| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Fabian Wegmann | Gerolsteiner | 04:41:38 | |
| 2 | Andrea Moletta | Gerolsteiner | + 00 | |
| 3 | Andriy Grivko | Team Milram | + 00 | |
| 4 | Stefano Garzelli | Liquigas | + 00 | |
| 5 | Manuele Mori | Saunier Duval - Prodir | + 00 | |
| 6 | Cristian Moreni | Cofidis | + 00 | |
| 7 | Aitor Osa | Astana - Würth Team | + 00 | |
| 8 | Jordi Berenguer Ferrer | Massi | + 06 | + 06 |
| 9 | Alberto Contador | Astana - Würth Team | + 06 | + 06 |
| 10 | Jon Bru | Kaiku | + 06 | + 06 |
| 11 | Igor Anton | Euskaltel-Euskadi | + 06 | + 06 |
| 12 | Jorge Azanza | Kaiku | + 06 | + 06 |
| 13 | Adolfo Garcia Quesada | Andalucia - Paul Versan | + 06 | + 06 |
| 14 | David Latasa Lasa | Comunidad Valenciana | + 14 | + 14 |
| 15 | Luis Arrieta José | AG2R Prévoyance | + 14 | + 14 |
| 16 | Alejandro Valverde | Caisse d'Epargne - Illes Balears | + 14 | + 14 |
| 17 | Antonio Colom | Caisse d'Epargne - Illes Balears | + 14 | + 14 |
| 18 | Jorge Ferrio Luque | 3 Molinos Resort | + 14 | + 14 |
| 19 | Mikel Astarloza | AG2R Prévoyance | + 14 | + 14 |
| 20 | Daniel Navarro | Astana - Würth Team | + 14 | + 14 |
| 21 | Haimar Zubeldia | Euskaltel-Euskadi | + 14 | + 14 |
| 22 | Stéphane Goubert | AG2R Prévoyance | + 14 | + 14 |
| 23 | Leonardo Bertagnolli | Cofidis | + 26 | + 26 |
| 24 | José Cobo Juan | Saunier Duval - Prodir | + 26 | + 26 |
| 25 | Joaquim Rodríguez | Caisse d'Epargne - Illes Balears | + 26 | + 26 |
| 26 | Sergio Pardilla | Vina Magna - Cropu | + 32 | + 32 |
| 27 | Gorka Amuriza Gumucio | Orbea | + 32 | + 32 |
| 28 | Javier Rodriguez | Comunidad Valenciana | + 32 | + 32 |
| 29 | Francisco Mancebo | AG2R Prévoyance | + 32 | + 32 |
| 30 | Mario Sanchez Fernandez | Andalucia - Paul Versan | + 32 | + 32 |
| 31 | Ángel Edo | Andalucia - Paul Versan | + 32 | + 32 |
| 32 | David Etxebarria | Astana - Würth Team | + 32 | + 32 |
| 33 | Juan Olmo | Andalucia - Paul Versan | + 32 | + 32 |
| 34 | Sergio Ghisalberti | Team Milram | + 39 | + 39 |
| 35 | Luengo Celaya Anton | Euskaltel-Euskadi | + 39 | + 39 |
| 36 | Iván Gutiérrez | Caisse d'Epargne - Illes Balears | + 39 | + 39 |
| 37 | Ramiro Parra Iván | Cofidis | + 39 | + 39 |
| 38 | Ezequiel Mosquera | Comunidad Valenciana | + 39 | + 39 |
| 39 | Danilo Di Luca | Liquigas | + 51 | + 51 |
| 40 | Joseba Beloki | Astana - Würth Team | + 58 | + 58 |
| 41 | Aitor Perez Arrieta | Caisse d'Epargne - Illes Balears | + 01:07 | + 01:07 |
| 42 | Leonardo Piepoli | Saunier Duval - Prodir | + 01:09 | + 01:09 |
| 43 | Vladimir Miholjevic | Liquigas | + 01:21 | + 01:21 |
| 44 | Xavier Tondó | Relax - GAM | + 01:21 | + 01:21 |
| 45 | Vladimir Karpets | Caisse d'Epargne - Illes Balears | + 01:21 | + 01:21 |
| 46 | Alberto Fernandez | Saunier Duval - Prodir | + 01:21 | + 01:21 |
| 47 | Xabat Ochotorena | Orbea | + 02:23 | + 02:23 |
| 48 | Carlos Lopez Marin Juan | Grupo Nicolas Mateos | + 02:49 | + 02:49 |
| 49 | Ricardo Serrano | Kaiku | + 02:49 | + 02:49 |
| 50 | Unai Osa | Astana - Würth Team | + 02:49 | + 02:49 |
| 51 | Sylvain Chavanel | Cofidis | + 02:49 | + 02:49 |
| 52 | Inigo Chaurreau | AG2R Prévoyance | + 02:49 | + 02:49 |
| 53 | Andrea Noè | Liquigas | + 03:17 | + 03:17 |
| 54 | David López | Euskaltel-Euskadi | + 03:39 | + 03:39 |
| 55 | Arkaitz Durán | Saunier Duval - Prodir | + 04:23 | + 04:23 |
| 56 | Manuel Lloret | Comunidad Valenciana | + 04:31 | + 04:31 |
| 57 | Luis Martinez Jose | Comunidad Valenciana | + 04:31 | + 04:31 |
| 58 | Beat Zberg | Gerolsteiner | + 04:31 | + 04:31 |
| 59 | Hubert Dupont | AG2R Prévoyance | + 04:31 | + 04:31 |
| 60 | Dario Cioni | Liquigas | + 04:31 | + 04:31 |
| 61 | Javier Ruiz de Larrinaga | Kaiku | + 04:31 | + 04:31 |
| 62 | Alessandro Spezialetti | Liquigas | + 04:31 | + 04:31 |
| 63 | Gorka Verdugo | Euskaltel-Euskadi | + 04:31 | + 04:31 |
| 64 | Maxim Iglinskiy | Team Milram | + 04:31 | + 04:31 |
| 65 | Patrick Calcagni | Liquigas | + 04:31 | + 04:31 |
| 66 | Oliver Zaugg | Saunier Duval - Prodir | + 04:31 | + 04:31 |
| 67 | Adrian Palomares | Kaiku | + 04:48 | + 04:48 |
| 68 | Ruben Lobato | Saunier Duval - Prodir | + 04:56 | + 04:56 |
| 69 | Francisco Andujar Sanchez | Massi | + 05:02 | + 05:02 |
| 70 | Alberto Rodriguez | Massi | + 07:57 | + 07:57 |
| 71 | Antonio Cosme Fraile | Vina Magna - Cropu | + 07:57 | + 07:57 |
| 72 | Aitor Hernández | Euskaltel-Euskadi | + 07:57 | + 07:57 |
| 73 | Luis Pérez Rodríguez | Cofidis | + 07:57 | + 07:57 |
| 74 | Gustavo Dominguez Lemos | Orbea | + 07:57 | + 07:57 |
| 75 | Vicente Peiro Marqueno | Comunidad Valenciana | + 07:57 | + 07:57 |
| 76 | Mario Almagro Valero Jose | Relax - GAM | + 07:57 | + 07:57 |
| 77 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 07:57 | + 07:57 |
| 78 | Ivan Velasco | Orbea | + 07:57 | + 07:57 |
| 79 | Raul Garcia de Mateos | Relax - GAM | + 08:10 | + 08:10 |
| 80 | Luis Marichalar Pedro | Andalucia - Paul Versan | + 08:10 | + 08:10 |
| 81 | Isidro Nozal Vega | Astana - Würth Team | + 08:15 | + 08:15 |
| 82 | Björn Schröder | Team Milram | + 11:50 | + 11:50 |
| 83 | Daniel Musiol | Team Milram | + 11:50 | + 11:50 |
| 84 | Victor Hernandez Baeta | Grupo Nicolas Mateos | + 11:50 | + 11:50 |
| 85 | Rafael Casero Moreno | 3 Molinos Resort | + 11:50 | + 11:50 |
| 86 | Inigo Lazkano Iriondo | Orbea | + 11:50 | + 11:50 |
| 87 | Maxime Monfort | Cofidis | + 11:50 | + 11:50 |
| 88 | Tristan Valentin | Cofidis | + 11:50 | + 11:50 |
| 89 | Nacor Burgos | Relax - GAM | + 11:50 | + 11:50 |
| 90 | Miguel Galindo Jose | Relax - GAM | + 11:50 | + 11:50 |
| 91 | Francisco Cabello | Andalucia - Paul Versan | + 11:50 | + 11:50 |
| 92 | Mauricio Ortega | Atom | + 11:50 | + 11:50 |
| 93 | Oscar Grau Jorda | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 94 | Alan Perez Lezaun | Orbea | + 11:50 | + 11:50 |
| 95 | Luis Maldonado Cano | Massi | + 11:50 | + 11:50 |
| 96 | Gerardo Fernandez | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 97 | Vicente Ballester Martinez | Comunidad Valenciana | + 11:50 | + 11:50 |
| 98 | Jorge Capitan Peregina | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 99 | Jose Herrada | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 100 | Israel Nunez Baticon | Kaiku | + 11:50 | + 11:50 |
| 101 | Roberto Laiseka | Euskaltel-Euskadi | + 11:50 | + 11:50 |
| 102 | Joseba Albizu Lizaso | Euskaltel-Euskadi | + 11:50 | + 11:50 |
| 103 | Jesús Hernández | Relax - GAM | + 11:50 | + 11:50 |
| 104 | Jorge García Marín | Relax - GAM | + 11:50 | + 11:50 |
| 105 | Isidro Cerrato Lopez | 3 Molinos Resort | + 11:50 | + 11:50 |
| 106 | Mikel Elgezabal Fernandez | Atom | + 11:50 | + 11:50 |
| 107 | Xabier Zandio | Caisse d'Epargne - Illes Balears | + 11:50 | + 11:50 |
| 108 | Pablo de Pedro Garcia | Grupo Nicolas Mateos | + 11:50 | + 11:50 |
| 109 | Sergio Herrero | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 110 | Josu Agirre Asegniloaza | Orbea | + 11:50 | + 11:50 |
| 111 | José Casas Claudio | Comunidad Valenciana | + 11:50 | + 11:50 |
| 112 | Pedro Martinez Romera | 3 Molinos Resort | + 11:50 | + 11:50 |
| 113 | Fernando Herrero Gutierrez | Grupo Nicolas Mateos | + 11:50 | + 11:50 |
| 114 | Diego Gallego | Vina Magna - Cropu | + 11:50 | + 11:50 |
| 115 | Manuel Diaz Armas Dailos | Orbea | + 11:50 | + 11:50 |
| 116 | David Arroyo | Caisse d'Epargne - Illes Balears | + 11:50 | + 11:50 |
| 117 | Giovanni Visconti | Team Milram | + 11:50 | + 11:50 |
| 118 | Mario de Sarraga Orviz | Relax - GAM | + 11:55 | + 11:55 |
| 119 | Mikel Gaztanaga | Atom | + 16:06 | + 16:06 |
| 120 | José Abril Merino Juan | Vina Magna - Cropu | + 16:06 | + 16:06 |
| 121 | Antonio Garcia Gonzalez | Massi | + 17:37 | + 17:37 |
| 122 | Daniel Becke | Team Milram | + 18:47 | + 18:47 |
| 123 | Joseba Zumeta Etxabe | Orbea | + 18:49 | + 18:49 |
| 124 | Javier Moreno | Grupo Nicolas Mateos | + 20:13 | + 20:13 |
| 125 | Manuel Garcia Estevez Victor | Grupo Nicolas Mateos | + 20:13 | + 20:13 |