| # | Rider | Team | Time | Gap |
|---|---|---|---|---|
| 1 | Rinaldo Nocentini | AG2R Prévoyance | 04:59:17 | |
| 2 | Joaquim Rodríguez | Caisse d'Epargne | + 03 | + 03 |
| 3 | Alejandro Valverde | Caisse d'Epargne | + 05 | + 05 |
| 4 | Steve Morabito | Astana | + 05 | + 05 |
| 5 | José Cobo Juan | Saunier Duval - Prodir | + 05 | + 05 |
| 6 | Alberto Benitez Jose | Saunier Duval - Prodir | + 05 | + 05 |
| 7 | Francisco Mancebo | Relax - GAM | + 10 | + 10 |
| 8 | Javier Moreno | Spiuk - Extremadura | + 13 | + 13 |
| 9 | Igor Anton | Euskaltel-Euskadi | + 15 | + 15 |
| 10 | Javier Ramirez Torres Jesus | Spiuk - Extremadura | + 15 | + 15 |
| 11 | Antonio Redondo Jose | Astana | + 15 | + 15 |
| 12 | Xabat Ochotorena | Orbea - Laukiz F.T. | + 15 | + 15 |
| 13 | Rodrigo Garcia Rena | Fuerteventura - Canarias | + 15 | + 15 |
| 14 | Leonardo Duque | Cofidis | + 15 | + 15 |
| 15 | Hubert Dupont | AG2R Prévoyance | + 15 | + 15 |
| 16 | David Moncoutié | Cofidis | + 15 | + 15 |
| 17 | Mirko Celestino | Team Milram | + 15 | + 15 |
| 18 | Santiago Pérez | Relax - GAM | + 15 | + 15 |
| 19 | Israel Pérez | Spiuk - Extremadura | + 15 | + 15 |
| 20 | Fernando Torres Martin | Spiuk - Extremadura | + 15 | + 15 |
| 21 | Bingen Fernández Bustinza | Cofidis | + 15 | + 15 |
| 22 | Ivan Gilmartin | Vina Magna - Cropu | + 15 | + 15 |
| 23 | Andrey Mizurov | Astana | + 15 | + 15 |
| 24 | Julien Mazet | Astana | + 15 | + 15 |
| 25 | Stéphane Goubert | AG2R Prévoyance | + 15 | + 15 |
| 26 | Josu Mondelo Diaz | Spiuk - Extremadura | + 15 | + 15 |
| 27 | Amaël Moinard | Cofidis | + 15 | + 15 |
| 28 | Antonio Olmo | Andalucia - Cajasur | + 15 | + 15 |
| 29 | Juan Olmo | Andalucia - Cajasur | + 15 | + 15 |
| 30 | Rui Sousa | Liberty Seguros | + 15 | + 15 |
| 31 | Luis Carrasco Gamiz José | Andalucia - Cajasur | + 15 | + 15 |
| 32 | José Oroz Juan | Orbea - Laukiz F.T. | + 15 | + 15 |
| 33 | Matthias Russ | Gerolsteiner | + 30 | + 30 |
| 34 | Filipe Cardoso | Liberty Seguros | + 35 | + 35 |
| 35 | Ramiro Parra Iván | Cofidis | + 35 | + 35 |
| 36 | Angel Vicioso | Relax - GAM | + 38 | + 38 |
| 37 | Gorka Verdugo | Euskaltel-Euskadi | + 44 | + 44 |
| 38 | Julen Zubero Aldekoa | Orbea - Laukiz F.T. | + 48 | + 48 |
| 39 | Manuel Ortega | Andalucia - Cajasur | + 50 | + 50 |
| 40 | Antonio Serrano Marcos | Karpin-Galicia | + 52 | + 52 |
| 41 | Rubén Pérez Moreno | Euskaltel-Euskadi | + 56 | + 56 |
| 42 | Igor Astarloa | Team Milram | + 58 | + 58 |
| 43 | Sylvain Chavanel | Cofidis | + 01:00 | + 01:00 |
| 44 | Mikel Astarloza | Euskaltel-Euskadi | + 01:00 | + 01:00 |
| 45 | Francisco Pérez | Caisse d'Epargne | + 01:00 | + 01:00 |
| 46 | Hector Guerra Garcia | Liberty Seguros | + 01:08 | + 01:08 |
| 47 | Aaron Villegas Trapaga | Orbea - Laukiz F.T. | + 01:09 | + 01:09 |
| 48 | David Muñoz | Fuerteventura - Canarias | + 01:21 | + 01:21 |
| 49 | Steve Zamperi | Cofidis | + 01:24 | + 01:24 |
| 50 | Haimar Zubeldia | Euskaltel-Euskadi | + 01:24 | + 01:24 |
| 51 | David Canada | Saunier Duval - Prodir | + 01:24 | + 01:24 |
| 52 | Aitor Galdos | Euskaltel-Euskadi | + 01:29 | + 01:29 |
| 53 | Aitor Perez Arrieta | Caisse d'Epargne | + 01:33 | + 01:33 |
| 54 | Adrian Bonilla | Fuerteventura - Canarias | + 01:44 | + 01:44 |
| 55 | Stefan Schumacher | Gerolsteiner | + 01:44 | + 01:44 |
| 56 | David Arroyo | Caisse d'Epargne | + 02:42 | + 02:42 |
| 57 | Ruben Lobato | Saunier Duval - Prodir | + 02:42 | + 02:42 |
| 58 | Constantino Zaballa | Caisse d'Epargne | + 04:26 | + 04:26 |
| 59 | Antonio Colom | Astana | + 04:26 | + 04:26 |
| 60 | Pablo Lastras | Caisse d'Epargne | + 04:26 | + 04:26 |
| 61 | Santos Gonzalez | Karpin-Galicia | + 06:31 | + 06:31 |
| 62 | Oscar Sevilla | Relax - GAM | + 06:48 | + 06:48 |
| 63 | José Martínez Francisco | Andalucia - Cajasur | + 06:48 | + 06:48 |
| 64 | Vladimir Karpets | Caisse d'Epargne | + 06:48 | + 06:48 |
| 65 | Angel Vallejo Dominquez | Relax - GAM | + 06:48 | + 06:48 |
| 66 | Vicente Ballester Martinez | Fuerteventura - Canarias | + 06:48 | + 06:48 |
| 67 | Jordi Grau Sogas | Liberty Seguros | + 12:06 | + 12:06 |
| 68 | Campo Jesus Antonio Manuel | Liberty Seguros | + 12:06 | + 12:06 |
| 69 | Denis Kudashev | Relax - GAM | + 12:06 | + 12:06 |
| 70 | Inigo Lazkano Iriondo | Orbea - Laukiz F.T. | + 12:06 | + 12:06 |
| 71 | Sergio Pardilla | Vina Magna - Cropu | + 12:06 | + 12:06 |
| 72 | Gustavo Dominguez Lemos | Karpin-Galicia | + 12:06 | + 12:06 |
| 73 | Carlos Fernandez Mora Juan | Spiuk - Extremadura | + 12:06 | + 12:06 |
| 74 | Oleg Chuzhda | Fuerteventura - Canarias | + 12:06 | + 12:06 |
| 75 | Julien Loubet | AG2R Prévoyance | + 12:06 | + 12:06 |
| 76 | Asier Fernandez Mateos | Orbea - Laukiz F.T. | + 12:06 | + 12:06 |
| 77 | Matej Jurco | Team Milram | + 12:06 | + 12:06 |
| 78 | Joseba Zumeta Etxabe | Orbea - Laukiz F.T. | + 12:06 | + 12:06 |
| 79 | Josu Agirre Asegniloaza | Orbea - Laukiz F.T. | + 12:06 | + 12:06 |
| 80 | Antonio Piedra | Fuerteventura - Canarias | + 12:06 | + 12:06 |
| 81 | Pablo Urtasun | Liberty Seguros | + 12:15 | + 12:15 |
| 82 | Gorka Amuriza Gumucio | Grupo Nicolas Mateos | + 12:21 | + 12:21 |
| 83 | Roman Troncoso | Karpin-Galicia | + 12:27 | + 12:27 |
| 84 | Jose Herrada | Vina Magna - Cropu | + 12:27 | + 12:27 |
| 85 | Björn Schröder | Team Milram | + 12:34 | + 12:34 |