32 |
| 33 | Ivan Velasco | Euskaltel-Euskadi | + 34 | + 34 |
| 34 | Javier Etxarri | Contentpolis - Murcia | + 35 | + 35 |
| 35 | Julien El Fares | Cofidis | + 35 | + 35 |
| 36 | Xabat Ochotorena | Extremadura | + 40 | + 40 |
| 37 | José Rujano | Caisse d'Epargne | + 41 | + 41 |
| 38 | Mikel Astarloza | Euskaltel-Euskadi | + 41 | + 41 |
| 39 | Egoi Martinez | Euskaltel-Euskadi | + 41 | + 41 |
| 40 | Iban Mayoz | Xacobeo-Galicia | + 44 | + 44 |
| 41 | Ezequiel Mosquera | Xacobeo-Galicia | + 44 | + 44 |
| 42 | Alberto Rodriguez | Contentpolis - Murcia | + 44 | + 44 |
| 43 | Rodrigo Garcia Rena | Extremadura | + 47 | + 47 |
| 44 | Kjell Carlström | Liquigas | + 48 | + 48 |
| 45 | Sergio Ghisalberti | Team Milram | + 49 | + 49 |
| 46 | Amaël Moinard | Cofidis | + 56 | + 56 |
| 47 | Daniel Moreno | Caisse d'Epargne | + 59 | + 59 |
| 48 | Francesco de Bonis | Gerolsteiner | + 01:00 | + 01:00 |
| 49 | Íñigo Cuesta | Team CSC - Saxo Bank | + 01:00 | + 01:00 |
| 50 | Bingen Fernández Bustinza | Cofidis | + 01:00 | + 01:00 |
| 51 | Manuel Ortega | Andalucia - Cajasur | + 01:07 | + 01:07 |
| 52 | Vladimir Karpets | Caisse d'Epargne | + 01:15 | + 01:15 |
| 53 | Xabier Zandio | Caisse d'Epargne | + 01:15 | + 01:15 |
| 54 | Iker Camaño | Scott - American Beef | + 01:15 | + 01:15 |
| 55 | Benat Intxausti | Scott - American Beef | + 01:21 | + 01:21 |
| 56 | Steve Zamperi | Cofidis | + 01:21 | + 01:21 |
| 57 | Stefan Schumacher | Gerolsteiner | + 01:26 | + 01:26 |
| 58 | Bernhard Kohl | Gerolsteiner | + 01:26 | + 01:26 |
| 59 | Johannes Fröhlinger | Gerolsteiner | + 01:26 | + 01:26 |
| 60 | Andy Schleck | Team CSC - Saxo Bank | + 01:29 | + 01:29 |
| 61 | Mickaël Buffaz | Cofidis | + 01:49 | + 01:49 |
| 62 | Blaise Sonnery | AG2R La Mondiale | + 03:00 | + 03:00 |
| 63 | Matej Jurco | Team Milram | + 03:00 | + 03:00 |
| 64 | Jonathan Castroviejo | Orbea - Oreka SDA | + 03:00 | + 03:00 |
| 65 | René Mandri | AG2R La Mondiale | + 03:00 | + 03:00 |
| 66 | Martin Velits | Team Milram | + 03:00 | + 03:00 |
| 67 | Oleg Chuzhda | Contentpolis - Murcia | + 03:00 | + 03:00 |
| 68 | Avelino Antuna Coro Andres | Burgos Monumental | + 03:00 | + 03:00 |
| 69 | Amets Txurruka | Euskaltel-Euskadi | + 03:00 | + 03:00 |
| 70 | Javier Ramirez Torres Jesus | Extremadura | + 03:00 | + 03:00 |
| 71 | Philip Deignan | AG2R La Mondiale | + 03:00 | + 03:00 |
| 72 | Pablo Lastras | Caisse d'Epargne | + 03:00 | + 03:00 |
| 73 | Iñaki Isasi | Euskaltel-Euskadi | + 03:09 | + 03:09 |
| 74 | Luis Arrieta José | AG2R La Mondiale | + 03:21 | + 03:21 |
| 75 | Iván Melero | Orbea - Oreka SDA | + 03:32 | + 03:32 |
| 76 | Adrian Palomares | Contentpolis - Murcia | + 03:37 | + 03:37 |
| 77 | Juan Olmo | Andalucia - Cajasur | + 03:37 | + 03:37 |
| 78 | Andriy Grivko | Team Milram | + 05:56 | + 05:56 |
| 79 | José Casas Claudio | Andalucia - Cajasur | + 06:45 | + 06:45 |
| 80 | Miguel Galindo Jose | Contentpolis - Murcia | + 07:36 | + 07:36 |
| 81 | Enrique Mata Cabello | Burgos Monumental | + 08:53 | + 08:53 |
| 82 | Pedro Gutierrez Alvarez | Burgos Monumental | + 08:56 | + 08:56 |
| 83 | Valerio Agnoli | Liquigas | + 09:00 | + 09:00 |
| 84 | Rafael Serrano Fernandez | Contentpolis - Murcia | + 09:00 | + 09:00 |
| 85 | Javier Estrada Juan | Andalucia - Cajasur | + 09:00 | + 09:00 |
| 86 | Antonio Carrasco Jose | Andalucia - Cajasur | + 09:00 | + 09:00 |
| 87 | Eduard Vorganov | Xacobeo-Galicia | + 09:03 | + 09:03 |
| 88 | Delio Fernandez | Xacobeo-Galicia | + 09:03 | + 09:03 |
| 89 | Francisco Mourón Juan | Xacobeo-Galicia | + 14:19 | + 14:19 |
| 90 | Israel Pérez | Extremadura | + 14:19 | + 14:19 |
| 91 | Javier Iriarte | Burgos Monumental | + 14:19 | + 14:19 |
| 92 | Rafael Rodriguez Segarra | Contentpolis - Murcia | + 14:22 | + 14:22 |